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Synthesis and crystal structure of 1D 2,3-naphtho 15-crown-5 complex [Na(N15C5)]2[Ni(i-mnt)2] containing S⋅sC and S⋅sπ interactions

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Abstract

The reaction of 2,3-naphtho-15-crown-5 (N15C5) with Na2[Ni(i-mnt)2] [i-mn = 1,1-dicyanoethylene-2,2-dithiolate] affords the title complex [Na(N15C5)]2[Ni(i-mnt)2] (1), which is characterized by elemental analysis, FT-IR, UV-visible spectra and single crystal X-ray diffraction. 1 crystallizes in the triclinic, space group P\(\bar{1}\) with a = 8.291(4), b = 12.833(7), c = 12.913(6) Å, α = 115.732 (7), β = 105.030(7), γ = 90.912(8)∘, V = 1182.2(10) Å3, Z = 1 and R 1(wR 2) = 0.0422(0.1001). The single crystal X-ray analysis shows that the [Na(N15C5)]+ complex cations act as the bridges linking the [Ni(i-mnt)2]2− anions into a 1D infinite chain through Na–N interactions and S⋅sC and S⋅sπ interactions are observed in the chain with the shortest S⋅sC distance of 3.433 Å.

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Authors and Affiliations

  1. Department of Chemistry, Liaocheng University, Liaocheng, 252059, P.R. China

    Xi-Ke Gao, Jian-Min Dou, Da-Cheng Li, Feng-Ying Dong & Da-Qi Wang

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  1. Xi-Ke Gao
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  2. Jian-Min Dou
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  3. Da-Cheng Li
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  4. Feng-Ying Dong
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  5. Da-Qi Wang
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Correspondence to Jian-Min Dou.

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Gao, XK., Dou, JM., Li, DC. et al. Synthesis and crystal structure of 1D 2,3-naphtho 15-crown-5 complex [Na(N15C5)]2[Ni(i-mnt)2] containing S⋅sC and S⋅sπ interactions. J Chem Crystallogr 35, 107–111 (2005). https://doi.org/10.1007/s10870-005-2798-z

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  • DOI: https://doi.org/10.1007/s10870-005-2798-z

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