Abstract
The microstructure evolution in several polycrystalline Ni0.6Zn0.4Fe2O4 samples as a result of a sintering scheme was studied in detail, in parallel with the changes in their magnetic properties. The Ni0.6Zn0.4Fe2O4 toroidal sample was prepared via mechanical alloying and subsequent molding; the sample with nanometer-sized compacted powder was repeatedly sintered from 600 to 1200 °C with an increment of 25 °C. An integrated analysis of phase, microstructural and hysteresis data pointed to existence of three distinct shape-differentiated groups of B–H hysteresis loops which belong to samples with weak, moderate and strong magnetism (Idza in Mater. Res. Bull. 47:1345–1352, 2012), respectively. The real permeability, μ′, and loss factor, μ″, increased with grain size which increased due to increase in sintering temperature and these two magnetic properties also seem to belong to three value-differentiated groups corresponding to the same temperature ranges found for the B–H groupings. These groupings are tentatively explained using Snoek’s Law.
Similar content being viewed by others
References
Adam, J.D., Davis, L.E., Dionne, G.F., et al.: Ferrite devices and materials. IEEE Trans. Microw. Theory Tech. 50(3), 721–737 (2002)
Dias, A., Moreira, R.L.: Mater. Lett. 39, 69–76 (1999)
Goldman, A.: Handbook of Modern Ferromagnetic Materials. (1999). Boston/Dordrecht/London
Gul, I.H., Ahmed, W., Maqsood, A.: Electrical and magnetic characterization of nanocrystalline Ni-Zn ferrite synthesis by co-precipitation route. J. Magn. Magn. Mater. 320, 270–275 (2008)
Harris, V.G., Geiler, A., Chen, Y., et al.: Recent advances in processing and applications of microwave ferrites. J. Magn. Magn. Mater. 321(14), 2035–2047 (2009)
Idza, I.R., et al.: Influence of evolving microstructure on magnetic-hysteresis characteristics in polycrystalline nickel–zinc ferrite, Ni0.3Zn0.7Fe2O4. Mater. Res. Bull. 47, 1345–1352 (2012)
Ismail, I.: The transition from paramagnetic to ferromagnetic states as influenced by evolving microstructure of Ni0.5Zn0.5Fe2O4. J. Supercond. Nov. Magn. 25, 71–77 (2012)
Ismail, I., Hashim, M.: Sintering temperature dependence of evolving morphologies and magnetic properties of Ni0.5Zn0.5Fe2O4 synthesized via mechanical alloying. J. Supercond. Nov. Magn. 25, 1551–1561 (2012)
Jiao, X., Chen, D., Hu, Y.: Hydrothermal synthesis of nanocrystalline M x (Zn1−x )Fe2O4 (M=Ni, Mn, Co; x=0.40–0.60) powders. Mater. Res. Bull. 37(9), 1583–1588 (2002)
Košak, A., Makovec, D., Žnidaršič, A., et al.: Preparation of MnZn ferrite with microemulsion technique. J. Eur. Ceram. Soc. 24(6), 959–962 (2004)
Kulikowski, J.: Soft magnetic ferrites—development or stagnation? J. Magn. Magn. Mater. 41(1–3), 56–62 (1984)
Le Floc’h, M., Konn, A.M.: Some of the magnetic properties of polycrystalline soft ferrites: Origins and developments of a model for the description of the quasistatic magnetization. J. Phys. (Paris) 7(1), C1-187-C181-190 (1997)
Nakamura, T.: J. Magn. Magn. Mater. 168, 285 (1997)
Nakamura, T., Okaro, Y.: J. Appl. Phys. 79, 7129 (1996)
Rafferty, A., Prescott, T., Brabazon, D.: Ceram. Int. 34, 15 (2008)
Rodziah, N., et al.: Dependence of developing magnetic hysteresis characteristics on stages of evolving microstructure in polycrystalline yttrium iron garnet. Appl. Surf. Sci. 258, 2679–2685 (2012)
Smit, J., Wijn, H.P.J.: Ferrites. In: Philips Technical Library, pp. 221–245. Eindhovan, Netherlands (1959)
Snoek, J.L.: New Developments in Ferromagnetic Materials. Elsevier, Amsterdam (1947)
Sun, K., Ian, Z., Chen, S., Sun, Y., Yu, Z.: Rare Met. 25, 509 (2006)
Takayama, A., Okuya, M., Kaneko, S.: Spray pyrolysis deposition of NiZn ferrite thin films. Solid State Ion. 172(1–4), 257–260 (2004)
Verma, A., Goel, T.C., Mendiratta, R.G., Alam, M.I.: Mater. Sci. Eng. B 60, 156–162 (1999)
Verma, A., Goel, T.C., Mendiratta, R.G., Gupta, R.G.: J. Magn. Magn. Mater. 192, 271–276 (1999)
Verma, A., Geol, T.C., Mendiratta, R.G.: J. Magn. Magn. Mater. 208, 13–19 (2000)
Verma, A., Goel, T.C., Mendiratta, R.G.: J. Magn. Magn. Mater. 210, 274–278 (2000)
Waje, S.B., Hashim, M., WanYusoff, W.D., Abbas, Z.: Sintering temperature dependence of room temperature magnetic and dielectric properties of Co0.5Zn0.5Fe2O4 prepared using mechanically alloyed nanoparticles. J. Magn. Magn. Mater. 322, 686–691 (2010)
Wang, X., Gui, Y., Wang, Y., Hao, S., Liu, C.: Rare Met. 25, 526 (2006)
Zahi, S., Hashim, M., Daud, A.R.: Synthesis, magnetic properties and microstructure of Ni-Zn ferrite by sol–gel technique. J. Magn. Magn. Mater. 308(2), 177–182 (2007)
Acknowledgement
The authors thank the Faculty of Science and Materials Synthesis and Characterization Laboratory, Institute of Advanced Technology, Universiti Putra Malaysia for their facility to complete this research.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Syazwan Mustaffa, M., Hashim, M., Azis, R.S. et al. Magnetic Phase-Transition Dependence on Nano-to-Micron Grain-Size Microstructural Changes of Mechanically Alloyed and Sintered Ni0.6Zn0.4Fe2 O 4 . J Supercond Nov Magn 27, 1451–1462 (2014). https://doi.org/10.1007/s10948-013-2453-4
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10948-013-2453-4