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Synthesis, properties and supramolecular structure of piperazinediium thiosulfate monohydrate+

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Abstract

Aqueous reaction of ammonium thiosulfate with piperazine (pip) results in the formation of the title compound (pipH2)[S2O3]∙H2O 1 (pipH2 = piperazinediium) in good yield. 1 was characterized by elemental analysis, IR, Raman and NMR spectra, X-ray powder pattern and its structure was determined. On heating at 100°C, 1 transforms to anhydrous piperazinediium thiosulfate 2, which can be rehydrated to the monohydrate on exposure to moisture. The structure of 1 consists of two crystallographically independent piperazinediium (pipH2)2+ cations located on inversion centers, a thiosulfate anion and a lattice water. The organic cations, thiosulfate anion and lattice water are linked by six varieties of hydrogen bond namely O–H∙∙∙O, O–H∙∙∙S, N–H∙∙∙O, N–H∙∙∙S, C–H∙∙∙O and C–H∙∙∙S, leading to the formation of alternating layers of (pipH2)2+ cations and water linked thiosulfate chains. A comparative study of several compounds charge balanced by the piperazinediium cation is described.

The synthesis, properties and supramolecular structure of piperazinediium thiosulfate monohydrate are described.

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Acknowledgements

The authors thank Dr. Sam P de Visser, University of Manchester and Dr. Devesh Kumar, Indian Institute of Chemical Technology (IICT), Hyderabad for helpful discussions. Financial support under the Special Assistance Programme [F.540/25/DRS/2007/(SAP-I)] of University Grants Commission (UGC), New Delhi is gratefully acknowledged.

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Authors and Affiliations

  1. Department of Chemistry, Goa University, Goa, 403 206, India

    Bikshandarkoil R Srinivasan, Ashish R Naik & Sunder N Dhuri

  2. Institut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Max-Eyth Straße 2, D-24118, Kiel, Germany

    Christian Näther & Wolfgang Bensch

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  1. Bikshandarkoil R Srinivasan
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  2. Ashish R Naik
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  3. Sunder N Dhuri
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  4. Christian Näther
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  5. Wolfgang Bensch
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Correspondence to Bikshandarkoil R Srinivasan.

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+Dedicated to Prof. Dr. P.T. Manoharan on the occasion of his 75th birthday

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Srinivasan, B.R., Naik, A.R., Dhuri, S.N. et al. Synthesis, properties and supramolecular structure of piperazinediium thiosulfate monohydrate+ . J Chem Sci 123, 55–61 (2011). https://doi.org/10.1007/s12039-011-0064-9

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