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Alkene Metathesis in Organic Synthesis pp 133–154Cite as

Enyne Metathesis

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Part of the book series: Topics in Organometallic Chemistry ((TOPORGAN,volume 1))

Abstract

Enyne metathesis is unique and interesting in synthetic organic chemistry. Since it is difficult to control intermolecular enyne metathesis, this reaction is used as intramolecular enyne metathesis. There are two types of enyne metathesis: one is caused by [2+2] cycloaddition of a multiple bond and transition metal carbene complex, and the other is an oxidative cyclization reaction caused by low-valent transition metals. In these cases, the alkylidene part migrates from alkene to alkyne carbon. Thus, this reaction is called an alkylidene migration reaction or a skeletal reorganization reaction. Many cyclized products having a diene moiety were obtained using intramolecular enyne metathesis. Very recently, intermolecular enyne metathesis has been developed between alkyne and ethylene as novel diene synthesis.

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Authors
  1. Miwako Mori
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Editors and Affiliations

  1. Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, D-45470, Mülheim an der Ruhr, Germany

    Alois Fürstner

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© 1998 Springer-Verlag Berlin Heidelberg

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Mori, M. (1998). Enyne Metathesis. In: Fürstner, A. (eds) Alkene Metathesis in Organic Synthesis. Topics in Organometallic Chemistry, vol 1. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-69708-X_5

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  • DOI: https://doi.org/10.1007/3-540-69708-X_5

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  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-64254-1

  • Online ISBN: 978-3-540-69708-4

  • eBook Packages: Springer Book Archive

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