Abstract
The effect of fluorine (F) content in the parent glass on nucleation and crystallization of glass-ceramics with canasite as the principle crystalline phase have been studied using differential thermal analysis, X-ray diffraction, and transmission electron and scanning electron microscopies. CaF2 precipitation occurred during the nucleation phase at all concentrations studied. However, canasite formation during subsequent crystallization was strongly dependent on F content. Canasite failed to form at both high and low concentrations of F, while with intermediate F concentrations canasite and CaF2 were the only phases identified. Agrellite (NaCa2Si4O10F) formed when the F content was high.
Similar content being viewed by others
References
G. H. Beall, Solid State Sci. 3 (1989) 333.
Idem. Corning Research (Corning Annual Report) (1973) 99.
D. G. Grossman, in “Advances in ceramics”, edited by J. H. Simmons, D. R. Uhlmann and G. H. Beall (The American Ceramic Society, Columbus, Ohio, 1982) p. 249.
G. H. Beall, J. Non-Cryst. Solids 129 (1991) 163.
Idem. US Patent 4 386 162 (May 31, 1983).
Idem. US Patent 4 397 670 (August 9, 1983).
P. W. McMillan, “Glass ceramics” 2nd edn (Academic Press, New York, 1979) p. 84.
Q. A. Juma'a and J. M. Parker, in “Advances in Ceramics”, edited by J. H. Simmons, D. R. Uhlmann and G. H. Beall (The American Ceramic Society, Columbus, Ohio, 1982) p. 218.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Likitvanichkul, S., Lacourse, W.C. Effect of fluorine content on crystallization of canasite glass-ceramics. Journal of Materials Science 30, 6151–6155 (1995). https://doi.org/10.1007/BF00369661
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/BF00369661