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Synthesis and transformations of metallacycles 38. The Cp2ZrCl2-catalyzed cyclometallation of α,ω-diynes upon the action of RMgR’ or R n AlCl3−n

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Abstract

The Cp2ZrCl2-catalyzed cyclometallation of α,ω-alkadiynes upon the action of RMgR’ or R n AlCl3−n was accomplished to yield unsaturated di- and tricyclic (magnesa)aluminacarbocycles in up to 85% yield.

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Authors and Affiliations

  1. Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, 141 prosp. Oktyabrya, 450075, Ufa, Russian Federation

    V. A. D’yakonov, R. A. Tuktarova & U. M. Dzhemilev

Authors
  1. V. A. D’yakonov
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  2. R. A. Tuktarova
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  3. U. M. Dzhemilev
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Corresponding author

Correspondence to V. A. D’yakonov.

Additional information

For Part 37, see Ref. 1.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1607–1613, August, 2011.

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D’yakonov, V.A., Tuktarova, R.A. & Dzhemilev, U.M. Synthesis and transformations of metallacycles 38. The Cp2ZrCl2-catalyzed cyclometallation of α,ω-diynes upon the action of RMgR’ or R n AlCl3−n . Russ Chem Bull 60, 1633–1639 (2011). https://doi.org/10.1007/s11172-011-0244-2

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  • DOI: https://doi.org/10.1007/s11172-011-0244-2

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