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Immobilization of palladium on functionalized nanoporous MCM-41 and its application in C–C bond-forming and synthesis of DHQs

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Abstract

A new palladium complex supported on mesoporous silica was successfully prepared by anchoring of 2-amino-3-hydroxy pyridine (2A3HP) on the wall of functionalized MCM-41, then reacted with Pd(OAc)2. This mesporous compound (Pd-2A3HP-MCM-41) was characterized by X-ray diffraction, Fourier transform infrared spectroscopy, thermogravimetric analysis, scanning electron microscopy, inductively coupled plasma atomic emission spectroscopy and transmission electron microscopy. Pd-2A3HP-MCM-41 was evaluated as an efficient catalyst for the C–C coupling reaction of aryl halides with sodium tetra phenyl borate and synthesis of 2,3-dihydroquinazolin-4(1H)-ones. The catalyst was successfully reused several times without appreciable change in its catalytic activity.

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Acknowledgments

This work was supported by the research facilities of Ilam University, Ilam, Iran.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Ilam University, P.O. Box 69315516, Ilam, Iran

    Mohsen Nikoorazm, Arash Ghorbani-Choghamarani & Maryam Khanmoradi

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  1. Mohsen Nikoorazm
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  2. Arash Ghorbani-Choghamarani
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  3. Maryam Khanmoradi
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Correspondence to Mohsen Nikoorazm.

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Nikoorazm, M., Ghorbani-Choghamarani, A. & Khanmoradi, M. Immobilization of palladium on functionalized nanoporous MCM-41 and its application in C–C bond-forming and synthesis of DHQs. J Porous Mater 23, 761–772 (2016). https://doi.org/10.1007/s10934-016-0131-1

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  • DOI: https://doi.org/10.1007/s10934-016-0131-1

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