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Geochemical assessment of water quality for irrigation in abandoned limestone quarry pit at Nkalagu area, southern Benue Trough, Nigeria

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Abstract

In the study, the quality of groundwater for irrigation is assessed. The following parameters were analysed using American Public Health Association standard method: pH, turbidity, electrical conductivity, total dissolved solids, Mg2+, SO42−, Cl, HCO32−, K+, Na2+ and Ca2+. Important constituents that influence the water quality for irrigation are electrical conductivity which ranges from 4 to 1560 µS/cm, soluble sodium percentage which ranges from 4 to 33%, magnesium adsorption ratio (MAR) which ranges from 30 to 81, Kelly’s ratio which ranges from 0 to 0.5, sodium percentage (Na %) which ranges from 4 to 50%, sodium adsorption ratio which ranges from 0 to 0.6, residual sodium carbonate (RSC) which ranges from 1.5 to 3.5, permeability index which ranges from 157 to 675% and total hardness (TH) which ranges from 102 to 614 mg/L in Nkalagu water. The above estimated parameter values satisfy the various permissible standard values for irrigation except MAR, TH, RSC that are slightly above the various permissible standard values. The hydrogeochemical facies analysis plotted in Piper diagram reveals that 53.85% of the samples are predominantly (Cl–SO42−) facies, 15.38% are (SO42−–Cl and SO42−–Cl–HCO3) facies, while 7.69% are (Mg2+–SO42−–Cl–HCO3 and Cl–SO42−–HCO3) facies. The water type is Ca–Cl2 with much considerable permanent hardness. Although some samples satisfied the various permissible standard values for irrigation, treatment is, however, very strongly recommended to improve the quality and make it more suitable for irrigation.

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References

  • Aleke CG, Okogbue CO, Aghamelu OP, Nnaji NJ (2016) Hydrogeological potential and qualitative assessment of groundwater from the Ajali Sandstone at Ninth Mile area, southeastern Nigeria. Environ Earth Sci 75:290. https://doi.org/10.1007/s12665-015-4843-3

    Article  Google Scholar 

  • American Public Health Association (APHA) (2012) Standards methods for the examination of water and wastewater, 22nd edn. American Public Health Association (APHA), American Water Works Association (AWWA) and Water Environment Federation (WEF), New York, p 1360

    Google Scholar 

  • Ayers RS, Westcot DW (1994) Water quality for agriculture: FAO irrigation and drainage paper 29. Revision. 1, pp 1–130

  • Benkheil J (1989) The origin and evolution of the Cretaceous Benue Trough, Nigeria. J Afr Earth Sci 8:251–282

    Article  Google Scholar 

  • Dessauvagie TFJ (1974) Geological Map of Nigeria: Scale 1: 1,000,000. Nigeria Mining Geology Metallurgical Society, Lagos

    Google Scholar 

  • Doneen LD (1964) Water quality for agriculture. Department of irrigation, University of California, Davis, p 4

    Google Scholar 

  • Eaton FM (1950) Significance of carbonates in irrigation waters. Soil Sci 39:123–133

    Article  Google Scholar 

  • Ede CO, Nnabo PN (2015) Hydrogeochemical evaluation of groundwater quality of Abakaliki and its environs, south eastern Nigeria. Int J Innov Sci Res 13(2):689–696

    Google Scholar 

  • Eyankware MO (2016) Hydrochemical appraisal of groundwater for irrigation purpose: a case study of Ekaeru Inyimagu and its Adjoining area, Ebonyi State, Nigeria. Indian J Sci 23(88):924–943

    Google Scholar 

  • Eyankware MO (2017) Groundwater hydrogeochemical evaluation for irrigation purposes in limestone mining areas of Umuoghara near Abakaliki SE. Nigeria. Sci Technol 3(9):1–19

    Google Scholar 

  • Eyankware MO, Nnabo PN, Omo-Irabor OO, Selemo OI (2016a) Assessment of the effect of anthropogenic activities on hydrogeochemical quality of water resources of Ekaeru Inyimagu and its environs, southeastern, Nigeria. Sky J Soil Sci Environ Manag Niger 5(5):33–43

    Google Scholar 

  • Eyankware MO, Obasi PN, Akakuru OC (2016b) Use of hydrochemical approach in evaluation of water quality around the vicinity of Mkpuma Ekwaoku mining district, Ebonyi state, SE. Nigeria for irrigation purpose. Indian J Sci 23(88):881–895

    Google Scholar 

  • Ezeh VO, Eyankware MO, Irabor OO, Nnabo PN (2016) Hydrochemical evaluation of water resources in Umuoghara and its environs, near Abakaliki, South Eastern Nigeria. Int J Sci Healthc Res. 1(2):23–31

    Google Scholar 

  • Fatoye FB, Gideon BY (2013) Geology and occurrence of Limestone and marble in Nigeria. J Nat Sci Res 3(11):60–65

    Google Scholar 

  • Fayose EA, De Klasz I (1976) Microfossils of the Eze Aku formation (Turonian) at Nkalagu quarry eastern Nigeria. Niger J Min Geol 13:51–61

    Google Scholar 

  • Hem JD (1985) Study and interpretation of the chemical characteristics of natural water, 3rd edn. U.S. Geological Survey Water-supply Paper 2254

  • Hounslow AW (1995) Water quality data: analysis and interpretation. CRS press, Inc. Lewis publishers, Boca Raton, p 397

    Google Scholar 

  • Igbozuruike MU (1975) Vegetation Types. In: Oformata GEK (ed) Nigeria in maps, eastern state. Ethiope Publ, Benin, pp 30–31

    Google Scholar 

  • Ikhane PR, Folorunso AF, Nton ME, Oluwalaanu JA (2009) Evaluations of Turonian limestone formation exposed at NIGERCEM quarry, Nkalagu, southeastern Nigeria: a geochemical approach. Pac J Sci Technol 10(2):763–771

    Google Scholar 

  • Kelly WP (1963) Use of saline irrigation water. Soil Sci 95(4):355–391

    Google Scholar 

  • Ketata M, Gueddari M, Bouhlila R (2011) Suitability assessment of shallow and deep groundwaters for drinking and irrigation use in the El Khairat aquifer (Enfidha, Tunisian Sahel). Environ Earth Sci. https://doi.org/10.1007/s12665-011-1091-z

    Google Scholar 

  • Moses OE, Ruth OE (2015) Environmental degradation on land in Enyigba with reference to Artisan Lead–Zinc miner in south eastern Nigeria. J Multidiscip Sci Res 3(3):32–34

    Google Scholar 

  • Nwachukwu SO (1972) Tectonic evolution of the southern portion of the Benue trough, Nigeria. Geol Mag 109:411–419

    Article  Google Scholar 

  • Nwajide CS (1990) Cretaceous sedimentation and paleogeography of the central Benue trough. In: Ofoegbu CO (ed) The Benue trough structure and evolution international monograph series. Vieweg and Sohne Verlag, Braunschweig and Wiesbaden, Germany, pp 19–38

  • Obasi PN, Eyankware MO, Akudinobi BBE, Nweke MO (2015) Hydrochemical investigation of water resources around Mkpuma Ekwaoku mining district, Ebonyi state southeastern Nigeria. Afr J Geo Sci Res 3(3):01–07

    Google Scholar 

  • Odukwe GC (1980) Industrial minerals of Nigeria. In: Proceedings 4th Industrial Minerals International Congress Atlanta, London, pp 103–108

  • Offodile ME (1976) A review of the geology of the cretaceous of the Benue valley. In: Kogbe CA (ed) Geology of Nigeria. Elizabeth Publishing Co., Lagos, pp 319–330

    Google Scholar 

  • Ojobo JR, Nnabo PN (2015) Levels of heavy metals on groundwater in Abakaliki and its environs, southeastern Nigeria. Int J Innovation Sci Res 12(2):444–452

    Google Scholar 

  • Oko GO (2002) The Nigeria cement company Plc., Nkalagu Ebonyi State, Re-evaluation of Limestone Reserve in NIGERCEM Leases, 19804, 9806, 9809

  • Petters SW (1982) Central West African Cretaceous-Tertiary benthic foramnifera and stratigraphy. Paleogeographica 179:1–104

    Google Scholar 

  • Petters SW (1991) Regional geology of Africa. In: Lecture notes in earth sciences series, vol 40. Springer, Berlin, Heidelberg

  • Piper AM (1944) A graphic procedure in the geochemical interpretation of water analyses. Trans Am Geophys Union 25:914–923

    Article  Google Scholar 

  • Raghunath IIM (1987) Groundwater, 2nd edn. Wiley, New Delhi, pp 344–369

    Google Scholar 

  • Reyment RA (1965) Aspects of geology of Nigeria. Ibadan Univ. Press, Ibadan, p 145

    Google Scholar 

  • Richards LA (ed) (1969) Diagnosis and improvement of saline and alkali soils. In: United States salinity laboratory staff. Agricultural handbook no. 60. The United States Government Printing Office, Washington DC

  • Sawyer CN, McCarty PL (1967) Chemistry for sanitary engineers, 2nd edn. McGraw-Hill, New York, p 518

    Google Scholar 

  • Spectrum Analytic Inc. Guide to interpreting irrigation water analysis, Washington C.H. www.spectrumanalytic.com

  • Thakur T, Rishi MS, Naik PK, Sharma P (2016) Elucidating hydrochemical properties of groundwater for drinking and agriculture in parts of Punjab, India. Environ Earth Sci 75:467

    Article  Google Scholar 

  • Todd DK (1980) Groundwater hydrology, 2nd edn. Wiley, New York

    Google Scholar 

  • Umeji AC (2000) Evolution of the Abakaliki and the Anambra sedimentary basins, Southeastern Nigeria. A report submitted to the shell petroluem development company Nigeria, Limited

  • Wilcox LV (1955) Classification and use of irrigation water. USDA, Circular, Washington, DC, USA, p 96

    Google Scholar 

Download references

Acknowledgements

The authors sincerely and graciously acknowledge Prof. Gunter Dörhöfer, Editor-in-Chief, Environmental Earth Science, for his valuable suggestions in improving the manuscript. The anonymous reviewers are also appreciated for their fruitful and constructive suggestions in bringing the manuscript to its present form.

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Correspondence to C. G. Aleke.

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Eyankware, M.O., Nnajieze, V.S. & Aleke, C.G. Geochemical assessment of water quality for irrigation in abandoned limestone quarry pit at Nkalagu area, southern Benue Trough, Nigeria. Environ Earth Sci 77, 66 (2018). https://doi.org/10.1007/s12665-018-7232-x

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