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Collective and Cooperative Phenomena in Molecular Functional Materials

  • Chapter
Non-Linear Optical Properties of Matter

Part of the book series: Challenges and Advances in Computational Chemistry and Physics ((COCH,volume 1))

Abstract

We discuss cooperative and collective behavior resulting from classical electrostatic intermolecular interactions in molecular materials with negligible intermolecular overlap. With reference to materials based on push-pull chromophores, we discuss the merits of several approximation schemes for the calculation of linear and non-linear optical susceptibilities. Collective and cooperative behavior is recognized in important deviations of the material properties from the oriented gas approximation scheme, and/or from the exciton model. Extreme collective and cooperative behavior in attractive clusters is discussed, where bistable behavior and the phenomenon of multielectron-transfer appear

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Authors and Affiliations

  1. Dip. Chimica GIAF, Parma University & INSTM-UdR Parma, Viale delle Scienze 17/A, 43100 Parma, Italy

    Anna Painelli

  2. Synthèse et ElectroSynthèse Organiques (CNRS, UMR 6510), Institut de Chimie, Université de Rennes 1, Campus Scientifique de Beaulieu, Bât 10A, F-35042 Rennes Cedex, France

    Francesca Terenziani

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  1. Anna Painelli
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Editors and Affiliations

  1. National Hellenic Research Foundation, Greece

    Manthos G. Papadopoulos

  2. Nicolaus Copernicus University, Poland

    Andrzej J. Sadlej

  3. Jackson State University, USA

    Jerzy Leszczynski

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Painelli, A., Terenziani, F. (2006). Collective and Cooperative Phenomena in Molecular Functional Materials. In: Papadopoulos, M.G., Sadlej, A.J., Leszczynski, J. (eds) Non-Linear Optical Properties of Matter. Challenges and Advances in Computational Chemistry and Physics, vol 1. Springer, Dordrecht. https://doi.org/10.1007/1-4020-4850-5_7

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