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Hybrid photocatalytic membranes embedding decatungstate for heterogeneous photooxygenation

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The incorporation of decatungstate in polymeric membranes provides new heterogeneous photocatalysts for the oxidation of organic substrates under oxygen atmosphere at 25 °C. Photocatalytic membranes have been prepared yielding polymeric films with a high thermal, chemical and mechanical stability (PVDF, PDMS, Hyflon). Surface spectroscopy techniques including transmittance and reflectance UV-Vis and FT-IR have been used to assess the photocatalyst integrity within the polymeric support. Catalyst screening has been performed under both homogeneous and heterogeneous photooxygenation conditions. The photocatalyst activity has been evaluated in terms of the substrate conversion, turnover numbers, and recycling experiments. A membrane induced selectivity behavior has been evidenced by comparison with homogeneous oxidations.

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Authors and Affiliations

  1. ITM-CNR and Department of Chemical Sciences, University of Padova, Via Marzolo, 1, 35131, Padova, Italy

    Marcella Bonchio, Mauro Carraro, Martino Gardan & Gianfranco Scorrano

  2. ITM-CNR, University of Calabria, Via P. Bucci, Cubo 17C, 87030, Rende (CS), Italy

    Enrico Drioli & Enrica Fontananova

Authors
  1. Marcella Bonchio
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  2. Mauro Carraro
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  3. Martino Gardan
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  4. Gianfranco Scorrano
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  5. Enrico Drioli
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  6. Enrica Fontananova
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Corresponding authors

Correspondence to Marcella Bonchio or Mauro Carraro.

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Bonchio, M., Carraro, M., Gardan, M. et al. Hybrid photocatalytic membranes embedding decatungstate for heterogeneous photooxygenation. Top Catal 40, 133–140 (2006). https://doi.org/10.1007/s11244-006-0115-5

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