Abstract
Copper has an ancient history, being used extensively in the Bronze Age. Its compounds are widely distributed in the earth’s crust, and occasionally it occurs naturally as the element. It is the last member of the first transition series; the configuration 3d10 4s1 gives rise to an extensive chemistry of the +1 oxidation state. In this respect it differs from all the other members of the first transition series. The next element, zinc with the 3d10 4s2 configuration, shows the +2 state almost exclusively and does not have the transition-metal properties associated with the variable oxidation states.
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Bibliography
A.F. Wells, Structural Inorganic Chemistry, Oxford (3rd edn 1962)—solidstate crystal structures
G.E. Coates, M.L.H. Green and K. Wade, Organometallic Compounds, Methuen, London (1968)—vol. II contains the transition-metal organometallic compounds
R.J.H. Clark, The Chemistry of Titanium and Vanadium, Elsevier, Amsterdam (1968)
H. Remy, Treatise on Inorganic Chemistry, Elsevier, Amsterdam (1956)—vol. II contains the transition elements
R. Colton and J.H. Canterford, Halides of the First Row Transition Metals, Wiley, London (1969)
F.A. Cotton and G. Wilkinson, Advanced Inorganic Chemistry, Interscience, London (1972, 3rd edn)
D.L. Kepert, The Early Transition Metals, Academic Press, London (1972)
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© 1974 D. Nicholls
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Nicholls, D. (1974). Copper. In: Complexes and First-Row Transition Elements. A Macmillan Chemistry Text. Palgrave, London. https://doi.org/10.1007/978-1-349-02335-6_18
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DOI: https://doi.org/10.1007/978-1-349-02335-6_18
Publisher Name: Palgrave, London
Print ISBN: 978-0-333-17088-5
Online ISBN: 978-1-349-02335-6
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