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Properties of a new dental photocurable resin based on the expanding monomer and three-component photoinitiator system

  • Biomaterials
  • Published:
Journal of Wuhan University of Technology-Mater. Sci. Ed. Aims and scope Submit manuscript

Abstract

The purpose of this study was to use a three-component photoinitiation system comprising 1wt% CQ (camphorquinone), 2wt% DMAEMA (2-(dimethylamino) ethyl meth acrylate) and 2wt% Ph2I+PF6 − (diphenyliodonium hexafluorophosphate) to initiate the copolymerization of the matrix resins which combine bisphenol-S-bis (3-methacrylate-2-hydroxy propyl) ether (BisS-GMA) with the expanding monomer unsaturated spiro orthoesters 2-methylene-1,4,6-trispiro[4,4] nonane (MTOSN), for minimizing the volumetric shrinkage that generally occurs during polymerization. It was hypothesized that MTOSN would expand volumetrically during polymerization under the three-component photoinitiator system and further reductions in volumetric shrinkage would be obtained. The performance study which consists of degree of conversion and condition of the ring-opening reactions of MTOSN, volumetric shrinkage and mechanical properties including tensile bond strength, compressive strength and Vicker’s hardness were carried out respectively by Fourier transfer infrared, the dilatometer and the universal testing machine. The results supported that the dental composites based on the expanding monomer and three-component photoinitiator system engendered a greater decrease of volumetric shrinkage and better mechanical properties.

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Authors and Affiliations

  1. State Key Laboratory of Oral Diseases, West China Hospital of Stomatology, Sichuan University, Chengdu, 610041, China

    Jing Fu  (付静), Wenjia Liu, Xiaoqing Liu & Hang Wang  (王航)

  2. Department of Prosthodontics, West China College of Stomatology, Sichuan University, Chengdu, 610041, China

    Jing Fu  (付静), Wenjia Liu, Sapna Laxmi Tuladhar, Qianbing Wan & Hang Wang  (王航)

Authors
  1. Jing Fu  (付静)
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  2. Wenjia Liu
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  3. Xiaoqing Liu
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  4. Sapna Laxmi Tuladhar
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  5. Qianbing Wan
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  6. Hang Wang  (王航)
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Corresponding author

Correspondence to Hang Wang  (王航).

Additional information

Funded by the National Natural Science Foundation of China (No.50673065)

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Fu, J., Liu, W., Liu, X. et al. Properties of a new dental photocurable resin based on the expanding monomer and three-component photoinitiator system. J. Wuhan Univ. Technol.-Mat. Sci. Edit. 29, 384–390 (2014). https://doi.org/10.1007/s11595-014-0926-3

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  • DOI: https://doi.org/10.1007/s11595-014-0926-3

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