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Synthesis and Crystal Structures of Two New Coordination Polymers Based on Diphenic Acid

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Abstract

Two new metal coordination polymers [Zn(dpa)(bim)] n and [Ni(dpa)(bpp)] n , (H2dpa = 3,4′-Biphenyl-dicarboxylic acid, bim = Benzimidazole and bpp = 1,3-Di (4-pyridyl)-propane) have been synthesized and structurally characterized by elemental analysis, IR and X-ray diffraction. Single-crystal X-ray analyses reveal that the 3,4′-diphenic acids act as bridging ligands, exhibiting three coordination modes to link metal ions: μ 2–η 1: η 1, μ 1–η 1: η 0 and μ 1 –η1: η1. Compound 1 demonstrates a one-dimensional zigzag chain. There exists intermolecular hydrogen bonding interactions in compound 1 which lead to form supramolecular structure. Compound 2 is a two-dimensional (4,4) net, and further assembled twofold interpenetrating net. Furthermore, compound [Zn(dpa)(bim)] n shows intense photoluminescence at room temperature.

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Acknowledgement

The authors gratefully acknowledge financial support from the National Natural Science Foundation of China (20971018).

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Authors and Affiliations

  1. Department of Chemistry, Dezhou University, Shandong, 253023, People’s Republic of China

    Feng Guo, Baoyong Zhu & Xiuling Zhang

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  1. Feng Guo
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  2. Baoyong Zhu
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  3. Xiuling Zhang
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Correspondence to Feng Guo.

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Guo, F., Zhu, B. & Zhang, X. Synthesis and Crystal Structures of Two New Coordination Polymers Based on Diphenic Acid. J Inorg Organomet Polym 20, 118–123 (2010). https://doi.org/10.1007/s10904-009-9321-5

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  • DOI: https://doi.org/10.1007/s10904-009-9321-5

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