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Extraction properties of 25,27-bis(carbonylmethoxy)calix[4]arenes towards Sr2+: competitive extraction and extraction in a synthetic groundwater

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Abstract

The Sr2+ extraction properties of some 25,27-bis(carbonylmethoxy)calix[4]arenes, in which ester (–CH2CO2Et), keto (–CH2COCH3) and acid functionalities (–CH2CO2H) have been attached to the lower rim, are reported. Strontium ion extraction experiments were performed in a chloroform/water system, and the extraction performance analyzed by radiotracing using the short-lived radio nuclide 85Sr. Effects of pH value, ligand to metal ratio, temperature, extraction time and strontium species on the extraction behavior were examined. It was observed that the 25,27-bis(carboxymethoxy)calix[4]arene derivatives are potent extracting agents towards the strontium ion, showing remarkable extraction performance in competition with a series of organic and inorganic impurities and in a synthetic groundwater. The crystal structure of 25,27-bis(acetonyloxy)calix[4]arene is also reported.

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Acknowledgments

This research project was funded by the Federal Ministry for Education and Research (BMBF) under grant number 02NUK014C. The authors would like to thank Prof. H. Krautscheid (Leipzig University) for providing facilities for X-ray crystallography and X-ray powder diffraction and M. Kischel for performing X-ray powder diffraction analysis. We are also indebted to Dr. H-J. Stärk (Helmholtz Centre for Environmental Research, Leipzig) for performing the ICP-OES measurements. M. Handke is grateful for ESF fellowship.

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Authors and Affiliations

  1. Institut für Anorganische Chemie, Fakultät für Chemie und Mineralogie, Universität Leipzig, Johannisallee 29, 04103, Leipzig, Germany

    Sebastian Haupt, René Schnorr, Marcel Handke & Berthold Kersting

  2. Abteilung Reaktiver Transport, Institut für Ressourcenökologie, Helmholtz-Zentrum Dresden-Rossendorf e.V. (HZDR), Forschungsstelle Leipzig, Permoserstraße 15, 04318, Leipzig, Germany

    Maria Poetsch & Alexander Mansel

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  1. Sebastian Haupt
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  2. René Schnorr
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Correspondence to Berthold Kersting.

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Haupt, S., Schnorr, R., Poetsch, M. et al. Extraction properties of 25,27-bis(carbonylmethoxy)calix[4]arenes towards Sr2+: competitive extraction and extraction in a synthetic groundwater. J Radioanal Nucl Chem 300, 779–786 (2014). https://doi.org/10.1007/s10967-014-3031-3

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  • DOI: https://doi.org/10.1007/s10967-014-3031-3

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