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Modification of kaolinite with alkylimidazolium salts

Nanocomposites with tunable d-spacing and thermal stability

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Abstract

We have demonstrated that the d-spacing and thermal stability of the alkylimidazolium intercalated kaolinite compounds can be controlled by adjusting chain length of the alkyl groups. The composites were synthesized by displacement method using selected imidazolium ionic liquids bearing different short alkyl chains as guest molecules. The effects of the length of alkyl side chain on d-spacing and thermal stability of the ionic liquids–kaolinite intercalations were investigated by XRD and TG-DSC. Results revealed that in these composites, increasing the length of alkyl substituent led to larger d-spacing and decreased thermal stability. Temperature was found to have influence on the intercalation ratio but not on the d-spacing of final product. The present study shows an easy way of tailoring the performance of these intercalations via small variation of guest ionic liquids, providing the possibility of finding “species-specific” modifier for fully exfoliated nanocomposites.

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Acknowledgements

Sincere thanks are due to anonymous reviewers for their careful and critical comments. We gratefully acknowledge financial support from the National Natural Science Foundation of China (Nos. 41172051 and 21203170). This work was supported by the National College Students’ Innovative Training Program (Nos. 201210491015 and 201410491029), Fundamental Research Founds for National University (No. 1410491B04) and TLOF (Nos. SKJ2012040, SKJ2013011 and SKJ2013019), China University of Geosciences (Wuhan).

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Correspondence to Dawei Meng or Xiuling Wu.

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Yan, Z., Meng, D., Huang, Y. et al. Modification of kaolinite with alkylimidazolium salts. J Therm Anal Calorim 118, 133–140 (2014). https://doi.org/10.1007/s10973-014-4018-6

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  • DOI: https://doi.org/10.1007/s10973-014-4018-6

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