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Controlled Synthesis of Acrylonitrile-Based Polymers as Precursors for Carbon Fiber Production

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Fibre Chemistry Aims and scope

The review considers modern methods for the synthesis of polyacrylonitrile as a precursor for the production of high-strength carbon fiber. Special emphasis was placed on using controlled radical polymerization techniques for the synthesis of a polyacrylonitrile precursor of a given molecular weight in organic solvents.

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The work was performed as part the state task of the Ministry of Education and Science of Russia 4.5630.2017/VU and the Russian Foundation for Basic Research. Project 18-03-520016.

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Authors and Affiliations

  1. N. I. Lobachevsky State University of Nizhny Novgorod, Nizhny Novgorod, Russia

    D. F. Grishin & I. D. Grishin

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  1. D. F. Grishin
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Correspondence to D. F. Grishin.

Additional information

Translated from Khimicheskie Volokna, No. 6, pp. 38 – 47, November – December 2018.

Appendices

Appendix 1.

figure b
figure c

where ÌtnLx is a metal complex catalyst; M is the monomer; kt is the chain termination reaction rate constant.

Appendix 2.

figure d

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Grishin, D.F., Grishin, I.D. Controlled Synthesis of Acrylonitrile-Based Polymers as Precursors for Carbon Fiber Production. Fibre Chem 50, 514–523 (2019). https://doi.org/10.1007/s10692-019-10021-8

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