Skip to main content
Log in

Effects of Zr Additions on the Microstructure and the Mechanical Behavior of PM Mo-Si-B Alloys

  • Published:
JOM Aims and scope Submit manuscript

Abstract

In this article, our current understanding on the effects of Zr additions on the properties of three-phase Mo-Si-B alloys is reported. This novel group of materials having high melting points around 2000°C have been identified as potential alloy systems for structural applications at temperatures beyond 1200°C, e.g., for substituting or supplementing state-of-the-art nickel-base superalloys in the power generation industry. In earlier work, we developed various Mo-Si-B materials with very good high-temperature deformation behavior and, in addition, that satisfy oxidation performance. Minimum brittle-to-ductile transition temperatures of around 950°C, however, do not meet the requirements for high-grade stressed structural materials. Therefore, in a second trial, we investigate the influence of the alloying element Zr (which was already proven to increase the strength as well as the ductility of a single-phase Mo-Si alloy) on three-phase Mo-Si-B alloys.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  1. D.M. Berczik, U.S. patents 5,595,616 and 5,693156 (1997).

  2. T.A. Parthasarathy, M. Mendiratta, and D.M. Dimiduk, Acta Mater. 50, 1857 (2002).

    Article  Google Scholar 

  3. J.A. Lemberg, M.R. Middlemas, T. Weingärtner, B. Gludovatz, J.K. Chochran, and R.O. Ritchie, Intermetallics 20, 141 (2012).

    Article  Google Scholar 

  4. M. Krüger, S. Franz, H. Saage, M. Heilmaier, J.H. Schneibel, P. Jéhanno, M. Böning, and H. Kestler, Intermetallics 16, 933 (2008).

    Article  Google Scholar 

  5. O. Hassomeris, G. Schumacher, M. Krüger, M. Heilmaier, and J. Banhart, Intermetallics 19, 470 (2011).

    Article  Google Scholar 

  6. M. Krüger, P. Jain, K.S. Kumar, M. Heilmaier, M. Böning, and H. Kestler, J. Phys. Conf. Series 240, 012087 (2010).

    Article  Google Scholar 

  7. M. Krüger, P. Jain, K.S. Kumar, and M. Heilmaier, unpublished work.

  8. C.B. Geller, R.W. Smith, J.E. Hack, P. Saxe, and E. Wimmer, Scripta Mater. 52, 205 (2005).

    Article  Google Scholar 

  9. H. Saage, M. Krüger, D. Sturm, M. Heilmaier, J.H. Schneibel, E.P. George, L. Heatherly, Ch Somsen, G. Eggeler, and Y. Yang, Acta Mater. 57, 3895 (2009).

    Article  Google Scholar 

  10. J.H. Schneibel, R.O. Ritchie, J.J. Kruzik, and P.F. Tortorelli, Metall. Mater. Trans. A 36A, 525 (2005).

    Article  Google Scholar 

  11. L. Northcott, Molybdenum - Metallurgy of the Rarer Metals - 5 (New York: Academic Press, 1956).

    Google Scholar 

  12. J.H. Schneibel, C.T. Liu, D.S. Easton, and M.C.A. Carmichael, Mater. Sci. Eng., A 261, 78 (1999).

    Article  Google Scholar 

  13. A. Guha, Metals Handbook: Mechanical Testing, Vol. 8 (Materials Park, OH: American Society for Metals, 1985), p. 132.

    Google Scholar 

  14. C. Hochmuth, R. Völkl, and U. Glatzel, University Bayreuth, unpublished research, 2012.

  15. P.M. Hazzledine, Scripta Metall. Mater. 26, 57 (1992).

    Article  Google Scholar 

  16. J.H. Schneibel, M. Heilmaier, W. Blum, G. Hasemann, and T. Shanmugasundaram, Acta Mater. 59, 1300 (2011).

    Article  Google Scholar 

  17. M. Heilmaier, M. Krüger, and H. Saage, Mater. Sci. Forum 633–634, 549 (2010).

    Google Scholar 

  18. P. Jéhanno, M. Heilmaier, H. Saage, M. Böning, H. Kestler, J. Freudenberger, and S. Drawin, Mater. Sci. Eng., A 463, 216 (2007).

    Article  Google Scholar 

  19. S. Burk, B. Gorr, M. Krüger, M. Heilmaier, and H.-J. Christ, JOM 63 (12), 32 (2011).

    Article  Google Scholar 

Download references

Acknowledgements

This research was partly supported by the German Science Foundation (DFG) within the framework of the research unit 727 “Beyond Nickelbase Superalloys.” We thank the members of this research unit (U. Glatzel, R. Völkl, C. Hochmuth, G. Eggeler, C. Somsen, and T. Depka) for fruitful cooperation and Plansee SE (Reutte, Austria) for help in compaction of the mechanically alloyed powders.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to D. Schliephake.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Krüger, M., Schliephake, D., Jain, P. et al. Effects of Zr Additions on the Microstructure and the Mechanical Behavior of PM Mo-Si-B Alloys. JOM 65, 301–306 (2013). https://doi.org/10.1007/s11837-012-0475-1

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11837-012-0475-1

Keywords

Navigation