Skip to main content
Log in

Activated carbons obtained from agro-industrial waste: textural analysis and adsorption environmental pollutants

  • Published:
Adsorption Aims and scope Submit manuscript

Abstract

In this study, we aimed to use as a new lignocellulosic precursor in the production of activated carbon. The physicochemical characteristics of the activated carbons obtained under optimum conditions were determined by using some techniques such as thermo-gravimetric (TG/DTG) analysis, nitrogen adsorption–desorption, scanning electron microscopy (SEM) and surface functional group analysis by Fourier transform infrared spectroscopy (FT-IR), Boehm titration method and point of zero charge (pHpzc). In addition, the activated carbons were tested to remove phenols from aqueous solutions. The results indicated that activated carbon the orange peel, pine cone and yerba mate, could be employed as an alternative low-cost activated carbon for the removal the phenolic contaminants from wastewater.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  • Almendros, A.I., Martín-Lara, M.A., Ronda, A., Pérez, A., Blázquez, G., Calero, M.: Physico-chemical characterization of pine cone shell and its use as biosorbent and fuel. Bioresource Technol. 196, 406–412 (2015)

    Article  CAS  Google Scholar 

  • Boehm, H.P.: Surface oxides on carbon and their analysis: a critical assessment. Carbon 40, 145–149 (2002)

    Article  CAS  Google Scholar 

  • Dawood, S., Sen, T.K., Phan, Ch.: Synthesis and characterisation of novel-activated carbon from waste biomass pine cone and its application in the removal of congo red dye from aqueous solution by adsorption. Water Air Soil Pollut. 225, 1818–1834 (2014)

    Article  CAS  Google Scholar 

  • Deladino, L., Navarro, A.S., Martino, M.N.: Microstructure of minerals and yerba mate extract co-crystallized with sucrose J. Food Eng. 96, 410–415 (2010)

  • Do, D.D.: Practical approaches of pure component adsorption equilibria. In: Duong, D. (ed.) Do Adsorption Analysis: Equilibria and Kinetics. Imperial College Press, United Kingdom (1998)

  • Fernandez, M.E., Nunell, G.V., Bonelli, P.R., Cukierman, A.L.: Activated carbon developed from orange peels: batch and dynamic competitive adsorption of basic dyes. Ind. Crop. Prod. 62, 437–445 (2014)

    Article  CAS  Google Scholar 

  • Foo, K.Y., Hameed, B.H.: Insights into the modeling of adsorption isotherm systems. Chem. Eng. J. 156, 2–10 (2010)

    Article  CAS  Google Scholar 

  • Gecgel, Ü., Kolancilar, H.: Adsorption of remazol brilliant blue R on activated carbon prepared from a pine cone. Nat. Prod. Res. 26, 7659–7664 (2012)

    Article  CAS  Google Scholar 

  • Giraldo, L., Moreno-Piraján, J.C.: Synthesis of activated carbon mesoporous from coffee waste and its application in adsorption zinc and mercury ions from aqueous solution. Eur. J. Chem. 9(2), 938–948 (2012)

    CAS  Google Scholar 

  • Gündogdu, A., Duran, C., Sentürk, H.B., Soylak, M., Imamoglu, M., Onal, Y.: Physicochemical characteristics of a novel activated carbon produced from tea industry waste. J. Anal. Appl. Pyrol. 104, 249–259 (2013)

    Article  CAS  Google Scholar 

  • Hamdaoui, O., Naffrechoux, E.: Modeling of adsorption isotherms of phenol and chlorophenols onto granular activated carbon Part II. Models with more than two parameters. J. Hazard. Mater. 147, 401–411 (2007)

  • Hameed, B.H., Mahmoud, D.K., Ahmad, A.L.: Sorption equilibrium and kinetics of basic dye from aqueous solution using banana stalk waste. J. Hazard. Mater. 158, 499–506 (2008)

    Article  CAS  Google Scholar 

  • Hui, Z., YanQiu, L., AiHong, M., QingHai, L., YanGuo, Z.: Thermogravimetric characteristics of typical municipal solid waste fractions during co-pyrolysis. Waste Manage. 38, 194–200 (2015)

    Article  CAS  Google Scholar 

  • Húmpola, P., Odetti, H.S., Albesa, A.G., Vicente, J.L.: Adsorption of phenols from different solvents on graphene: semi-empirical quantum mechanical calculations. Adsorpt. Sci. Technol. 31, 359–371 (2013a)

    Article  Google Scholar 

  • Húmpola, P.D., Odetti, H.S., Fertitta, A.E., Vicente, J.L.: Thermodynamic analysis of adsorption models of phenol in liquid phase on different activated carbons. J. Chil. Chem. Soc. 58(1), 1541–1544 (2013b)

    Article  Google Scholar 

  • Kasper Fernandes, E.R., Marangoni, C., Souza, O., Sellin, N.: Thermochemical characterization of banana leaves as a potential energy source. Energy Convers. Manage. 75, 603–608 (2013)

  • Linhares, B., Trevisan Weber, C., Luiz Foletto, E., Silva Paz, D., Mazutti, M.A., Carvalho Collazzo, G.: Activated carbon prepared from yerba mate used as a novel adsorbent for removal of tannery dye from aqueous solution. Environ. Technol. 34(16), 2401–2406 (2013)

    Article  CAS  Google Scholar 

  • Lopez-Ramon, M.V., Stoeckli, F., Moreno-Castilla, C., Carrasco-Marin, F.: On the characterization of acidic and basic surface sites on carbon by various techniques. Carbon 37, 1215–1221 (1999)

    Article  CAS  Google Scholar 

  • Malik, P.K.: Use of activated carbons prepared from sawdust and rice-husk for adsorption of acid dyes: a case study of Acid Yellow 36. Dyes Pigments 56(3), 239–249 (2003)

    Article  CAS  Google Scholar 

  • Miranda, R., Bustos-Martinez, D., Sosa Blanco, C., Gutiérrez Villarreal, M.H., Rodriguez Cantú, M.E.: Pyrolysis of sweet orange (Citrus sinensis) dry peel. J. Anal. Appl. Pyrolysis 86, 245–251 (2009)

  • Momčilović, M., Purenović, M., Bojić, A., Zarubica, A., Ranđelović, M.: Removal of lead (II) ions from aqueous solutions by adsorption onto pine cone activated carbon. Desalination 276, 53–59 (2011)

    Article  CAS  Google Scholar 

  • Moreno-Barbosa, J.J., López-Velandia, C., Maldonado, AdP, Giraldo, L., Moreno-Piraján, J.C.: Removal of lead(II) and zinc(II) ions from aqueous solutions by adsorption onto activated carbon synthesized from watermelon shell and walnut shell. Adsorption 19, 675–685 (2013)

    Article  CAS  Google Scholar 

  • Nsaful, F., Collard, F., Carrier, M., Görgens, J.F., Knoetze, J.H.: Lignocellulose pyrolysis with condensable volatiles quantification by thermogravimetric analysis—Thermal desorption/gas chromatography–mass spectrometry method. J. Anal. Appl. Pyrolysis 116, 86–95 (2015)

    Article  CAS  Google Scholar 

  • Nunell, G.V., Fernandez, M.E., Bonelli, P.R., Cukierman, A.L.: Nitrate uptake improvement by modified activated carbons developed from two species of pine cones. J. Colloid Interface Sci. 440, 102–108 (2015)

    Article  CAS  Google Scholar 

  • Ozdemir, I., Sahin, M., Orhan, R., Erdem, M.: Preparation and characterization of activated carbon from grape stalk by zinc chloride activation. Fuel Process. Technol. 125, 200–206 (2014)

    Article  CAS  Google Scholar 

  • Puziy, A.M., Poddubnaya, O.I., Martínez-Alonso, A., Castro-Muñiz, A., Suárez-García, F., Tascón, J.M.D.: Oxygen and phosphorus enriched carbons from lignocellulosic material. Carbon 45, 1941–1950 (2007)

    Article  CAS  Google Scholar 

  • Reddy, K.S.K., Al Shoaibi, A., Srinivasakannan, C.: A comparison of microstructure and adsorption characteristics of activated carbons by CO2 and H3PO4 activation from date palm pits. New Carbon Mater. 27, 344–351 (2012)

    Article  CAS  Google Scholar 

  • Rios, R.B., Silva, F.W.M., Torres, A.E.B., Azevedo, D.C.S., Silva, M., Cavalcante Jr., C.L.: Adsorption of methane in activated carbons obtained from coconut shells using H3PO4 chemical activation. Adsorption 15, 271–277 (2009)

    Article  CAS  Google Scholar 

  • Rodríguez Reinoso, F., Molina-Sabio, M.: Textural and chemical characterization of microporous carbons. Adv Colloid Interfac. 76, 271–294 (1998).

  • Salman, J.M., Hameed, B.H.: Removal of insecticide carbofuran from aqueous solutions by banana stalks activated carbon. J. Hazard. Mater. 176, 814–819 (2010)

    Article  CAS  Google Scholar 

  • Salman, J.M., Njoku, V.O., Hameed, B.H.: Adsorption of pesticides from aqueous solution onto banana stalk activated carbon. Chem. Eng. J. 174, 41–48 (2011)

    Article  CAS  Google Scholar 

  • Santra, A.K., Pal, T.K., Datta, S.: Removal of metanil yellow from its aqueous solution by fly ash and activated carbon produced from different sources. Sep. Sci. Technol. 43(6), 1434–1458 (2008)

    Article  CAS  Google Scholar 

  • Solomon Bello, O., Ahmada, M.A., Ahmada, N.: Adsorptive features of banana (Musa paradisiaca) stalk-based activated carbon for malachite green dye removal. Chem Ecol. 28(2), 153–167 (2012)

  • Szymański, G., Karpiński, Z., Biniak, S., Świątkowski, A.: The effect of the gradual thermal decomposition of surface oxygen species on the chemical and catalytic properties of oxidized activated carbon. Carbon 40, 2627–2639 (2002)

    Article  Google Scholar 

  • Terzyk, A.P.: Further insights into the role of carbon surface functionalities in the mechanism of phenol adsorption. J. Colloid Interface Sci. 268, 301–329 (2003)

    Article  CAS  Google Scholar 

  • Thommes, M., Cychosz, K.A., Neimark, A.V.: Advanced physical adsorption characterization of nanoporous carbons. In: Tascón, J.M.D. (ed.) Novels Carbons Adsorbent. Elsevier, Great Britain (2012)

    Google Scholar 

  • Vargas, D.P., Giraldo, L., Moreno-Piraján, J.C.: Carbon dioxide and methane adsorption at high pressure on activated carbon materials. Adsorption 19, 1075–1082 (2013)

    Article  CAS  Google Scholar 

  • Wu, F.-C., Wu, P.-H., Tseng, R.-L., Juang, R.-S.: Use of refuse-derived fuel waste for the adsorption of 4-chlorophenol and dyes from aqueous solution: equilibrium and kinetics. J. Taiwan Inst. Chem. E. 45, 2628–2639 (2014)

    Article  CAS  Google Scholar 

  • Yahya, M.A., Al-Qodah, Z., Zanariah Ngah, C.W.: Agricultural bio-waste materials as potential sustainable precursors used for activated carbon production: a review. Renew. Sustain. Energy Rev. 46, 218–235 (2015)

Download references

Acknowledgments

The authors thank the University National of Litoral, University of the Andes, University National of Colombian and Organization of American States.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Pablo Húmpola.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Húmpola, P., Odetti, H., Moreno-Piraján, J.C. et al. Activated carbons obtained from agro-industrial waste: textural analysis and adsorption environmental pollutants. Adsorption 22, 23–31 (2016). https://doi.org/10.1007/s10450-015-9728-y

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10450-015-9728-y

Keywords

Navigation