Abstract
Surface water samples were collected from 21 sampling sites throughout the Subarnarekha River during pre-monsoon, monsoon and post-monsoon seasons. The concentrations of Al, As, Ba, Cr, Co, Cu, Fe, Mn, Ni, Se, V and Zn were determined using inductively coupled plasma-mass spectrometry for seasonal fluctuation, source apportionment and heavy metal pollution indexing. The results demonstrated that concentrations of the metals showed significant seasonality and most variables exhibited higher levels in the pre-monsoon season. Principal component analysis outcome of four factors together explained 73.13 % of the variance with \(>\)1 initial Eigenvalue indicating both innate and anthropogenic activities as contributing factors of metal profusion in the river. To assess the composite influence of all the considered metals on the overall quality of the water, heavy metal pollution indices were calculated. The HPI for surface water of the river considering all the seasons and locations was 32.27. The HPI of the river calculated for the individual locations showed great variations ranging from 3.55 to 388.9. All the locations fall under low to medium classes of HPI except few locations which are under the influence of industries, mining or near the estuary. The enhanced concentrations of certain metals in the Subarnarekha River near industrial and mining establishments may be attributed to anthropogenic contribution from the industrial and mining activities of the area.
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References
Adaikpoh EO, Nwajei GE, Ogala JE (2005) Heavy metals concentrations in coal and sediments from river Ekulu in Enugu, Coal City of Nigeria. J Appl Sci Environ Manag 9(3):5–8
Ahmad MK, Islam S, Rahman S, Haque MR, Islam MM (2010) Heavy metals in water, sediment and some fishes of Buriganga River, Bangladesh. Int J Environ Res 4(2):321–332
Akoto O, Bruce TN, Darko G (2008) Heavy metals pollution profiles in streams serving the Owabi reservoir. Afr J Environ Sci Technol 2(11):354–359
Alimonti A, Petrucci F, Krachler M et al (2000) Reference values for chromium, nickel and vanadium in urine of youngsters from the urban area of Rome. J Environ Monit 2(4):351–354
Alloway BJ (1990) Soil processes and the behaviour of metals. In: Alloway BJ (ed) Heavy metals in soils. Blackie, London, pp 11–37
Amadi AN (2011) Assessing the Effects of Aladimma dumpsite on soil and groundwater using water quality index and factor analysis. Aust J Basic Appl Sci 5(11):763–770
Ammann AA, Michalke B, Schramel P (2002) Speciation of heavy metals in environmental water by ion chromatography coupled to ICP-MS. Anal Bioanal Chem 372(3):448–452
Avudainayagam S, Megharaj M, Owens G et al (2003) Chemistry of chromium in soils with emphasis on tannery waste sites. Rev Environ Contam Toxicol 178:53–91
ATSDR (2000) Agency for Toxic Substances and Disease Registry. Toxicological Profile for Chromium. U.S. Department of Health and Human Services, Washington
ATSDR (2008) Agency for Toxic Substances and Disease Registry. Draft Toxicological Profile for Manganese. U.S. Department of Health and Human Services, Atlanta
Barceloux DG (1999) Cobalt. Clin Toxicol 37:201–216
Bellos D, Swaidis T (2005) Chemical pollution monitoring of the River Pinios Thessalia-Greece. J Environ Manag 76:282–292
Bengraine K, Marhaba TF (2003) Using principal component analysis to monitor spatial and temporal changes in water quality. J Hazard Mater 100:179–195
Bharti N, Katyal D (2011) Water quality indices used for surface water vulnerability assessment. Int J Ecol Environ Sci 2(1):154–173
Bogradi E (1971) The Vanadium content of Hungarian bauxites and its utilization. In: Proc of the 2nd international symposium of ICSOBA, vol 3, pp 349–358
Brown RM, McClelland NI, Deininger RA, Tozer RG (1970) A water quality index—do we dare? Water Sew Works 117(10):339–343
Brown RM, McClelland NI, Deininger RA, O’Connor M (1971) A water quality index–crashing the psychological barrier. Presented at 138th meeting of the American Association for the Advancement of Science, Philadelphia, PA
Cidu R, Biddau R (2007) Transport of trace elements under different seasonal conditions: effects on the quality of river water in a Mediterranean area. Appl Geochem 22:2777–2794
Connell DW, Miller GJ (1984) Chemistry and ecotoxicology of pollution. Wiley, New York
Cude CG (2001) Oregon water quality index: a tool for evaluating water quality management effectiveness. J Am Water Resour Assoc 37(1):125–137
Curiel A, Garibay MG (2011) Automobiles and the Deterioration of Environmental Health in the City of Guadalajara, Mexico. Epidemiology 22(1):S209
Davis A, Shokouhian M, Ni S (2001) Loading estimates of lead, copper, cadmium and zinc in urban runoff from specific sources. Chemosphere 44:997–1009
Dede OT, Telci IT, Aral MM (2013) The Use of Water Quality Index Models for the Evaluation of Surface Water Quality: A Case Study for Kirmir Basin, Ankara, Turkey. Water Qual Expo Health 5: 41–56
Edet AE, Offiong OE (2002) Evaluation of water quality pollution indices for heavy metal contamination monitoring. A study case from Akpabuyo-Odukpani area, Lower Cross River Basin (southeastern Nigeria). GeoJournal 57:295–304
Elder JF (1988) Metal biogeochemistry in surface water system—a review of principals and concepts. U.S. Geological Survey Circular 1013
Fishbein L (1981) Sources, transport and alterations of metal compounds: an overview. I. Arsenic, beryllium, cadmium, chromium and nickel. Environ Health Perspect 40:43–64
Gerke TL, Scheckel KG, Maynard JB (2010) Speciation and distribution of vanadium in drinking water iron pipe corrosion by-products. Sci Total Environ 408:5845–5853
Hair JF, Anderson RE, Tatham RL, Black WC (1995) Multivariate data analysis with readings, 4th edn. Prentice-Hall, London
Hopke PK, Lamb RE, Natusch DFS (1980) Multielemental characterisation of urban roadway dust. Environ Sci Technol 14:164–172
Horton RK (1965) An index number system for rating water quality. J Water Pollut Control Federation 37(3):300–306
Ikenaka Y, Shouta M, Nakayama M, Muzandu K, Choongo K, Teraoka H, Mizuno N, Ishizuka M (2010) Heavy metal contamination of soil and sediment in Zambia. Afr J Environ Sci Technol 4:729–739
Indian Bureau of Mines (2012) Indian Minerals Yearbook 2011, Part 2, Vanadium, 50th edition, vol 77(2)
Ipeaiyeda AR, Dawodu M (2008) Heavy metals contamination of topsoil and dispersion in the vicinities of reclaimed auto-repair workshops in Iwo, Nigeria. Bull Chem Soc Ethiop 22:339–348
IS (2012) Drinking water specifications 2nd revision. Bureau of Indian Standards (IS 10500: 2012). New Delhi. ftp://law.resource.org/in/bis/S06/is.10500.2012.pdf
Johnson J, Schewel L, Graedel TE (2006) The contemporary anthropogenic chromium cycle. Environ Sci Technol 40:7060–7069
Joung HM, Miller WW, Mahannah CN, Guitjens JC (1979) A generalized water quality index based on multivariate factor analysis. J Environ Qual 8(1):95–100
Juang DF, Lee CH, Hsueh SC (2009) Chlorinated volatile organic compounds found near the water surface of heavily polluted rivers. Int J Environ Sci Technol 6(4):545–556
Kaiser HF (1960) The application of electronic computers to factor analysis. Educ Psychol Meas 20:141–151
Karbassi AR, Monavari SM, Nabi Bidhendi GR, Nouri J, Nematpour K (2008) Metal pollution assessment of sediment and water in the Shur River. Environ Monitor Assess 147(1–3):107–116
Karbassi AR, Nouri J, Ayaz GO (2007) Flocculation of trace metals during mixing of Talar river water with Caspian Seawater. Int J Environ Res 1(1):66–73
Kennedy P, Gadd J (2000) Preliminary examination of inorganic compounds present in tyres, brake pads and road bitumen in New Zealand. Prepared by Kingett Mitchell Ltd for Ministry of Transport, November 2000. Revised October 2003
Khadse GK, Patni PM, Kelkar PS, Devotta S (2008) Qualitative evaluation of Kanhan river and its tributaries flowing over central Indian plateau. Environ Monitor Assess 147(1–3):83–92
Kirkpatrick T (1985) Barium compounds. In: Grayson M, Eckroth D (eds) Kirk–Othmer concise encyclopedia of chemical technology. Wiley, New York, pp 147–148
Landwehr JM (1974) Water quality indices construction and analysis. Ph.D. Thesis, University of Michigan, Ann Arbor
Lantzy RJ, Mackenzie FT (1979) Atmospheric trace metals: global cycles and assessment of man’s impact. Geochim Cosmochim Acta 43:511–525
Lohani BN, Todino G (1984) Water Quality Index for Chao Pharya River. J Environ Eng ASCE 110(6):1163–1176
Loranger S, Zayed J, Forget E (1994) Manganese contamination in Montreal in relation with traffic density. Water Air Soil Pollut 74:385–396
Lumb A, Sharma TC, Bibeault J (2011a) A review of genesis and evolution of Water Quality Index (WQI) and some future directions
Lumb A, Sharma TC, Bibeault J, Klawunn P (2011b) A comparative study of USA and Canadian Water Quality Index models. Water Qual Expo Health 3(3–4):203–216
Malm O, Pfeiffer WC, Fiszman M et al (1988) Transport and availability of heavy metals in the Paraiba do Sul-Guandu River system, Rio de Janeiro state, Brazil. Sci Total Environ 75:201–209
Mirenda RJ (1986) Acute toxicity and accumulation of zinc in the crayfish Orconectes virilis(Hagen). Bull Environ Contam Toxicol 37:387–394
Mohan SV, Nithila P, Reddy SJ (1996) Estimation of heavy metal in drinking water and development of heavy metal pollution index. J Environ Sci Health A 31(2):283–289
Nouri J, Mahvi AH, Babaei A, Ahmadpour E (2006) Regional pattern distribution of groundwater fluoride in the Shush aquifer of Khuzestan County Iran Fluoride. Fluoride 39(4):321–325
Nouri J, Mahvi AH, Jahed GR, Babaei AA (2008) Regional distribution pattern of groundwater heavy metals resulting from agricultural activities. Environ Geol 55(6):1337–1343
Nriagu JO (1989) A global assessment of natural sources of atmospheric trace metals. Nature 338:47–49
Nriagu JO, Pacyna JM (1988) Quantitative assessment of worldwide contamination of air, water and soils by trace metals. Nature 333:134–139
Olias M, Nieto JM, Sarmiento AM, Ceron JC, Canovas CR (2004) Seasonal water quality variations in a river affected by acid mine drainage: the Odiel River (South West Spain). Sci Total Environ 333:267–281
Ouyang Y, Nkedi-Kizza P, Wu Q, Shinde D, Huang C (2006) Assessment of seasonal variations in surface water quality. Water Res 40:3800–3810
Prasad B, Bose JM (2001) Evaluation of heavy metal pollution index for surface and spring water near a limestone mining area of the lower Himalayas. Environ Geol 41:183–188
Radojevic M, Bashkin VN (1999) Practical environmental analysis. Royal Society of Chemistry, London
Reddy SJ (1995) Encyclopaedia of environmental pollution and control, vol 1. India, Environmental Media, Karlia, p 342
Rim-Rukeh A, Ikhifa OG, Okokoyo AP (2006) Effects of agricultural activities on the water quality of Orogodo River, Agbor Nigeria. J Appl Sci Res 2(5):256–259
Sarkar C, Abbasi SA (2006) Qualidex—a new software for generating water quality index. Environ Monit Assess 119:201–231
Sekabira K, Oryem-Origa H, Basamba TA, Mutumba G, Kakudidi E (2010) Assessment of heavy metal pollution in the urban stream sediments and its tributaries. Int J Environ Sci Technol 7(3):435–446
Sharma S (1996) Applied multivariate techniques. Wiley, New York
Simeonov V, Stratis JA, Samara C, Zachariadis G, Voutsa D, Anthemidis A (2003) Assessment of the surface water quality in northern Greece. Water Res 37:4119–4124
Singh KP, Malik A, Mohan D, Sinha S (2004) Multivariate statistical techniques for the evaluation of spatial and temporal variations in water quality of Gomti River (India)-a case study. Water Res 38:3980–3992
Stokinger HE (1981) Barium, Ba. In: Clayton CD, Clayton FE (eds) Patty’s industrial hygiene and toxicology, vol 2A, 3rd edn. Wiley, New York, pp 1531–1537
Tahri M, Benyaich F, Bounakhla M, Bilal E, Gruffat JJ, Moutte J (2005) Multivariate analysis of heavy metal contents in soils, sediments and water in the region of Meknes (Central Morocco). Environ Monit Assess 102:405–417
Tiwari TN, Mishra MA (1985) Preliminary assignment of water quality index to major Indian rivers. Ind J Environ Prot 5(4):276–279
USEPA (1980) Exposure and risk assessment for zinc. Office of Water Regulations and Standards (WH-553). EPA440481016. PB85212009. U.S. Environmental Protection Agency, Washington.
USEPA (2002) U.S. Environmental Protection Agency’s (USEPA) National Center for Environmental Assessment (NCEA) document entitled “Risk Assessment Issue Paper for: Derivation of a Provisional RfD for Cobalt and Compounds,” CASRN 7440-48-4. U.S. Environmental Protection Agency, Washington
USEPA (2003) Health effects support document for manganese. EPA822R03003. U.S. Environmental Protection Agency, Washington
USEPA (2006) National recommended water quality criteria, Office of Water, EPA-822-R-02-047. U.S. Environmental Protection Agency, Washington
USEPA (2009) National Primary Drinking water regulations. Federal register, EPA816-F-09-004. U.S. Environmental Protection Agency, Washington
Vega M, Pardo R, Barrado E, Deban L (1998) Assessment of seasonal and polluting effects on the quality of river water by exploratory data analysis. Water Res 32:3581–3592
Venugopal T, Giridharan L, Jayaprakash M (2009) Characterization and risk assessment studies of bed sediments of River Adyar—an application of speciation study. Int J Environ Res 3(4):581–598
WHO (1986) Diseases caused by manganese and its toxic compounds. Early detection of occupational diseases. World Health Organization, Geneva, pp 69–73
WHO (2006) Guidelines for drinking-water quality, 3rd edn. World Health Organization, Geneva
Wong CSC, Li XD, Zhang G, Qi SH, Peng XZ (2003) Atmospheric deposition of heavy metals in the Pearl River Delta. China. Atmos Environ 37(6):767–776
Wunderlin DA, Días MP, Amémaría V, Pesce SF, Hued AC, Bistoni MÁ (2001) Pattern recognition techniques for the evaluation of spatial and temporal variations in water quality. A case study: Suquia river basin (Cordoba-Argentina). Water Res 35:2881–2894
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The authors are grateful to Department of Science and Technology, Government of India, for providing the necessary funding under the Fast Track Young Scientist Scheme {Grant No. SR/FTP/ES-185/2010 (G)} for the study. Also, the authors are thankful to the Director and Geo-Environment Division (EMG), Central Institute of Mining and Fuel Research, Dhanbad for providing the necessary laboratory facilities and other logistic support for the study.
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Giri, S., Singh, A.K. Assessment of Surface Water Quality Using Heavy Metal Pollution Index in Subarnarekha River, India. Water Qual Expo Health 5, 173–182 (2014). https://doi.org/10.1007/s12403-013-0106-2
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DOI: https://doi.org/10.1007/s12403-013-0106-2