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Cerium-tannic acid passivation treatment on galvanized steel

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Abstract

A novel cerium-tannic acid passivation treatment was performed on galvanized steel. The corrosion resistance of cerium-tannic passivated samples was tested by dropping test with 0.5 wt.% CuSO4 aqueous solution. The mass loss per unit area of passivated samples was measured after the corrosion in 0.5 mol/L NaCl + 0.005 mol/L H2SO4 at room temperature for 96 h. The electrochemical behaviors of cerium, tannic acid, and cerium-tannic acid passivated samples on galvanized steel in 0.5 mol/L NaCl solution were investigated by polarization curves and electrochemical impendence spectra. The corrosion equivalent circuit was established according to the impedance characteristics. The results show that cerium-tannic acid treated samples exhibit better corrosion resistance than the sole cerium or tannic acid treated samples under the same condition. The mechanism of synergistic effect for cerium-tannic acid passivation on galvanized steel was discussed.

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References

  1. Lunder O., Walmsley J.C., Mack P., and Nisancioglu K., Formation and characterisation of a chromate conversion coating on AA6060 aluminium, Corros. Sci., 2005, 47: 1604.

    Article  CAS  Google Scholar 

  2. Hao J.J., An C.Q., and Mou S.H., Advances in research on unchromium passivation of galvanized zinc layer, Mater. Rev., 2003, 9(17): 19.

    Google Scholar 

  3. Tang T. and Beth-Nielsen G., Molybdate-based alternatives to chromating as a passivation treatment for zinc, Plat. Surf. Finish., 1994, 18(11): 20.

    Google Scholar 

  4. Wang D. and Tang X., A study of the film formation kinetics on zinc in different acidic corrosion inhibitor solutions by quartz crystal microbalance, Corros. Sci., 2005, 9(47): 2157.

    Article  MathSciNet  Google Scholar 

  5. Bexell U. and Grehk T.M., A corrosion study of hot-dip galvanized steel sheet pre-treated with γ-mercaptopropyltrimethoxysilane, Surf. Coat. Technol., 2007, 201: 4734.

    Article  CAS  Google Scholar 

  6. Deflorian F., Rossi S., Fedrizzi L., and Bonora P.L., EIS study of organic coating on zinc surface pretreated with environmentally friendly products, Prog. Org. Coat., 2005, 52: 271.

    Article  CAS  Google Scholar 

  7. Aramaki K. The effect of medication with hydrogen peroxide on a hydrated cerium (III) oxide layer for protection of zinc against corrosion in 0.5 M NaCl, Corros. Sci., 2006, 48(16): 766.

    Article  CAS  Google Scholar 

  8. Hinton B.R.W. and Wilson L., The corrosion inhibition of zinc with cerous chloride, Corros. Sci., 1989, 29(9): 967.

    Article  CAS  Google Scholar 

  9. Roman L., Blidariu M., and Cristescu C., Study of conversion coating on zinc deposition obtained from low pollution solutions, Trans. IMF, 1997, 75: 324.

    Google Scholar 

  10. Hiromasa S. and Masao S., Surface Treated Metallic Materials with Corrosion Resistance and Surface Treatment Used therefore, USA patent, WO 28291, 1996.

  11. Takao O., Surface Treatment Agent for Zinciferous-Plated Steel, USA patent, 5846342, 1998.

  12. Jaen J.A., Arauz E.Y., Iglesias J., and Delgado Y., Reactivity of tannic acid with common corrosion products and its influence on the hydrolysis of iron in alkaline solutions, Hyperfine Interact., 2003, 148/149: 199.

    Article  ADS  CAS  Google Scholar 

  13. Iglesias J., Saldana E.G.D., and Jaen J.A., On the tannic acid interaction with metallic iron, Hyperfine Interact., 2001, 134: 109.

    Article  ADS  CAS  Google Scholar 

  14. Al-Mayouf A.M., Inhibitors for chemical cleaning of iron with tannic acid, Desalination, 1999, 121(2): 173.

    Article  CAS  Google Scholar 

  15. Mu G.N. and Liu G.H., The synergistic inhibition effect of Y(III) ion and polyethlene glycol mono-(p) octyl phenyl ether (OP) on corrosion of zinc, Corros. Prot. (in Chinese), 2002, 23(2): 51.

    CAS  MathSciNet  Google Scholar 

  16. Rajendran S., Apparao B.V, and Palaniswamy N., Synergistic and antagonistic effects existing among polyacrylamide phenyl phosphonate and Zn2+ on the inhibition of corrosion of mild steel in a neutral aqueous environment, Electrochem. Acta, 1998, 44: 533.

    Article  CAS  Google Scholar 

  17. Yang L., Liu G., Qian Y., and Du N., Electrochemical behavior of the cerium passivating film on galvanized steel, Surf. Technol. (in Chinese), 2006, 35(6): 11.

    CAS  Google Scholar 

  18. Geary M., and Breslin C.B., The influence of chromate and cerium passivation treatments on the dissolution of Sn/Zn coating, Corros. Sci., 1997, 39: 1341.

    Article  CAS  Google Scholar 

  19. Aramaki K., The inhibition effects of chromate-free, anion inhibitors on corrosion of zinc in aerated 0.5 M NaCl, Corros. Sci., 2001, 43: 591.

    Article  CAS  Google Scholar 

  20. Wang J. and Fang J., Chemical conversion film of the mixed rare earth on zinc deposit, J. Chin. Rare Earth Soc. (in Chinese), 1997, 15(1): 31.

    Google Scholar 

  21. Philip A. and Schweitzer P.E., Corrosion Technology, Marcel Dekker Inc., New York, 2003: 287.

    Google Scholar 

  22. Kapel M. and Karunanithy R., The determination of tannins with cerium(IV) sulphate, Analyst, 1974, 99: 661.

    Article  PubMed  ADS  CAS  Google Scholar 

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Correspondence to Guangming Liu.

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Liu, G., Yu, F., Yang, L. et al. Cerium-tannic acid passivation treatment on galvanized steel. Rare Metals 28, 284–288 (2009). https://doi.org/10.1007/s12598-009-0056-9

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  • DOI: https://doi.org/10.1007/s12598-009-0056-9

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