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Thermal equation of state of natural chromium spinel up to 26.8 GPa and 628 K

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Abstract

A pressure–volume–temperature data set has been obtained for natural chromium spinel, using synchrotron X-ray diffraction with a resistance heated diamond-anvil cell (RHDAC). The unit cell parameter of the chromium spinel was measured by energy dispersive X-ray diffraction up to pressures of 26.8 GPa and temperatures of 628 K. No phase change has been observed. The observed P–V–T data were fit to the high-temperature Birch-Murnaghan equation of state, with V 0 fixed at its experimental value, yields K 0 = 209 ± 9 GPa, (∂K/∂T)P = −0.056 ± 0.035 GPa K−1, and α0 = 7±1 × 10−5 K−1. The temperature derivative of the bulk modulus (∂K/∂T)P of chromium spinel is determined here for the first time. The obtained K 0 is slightly higher than the previous results of synthetic spinel. We suggest that Fe2+–Mg2+ substitution is responsible for the high bulk modulus of chromium spinel.

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Acknowledgements

We thank two anonymous referees for their helpful comments and suggestions. This work was performed at 4W2 High-Pressure Station, Beijing Synchrotron Radiation Facility (BSRF). High-Pressure Station is supported by Chinese Academy of Sciences (Grant No. KJCX2-SW-N20,KJCX2-SW-N03). This work is supported by National Basic Research Program of China (Grant No 2005CB724400), the Knowledge Innovation Project of Chinese Academy of Science (Grant No KJCX2-SW-N20), and the National Natural Science Foundation of China (Grant No 40574036).

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Authors and Affiliations

  1. Institute of Geochemistry, Chinese Academy of Science, Guiyang, 550002, China

    Dawei Fan, Wenge Zhou, Yonggang Liu, Fang Wan & Hongsen Xie

  2. Graduate University of Chinese Academy of Science, Beijing, 100049, China

    Dawei Fan & Fang Wan

  3. Institute of Geochemistry, Chinese Academy of Science, Guiyang, 550002, China

    Chongqiang Liu

  4. College of Resource and Environment Engineering of Guiozhou University, Guiyang, 550003, China

    Xi Jiang

  5. Institute of High Energy Physics, Chinese Academy of Science, Beijing, 100049, China

    Jing Liu & Xiaodong Li

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  1. Dawei Fan
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Correspondence to Wenge Zhou.

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Fan, D., Zhou, W., Liu, C. et al. Thermal equation of state of natural chromium spinel up to 26.8 GPa and 628 K. J Mater Sci 43, 5546–5550 (2008). https://doi.org/10.1007/s10853-008-2825-5

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  • DOI: https://doi.org/10.1007/s10853-008-2825-5

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