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Coordination and Organometallic Complexes as Second-Order Nonlinear Optical Molecular Materials

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Molecular Organometallic Materials for Optics

Part of the book series: Topics in Organometallic Chemistry ((TOPORGAN,volume 28))

Abstract

Coordination and organometallic complexes with second-order nonlinear optical (NLO) properties have attracted increasing attention as potential molecular building block materials for optical communications, optical data processing and storage, or electrooptical devices. In particular, they can offer additional flexibility, when compared to organic chromophores, due to the presence of metal–ligand charge-transfer transitions, usually at relatively low-energy and of high intensity, tunable by virtue of the nature, oxidation state, and coordination sphere of the metal center. This chapter presents an overview of the main classes of second-order NLO coordination and organometallic complexes with various ligands such as substituted amines, pyridines, stilbazoles, chelating ligands (bipyridines, phenanthrolines, terpyridines, Schiff bases), alkynyl, vinylidene, and cyclometallated ligands, macrocyclic ligands (porphyrins and phthalocyanines), metallocene derivatives, and chromophores with two metal centers. The coverage, mainly from 2000 up to now, is focused on NLO properties measured at molecular level from solution studies, as well as on NLO properties of bulk materials.

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Acknowledgements

We sincerely thank Dr Lea Vaiana for assistance in drawing various figures, the Ministero dell'Istruzione, dell'Università e della Ricerca (Progetto FIRB 2003 RBNE033KMA Molecular compounds and hybrid nanostructured materials with resonant and non resonant optical properties for photonic devices) and the Centro Nazionale delle Ricerche (PROMO 2006 Nanostrutture organiche, organometalliche, polimeriche ed ibride: ingegnerizzazione supramolecolare delle proprietà fotoniche dispositivistiche innovative per optoelettronica) for financial support.

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Authors and Affiliations

  1. Dipartimento di Scienze Chimiche, Università di Catania, Viale A. Doria 8, 95125, Catania, Italy

    Santo Di Bella

  2. Dipartimento di Chimica Inorganica, Metallorganica e Analitica “Lamberto Malatesta” dell’Università degli Studi di Milano, UdR-INSTM di Milano and ISTM-CNR, Via Venezian 21, 20133, Milano, Italy

    Claudia Dragonetti, Maddalena Pizzotti, Dominique Roberto, Francesca Tessore & Renato Ugo

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  1. Santo Di Bella
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  2. Claudia Dragonetti
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  3. Maddalena Pizzotti
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  4. Dominique Roberto
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  5. Francesca Tessore
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  6. Renato Ugo
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Correspondence to Santo Di Bella or Dominique Roberto .

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  1. CNRS UMR 6509, Universite Rennes I, avenue du Gl Leclerc, Rennes CX, 35042, France

    Hubert Bozec

  2. UMR 6226 CNRS, Université de Rennes 1, av. du Général Leclerc 263, Rennes CX, 35042, France

    Véronique Guerchais

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Di Bella, S., Dragonetti, C., Pizzotti, M., Roberto, D., Tessore, F., Ugo, R. (2010). Coordination and Organometallic Complexes as Second-Order Nonlinear Optical Molecular Materials. In: Bozec, H., Guerchais, V. (eds) Molecular Organometallic Materials for Optics. Topics in Organometallic Chemistry, vol 28. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-01866-4_1

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