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Synthesis, Spectral and Structural Studies of a Novel Semicarbazone Synthesized from Quinoline-2-Carboxaldehyde and N4-Phenyl-3-Semicarbazide

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Abstract

A new semicarbazone, HL has been synthesized from quinoline-2-carboxaldehyde and N4-phenyl-3-semicarbazide and structurally and spectrochemically characterized. 1H NMR, 13C NMR, IR and electronic spectra of the compound are studied. The existence of keto form in the solid state is supported by the crystal structure and IR data. The compound crystallizes into an orthorhombic space group P212121. Intra and intermolecular hydrogen bonding interactions facilitates unit cell packing in the crystal lattice.

Index Abstract

A new semicarbazone, HL has been synthesized from quinoline-2-carboxaldehyde and N4-phenyl-3-semicarbazide and it crystallizes into an orthorhombic with a space group P212121. Unit cell parameters a = 6.4662(3) Å, b = 10.3994(5) Å, c = 21.0315(11) Å, α = 90°, β = 90° and γ = 90°. 1H NMR, 13C NMR, IR and electronic spectra of the compound were studied. The existence of keto form in the solid state is supported by the crystal structure and IR data. Intra and intermolecular hydrogen bonding interactions facilitates unit cell packing in the crystal lattice.

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Acknowledgements

M.R.P. Kurup is thankful to the Council of Scientific & Industrial Research, New Delhi, India for the financial assistance. The authors are thankful to the National Single Crystal X-ray diffraction Facility, IIT, Bombay, India for providing single crystal XRD data.

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  1. Department of Applied Chemistry, Cochin University of Science and Technology, Kochi, 682 022, Kerala, India

    T. A. Reena & M. R. Prathapachandra Kurup

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  1. T. A. Reena
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  2. M. R. Prathapachandra Kurup
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Correspondence to M. R. Prathapachandra Kurup.

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Reena, T.A., Kurup, M.R.P. Synthesis, Spectral and Structural Studies of a Novel Semicarbazone Synthesized from Quinoline-2-Carboxaldehyde and N4-Phenyl-3-Semicarbazide. J Chem Crystallogr 40, 927–932 (2010). https://doi.org/10.1007/s10870-010-9765-z

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  • DOI: https://doi.org/10.1007/s10870-010-9765-z

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