Abstract
This chapter summarizes the solutions of the one-electron nonrelativistic Schrödinger equation, and the one-electron relativistic Dirac equation, for the Coulomb potential. The standard notations and conventions used in the mathematics literature for special functions have been chosen in preference to the notations customarily used in the physics literature whenever there is a conflict. This has been done to facilitate the use of standard reference works such as Abramowitz and Stegun [9.1], the Bateman project [9.2,3], Gradshteyn and Ryzhik [9.4], Jahnke and Emde [9.5], Luke [9.6,7], Magnus, Oberhettinger, and Soni [9.8], Olver [9.9], Szego [9.10], and the new NIST Digital Library of Mathematical Functions project, which is preparing a hardcover update [9.11] of Abramowitz and Stegun [9.1] and an online digital library of mathematical functions [9.12]. The section on special functions contains many of the formulas which are needed to check the results quoted in the previous sections, together with a number of other useful formulas. Itincludes a brief introduction to asymptotic methods.
References to the numerical evaluation of special functions are given.
Abbreviations
- NIST:
-
National Institute of Standards and Technology
References
M. Abramowitz, I. A. Stegun: Handbook of Mathematical Functions (Dover, New York 1965)
A. Erdelyi, W. Magnus, F. Oberhettinger, F. G. Tricomi: Higher Transcendental Functions, Vol. 1, 2, 3 (McGraw-Hill, New York 1955) p. 1953
A. Erdelyi, W. Magnus, F. Oberhettinger, F. G. Tricomi: Tables of Integral Transforms, Vol. 1, 2 (McGraw-Hill, New York 1954)
I. S. Gradshteyn, I. W. Ryzhik: Tables of Integrals, Series, and Products, 4th edn. (Academic Press, New York 1965)
E. Jahnke, F. Emde: Tables of Functions with Formulae and Curves, 4th edn. (Dover, New York 1945)
Y. L. Luke: The Special Functions and Their Approximations, Vol. 1, 2 (Academic Press, New York 1969)
Y. L. Luke: Mathematical Functions and Their Approximations (Academic Press, New York 1975)
W. Magnus, F. Oberhettinger, R. P. Soni: Formulas and Theorems for the Special Functions of Mathematical Physics, 3rd edn. (Springer, Berlin, Heidelberg 1966)
F. W. J. Olver: Asymptotics and Special Functions (Academic Press, New York 1974) Reprinted A. K. Peters, Wellesley 1997
G. Szego: Orthogonal Polynomials, Vol. 23, 4th edn. (American Mathematical Society, Providence 1975)
F. W. J. Olver, D. W. Lozier, R. F. Boisvert, C. W. Clark: NIST Handbook of Mathematical Functions, in preparation
F. W. J. Olver, D. W. Lozier, R. F. Boisvert, C. W. Clark: NIST Digital Library of Mathematical Functions, in preparation (see http://dlmf.nist.gov/)
A. R. Edmonds: Angular Momentum in Quantum Mechanics (Princeton Univ. Press, Princeton 1960) Sec. 2.5
L. Pauling, E. Bright Wilson: Introduction to Quantum Mechanics With Applications to Chemistry (McGraw-Hill, New York 1935) Sect. 21
G. W. F. Drake, R. N. Hill: J. Phys. B 26, 3159 (1993)
L. I. Schiff: Quantum Mechanics, 3rd edn. (McGraw-Hill, New York 1968) pp. 234-239
J. D. Talman: Special Functions, A Group Theoretic Approach (W. A. Benjamin, New York 1968) pp. 186-188
V. Fock: Z. Physik 98, 145 (1935) The relation of the Runge-Lenz vector to the “hidden” O(4) symmetry is discussed in Section 3.6.3
M. Reed, B. Simon: Methods of Modern Mathematical Physics. I. Functional Analysis (Academic Press, New York, London 1972) pp. 263-264 Chapters VII The Spectral Theorem and VIII Unbounded Operators. See Theorem VIII.6
L. Hostler: J. Math. Phys. 5, 591, 1235 (1964)
J. Schwinger: J. Math. Phys. 5, 1606 (1964)
R. A. Swainson, G. W. F. Drake: J. Phys. A 24, 79, 95,1801 (1991)
R. N. Hill, B. D. Huxtable: J. Math. Phys. 23, 2365 (1982)
R. Courant, D. Hilbert: Methods of Mathematical Physics, Vol. 1 (Interscience, New York 1953)
D. J. Hylton: J. Math. Phys. 25, 1125 (1984)
D. W. Lozier, F. W. J. Olver: Mathematics of Computation 1943-1993: A Half-Century of Computational Mathematics, Proceedings of Symposia in Applied Mathematics Vol. 48, ed. by W. Gautschi (American Mathematical Society, Providence 1994)
I. J. Thompson, A. R. Barnett: J. Comput. Phys. 64, 490 (1986)
I. J. Thompson, A. R. Barnett: Comp. Phys. Commun. 36, 363 (1985)
R. E. Meyer: SIAM Rev. 31, 435 (1989)
H. Skovgarrd: Uniform Asymptotic Expansions of Confluent Hypergeometric Functions and Whittaker Functions (Gjellerups, Copenhagen 1966)
N. Bleistein, R. A. Handelsman: Asymptotic Expansions of Integrals (Holt, Rinehart, & Winston, New York 1975) Reprinted Dover, New York 1986
R. Wong: Asymptotic Approximations of Integrals (Academic Press, San Diego 1989) Reprinted SIAM, Philadelphia 2001
R. C. Forrey, R. N. Hill: Ann. Phys. 226, 88-157 (1993)
R. N. Hill: Phys. Rev. A 51, 4433 (1995)
R. C. Forrey, R. N. Hill, R. D. Sharma: Phys. Rev. A 52, 2948 (1995)
C. Krauthauser, R. N. Hill: Can. J. Phys. 80, 181 (2002)
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Hill, R. (2006). Hydrogenic Wave Functions. In: Drake, G. (eds) Springer Handbook of Atomic, Molecular, and Optical Physics. Springer Handbooks. Springer, New York, NY. https://doi.org/10.1007/978-0-387-26308-3_9
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