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Organometallic Oxometal Clusters

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Polyoxometalate Chemistry From Topology via Self-Assembly to Applications

Abstract

The presentation focusses on integrated oxometal clusters containing fac-{M(CO)3}+ (M = Mn, Re), {Rh(η5-C5Me5)2+ or {Ru(η6-arene)}2+ organometallic subunits and oxo(alkoxo)molybdenum or tungsten subunits. The discussion adresses the following questions: i) structural relationships, ii) structural preferences, and iii) stereochemical non-rigidity. The molecular structures of the organometallic oxometal clusters are discussed in connection with those of previously reported polyoxo(alkoxo)metalates and organometallic clusters. The apparent structural relationships within these clusters underscore the electronic connection between d6-fac-{ML3} (M = Mn, Re, Ru, Rh,) and d0-fac-{MO3} or d0-fac-{MO2(OR)}+ (M = Mo, W) units.

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References

  1. R. K. C. Ho, and W. G. Klemperer: J. Am. Chem. Soc. 100, 6772 (1978).

    Article  CAS  Google Scholar 

  2. W. H. Knoth: J. Am. chem. Soc. 101, 759 (1979).

    CAS  Google Scholar 

  3. For lead references to the extensive studies of Klemperer, Day and co-workers, see: V. W. Day, and W. G. Klemperer: Science 228, 533 (198

    CAS  Google Scholar 

  4. V. W. Day, and W. G. Klemperer in Polyoxometalates: From Platonic Solids to Anti-Retroviral Activity (Eds.: M. T. Pope, A. Müller), Kluwer Academic Publishers, Dordrecht, 1994, pp. 87–104.

    Google Scholar 

  5. R. G. Finke, and M. W. Droege: J. Am. Chem. Soc. 106, 7274 (1984).

    CAS  Google Scholar 

  6. R. G. Finke, B. Rapko, and P. J. Domaille: Organometallics 5, 175 (1986).

    CAS  Google Scholar 

  7. For lead references to the extensive studies of Finke and co-workers, see: R. G. Finke, in Polyoxometalates: From Platonic Solids to Anti-Retroviral Activity (Eds.: M. T. Pope, A. Müller), Kluwer, Dordrecht, 1994, pp. 267–280

    Google Scholar 

  8. H. Weiner, J. D. Aiken III, and R. G. Finke: Inorg. Chem. 35, 7905 (1996) and references 6 and 7 therein.

    Article  CAS  Google Scholar 

  9. P. Gouzerh, and A. Proust: Chem. Rev. 98, 77 (1998).

    Article  CAS  Google Scholar 

  10. K. Isobe, and A. Yagasaki: Acc. Chem. Res. 26, 524 (1993), and references therein.

    Article  CAS  Google Scholar 

  11. A. R. Siedle, R. A. Newmark, W. B. Gleason, R. P. Skarjune, K. O. Hodgson, A. L. Roe, and V. W. Day: Solid State Ionics 26, 109 (1988).

    Article  CAS  Google Scholar 

  12. A. R. Siedle: New J. Chem. 13, 719 (1989), and references therein.

    CAS  Google Scholar 

  13. T. Nagata, M. Pohl, H. Weiner, and R. G. Finke: Inorg. Chem. 36, 1366 (1997) and references therein.

    Article  CAS  Google Scholar 

  14. A. R. Siedle, C. G. Markell, P. A. Lyon, K. O. Hodgson, and A. L. Roe: Inorg. Chem. 26, 219 (1987).

    Article  CAS  Google Scholar 

  15. Y. Imada, T. Shido, R. Ohnishi, K. Isobe, and M. Ichikawa: Catal. Lett. 38, 101 (1996).

    Article  CAS  Google Scholar 

  16. F. Bottomley, and J. Chen: Organometallics 11, 3404 (1992).

    CAS  Google Scholar 

  17. J. R. Harper, and A. L. Rheingold: J. Am. Chem. Soc. 112, 4037 (1990).

    Article  CAS  Google Scholar 

  18. P. Gouzerh, Y. Jeannin, A. Proust, and F. Robert, Angew. Chem., Int. Ed. Engl. 28, 1363 (1989).

    Article  Google Scholar 

  19. A. Proust, P. Gouzerh, and F. Robert: Inorg. Chem. 32, 5291, (1993).

    CAS  Google Scholar 

  20. C. J. Besecker, and W. G. Klemperer: J. Am. Chem. Soc. 102, 7598 (1980).

    Article  CAS  Google Scholar 

  21. V. W. Day, M. F. Fredrich, M. R. Thompson, W. G. Klemperer, R.-S. liu, and W. Shum: J. Am. Chem. Soc. 103, 3597 (1981).

    CAS  Google Scholar 

  22. R. Villanneau: Doctoral Dissertation, Université Pierre et Marie Curie (1997).

    Google Scholar 

  23. R. Villanneau, R. Delmont, A. Proust, and P. Gouzerh: submitted for publication.

    Google Scholar 

  24. M. D. Clerk and M. J. Zaworotko: J. Chem. Soc., Chem. Commun 1607 (1991).

    Google Scholar 

  25. M. Herberhold, G., Süβ J. Ellermnn, and H. Gäbelein: Chem. Ber. 111, 2931 (1978).

    CAS  Google Scholar 

  26. H. Kang, S. Liu, S. N. Shaikh, T. Nicholson, and J. Zubieta: Inorg. Chem. 28, 920 (1989).

    CAS  Google Scholar 

  27. A. J. Wilson, W. T. Robinson, and C. J. Wilkins: Acta Crystallogr. Sect. C. 39, 54, (1983).

    Google Scholar 

  28. S. Liu, L. Ma, D. McGowty, and J. Zubieta: Polyhedron 13, 1541 (1990).

    Google Scholar 

  29. D. Crans, R. W. Marshman, M. S. Gotlieb, O. P. Anderson, and M. M. Miller: Inorg. Chem. 31, 4939 (1992).

    Article  CAS  Google Scholar 

  30. R. Delmont: Doctoral Dissertation, Université Pierre et Marie Curie (1997).

    Google Scholar 

  31. 22. (b) R. Delmont, A. Proust, F. Robert, and P. Gouzerh: submitted for publication.

    Google Scholar 

  32. W. N. Lipscomb: Inorg. Chem. 4, 132 (1965).

    Article  CAS  Google Scholar 

  33. Y. Hayashi, F. Müller, Y. Lin, S. M. Miller, O. P. Anderson, and R. G. Finke: J. Am. Chem. Soc. 119, 11401 (1997).

    CAS  Google Scholar 

  34. E. W. Corcoran: Inorg. Chem. 29, 157 (1990).

    Article  CAS  Google Scholar 

  35. R. C. Haushalter: J. Chem. Soc., Chem. Commun. 1566 (1987).

    Google Scholar 

  36. K.-H. Lii, R. C. Haushalter, and C. J. O’Connor: Angew. Chem. Int. Ed. Engl. 26, 549 (1987).

    Article  Google Scholar 

  37. L. A. Mundi, and R. C. Haushalter: J. Am. Chem. Soc. 113, 6340 (1991).

    Article  CAS  Google Scholar 

  38. A. Hüllen: Angew. Chem. 76, 588 (1964).

    Google Scholar 

  39. A. Hüllen: Ber. Bunsengesell. 70, 598 (1966).

    Google Scholar 

  40. L. Ma, S. Liu, and J. Zubieta: Inorg. Chem. 28, 175 (1989).

    Article  CAS  Google Scholar 

  41. A. Müller, J. Meyer, H. Bögge, A. Stammler, and A. Botar: Chem. Eur. J. 4, 1388 (1998).

    Google Scholar 

  42. L. Ma, S. Liu, and J. Zubieta: J. Chem. Soc., Chem. Commun 440 (1989).

    Google Scholar 

  43. R. Villanneau, A. Proust, F. Robert, and P. Gouzerh: manuscript in preparation.

    Google Scholar 

  44. C. J. Besecker, V. W. Day, W. G. Klemperer, and M. R. Thompson: J. Am. Chem. Soc. 106, 4125 (1984).

    Article  CAS  Google Scholar 

  45. H. K. Chae, W. G. Klemperer, D. E. Paez Loya, V. W. Day, and T. A. Eberspacher: Inorg. Chem. 31, 3187 (1992).

    Article  CAS  Google Scholar 

  46. D. J. Edlund, R. J. Saxton, D. K. Lyon, and R. G. Finke: Organometallics 7, 1692 (1988).

    Article  CAS  Google Scholar 

  47. K. Nomiya, C. Nozaki, M. Kaneko, R. G. Finke, and M. Pohl: J. Organomet. Chem. 505, 23 (1995).

    Article  CAS  Google Scholar 

  48. M. Pohl, Y. Lin, T. J. R. Weakley, K. Nomiya, M. Kaneko, H. Weiner, and R. G. Finke: Inorg. Chem. 34, 767 (1995).

    CAS  Google Scholar 

  49. H. K. Chae, W. G. Klemperer, and V. W. Day: Inorg. Chem. 28, 1423 (1989).

    Article  CAS  Google Scholar 

  50. Y. Hayashi, Y. Ozawa, and K. Isobe: Chem. Lett. 425 (1989).

    Google Scholar 

  51. A. Proust, P. Gouzerh, and F. Robert: Angew. Chem. Int. Ed. Engl. 32, 115 (1993).

    Article  Google Scholar 

  52. Y. Hayashi, K. Toriumi, and K. Isobe: J. Am. Chem. Soc. 110, 3666 (1988).

    CAS  Google Scholar 

  53. Y. Do, X.-Z. You, C. Zhang, Y. Ozawa, and K. Isobe: J. Am. Chem. Soc. 113, 5892 (1991).

    Article  CAS  Google Scholar 

  54. G. Süss-Fink, L. Plasseraud, V. Ferrand, and H. Stoeckli-Evans: J. Chem. Soc., Chem. Commun. 1657 (1997).

    Google Scholar 

  55. G. Süss-Fink, L. Plasseraud, V. Ferrand, S. Stanislas, A. Neels, H. Stoeckli-Evans, M. Henry, G. Laurenczy, and R. Roulet: Polyhedron 17, 2817 (1998).

    Google Scholar 

  56. S. Tahara, T. Nishioka, I. Kinoshita, and K. Isobe: J. Chem. Soc., Chem. Commun. 891 (1997).

    Google Scholar 

  57. E. M. McCarron III, and R. L. Harlow, J. Am. Chem. Soc. 105, 6179 (1983).

    Article  CAS  Google Scholar 

  58. V. W. Day, T. A. Eberspacher, W. G. Klemperer, R. P. Planalp, P. W. Schiller, A. Yagasaki, and B. Zhong: Inorg. Chem. 32, 1629 (1993).

    CAS  Google Scholar 

  59. V. Artero: Doctoral Dissertation (in preparation), Université Pierre et Marie Curie

    Google Scholar 

  60. V. Artero, A. Proust, P. Herson, R. Thouvenot, and P. Gouzerh: manuscript in preparation.

    Google Scholar 

  61. L. Plasseraud, H. Stoeckli-Evans, and G. Süss-Fink: Inorg. Chem. Comm., 2, 344 (1999).

    Article  CAS  Google Scholar 

  62. T. Szyperski, and P. Schwerdfeger: Angew. Chem. Int. Ed. Engl. 28, 1228 (1989).

    Article  Google Scholar 

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Authors and Affiliations

  1. Laboratoire de Chimie Inorganique et Matériaux Moléculaires, Unité CNRS 7071, Case 42, Université Pierre et Marie Curie, 4 Place Jussieu, 75252, Paris Cedex 05, France

    A. Proust, R. Villanneau, R. Delmont, V. Artero & P. Gouzerh

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  1. A. Proust
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  2. R. Villanneau
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  3. R. Delmont
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  4. V. Artero
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  5. P. Gouzerh
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Editors and Affiliations

  1. Georgetown University, Washington, DC, USA

    Michael T. Pope

  2. University of Bielefeld, Bielefeld, Germany

    Achim Müller

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© 2001 Kluwer Academic Publishers

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Proust, A., Villanneau, R., Delmont, R., Artero, V., Gouzerh, P. (2001). Organometallic Oxometal Clusters. In: Pope, M.T., Müller, A. (eds) Polyoxometalate Chemistry From Topology via Self-Assembly to Applications. Springer, Dordrecht. https://doi.org/10.1007/0-306-47625-8_5

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  • DOI: https://doi.org/10.1007/0-306-47625-8_5

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-0-7923-7011-6

  • Online ISBN: 978-0-306-47625-9

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