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Hypervalent iodine in the structure of N-heterocycles: synthesis, structure, and application in organic synthesis

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Chemistry of Heterocyclic Compounds Aims and scope

The review is devoted to one of the most substantial trends in the chemistry of hypervalent iodine – synthesis, structure, and properties of heterocyclic and pseudoheterocyclic systems based on λ3- and λ5-iodanes. Among the variety of cyclic reagents based on hypervalent iodine, special attention has recently been paid to iodanes having close contact between I and N atoms. The review is addressing the synthetic approaches, structural features, and application of these reagents. The review includes more than 100 literature sources, mainly covering publications from 1990 to 2020 and key research from earlier years.

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The review was prepared with the financial support of the Russian Foundation for Basic Research (grant 19-43-703004).

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Authors and Affiliations

  1. Research School of Chemistry and Applied Biomedical Sciences, National Research Tomsk Polytechnic University, 30 Lenina Ave, Tomsk, 634050, Russia

    Yulia А. Vlasenko, Mekhman S. Yusubov & Pavel S. Postnikov

  2. Department of Biological Chemistry, IQAC-CSIC, 18–26 c/Jordi Girona, 08034, Barcelona, Spain

    Alexandr Shafir

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  1. Yulia А. Vlasenko
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  2. Mekhman S. Yusubov
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  3. Alexandr Shafir
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  4. Pavel S. Postnikov
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Correspondence to Alexandr Shafir or Pavel S. Postnikov.

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Translated from Khimiya Geterotsiklicheskikh Soedinenii, 2020, 56(7), 854–866

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Vlasenko, Y.А., Yusubov, M.S., Shafir, A. et al. Hypervalent iodine in the structure of N-heterocycles: synthesis, structure, and application in organic synthesis. Chem Heterocycl Comp 56, 854–866 (2020). https://doi.org/10.1007/s10593-020-02742-0

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