Abstract
Producing green and efficient energy sources is a major challenge. As a consequence, the use of photovoltaic devices for conversion of light into electricity is growing worldwide. A lot of effort had been invested to create high-efficient solar cells, but their durability, stability, flexibility and efficiency at low light intensities are still unexplored. Here, we built a flexible solar cell made of p-doped, amorphized a-undoped and n-doped Sb2S3 solid carrier loaded with electrolyte. Indium tin oxide glass was the working electrode, and aluminium was the counter electrode. Every (p–a–n) flexible Sb2S3/solid carrier layers were obtained using a cheap casting/solvent evaporation technique, from a blend consisted of chitosan, polyethylene glycol and electrolyte containing 0.5 M potassium iodide and 0.05 M iodine, and corresponding synthesized amorphized a-undoped and p and n-doped Sb2S3 semiconductor. Results show that flexible Sb2S3 solar cell possesses good stability and efficiency of about 10% at 5% sun. Overall, our findings demonstrate for the first time that flexible solar cell can be made and used for low light intensity applications.
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Ahmad Z, Najeeb MA, Shakoor RA, Al-Muhtaseb SA, Touati F (2018) Limits and possible solutions in quantum dot organic solar cells. Renew Sustain Energy Rev 82:1551–1564. https://doi.org/10.1016/j.rser.2017.07.001
Ansari MIH, Qurashi A, Nazeeruddin MK (2018) Frontiers, opportunities, and challenges in perovskite solar cells: a critical review. J Photochem Photobiol, C 35:1–24. https://doi.org/10.1016/j.jphotochemrev.2017.11.002
Bagher AM (2014) Introduction to organic solar cells. Sustain Energy 2:85–90. https://doi.org/10.12691/rse-2-3-2
Bao H, Cui X, Li CM, Song Q, Lu Z, Guo J (2007) Synthesis and electrical transport properties of single-crystal antimony sulfide nanowires. J Phys Chem C 111:17131–17135. https://doi.org/10.1021/jp076828q
Gunes S, Neugebauer H, Sariciftci NS (2007) Conjugated polymer- based organic solar cells. Chem Rev 107:1324–1338. https://doi.org/10.1021/cr050149z
Janošević V, Mitrić M, Bundaleski N, Rakočević Z, Validžić ILj (2016a) High-efficiency Sb2S3- based hybrid solar cell at low light intensity: cell made of synthesized Cu and Se-doped Sb2S3. Prog Photovolt Res Appl 24:704–715. https://doi.org/10.1002/pip.2724
Janošević V, Mitrić M, Savić J, Validžić ILj (2016b) Structural, optical, and electrical properties of applied amorphized and polycrystalline Sb2S3 thin films. Metall Mat Trans A 47:1460–1468. https://doi.org/10.1007/s11661-015-3282-9
Janošević V, Mitrić M, Janošević-Ležaić A, Validžić ILj (2016c) Weak light performance of synthesized amorphous Sb2S3-based hybrid solar cell. IEEE J Photovolt 6:473–479. https://doi.org/10.1109/JPHOTOV.2015.2501731
Kamat PV (2007) Meeting the clean energy demand: nanostructure architectures for solar energy conversion. J Phys Chem C 111:2834–2860. https://doi.org/10.1021/jp066952u
Lojpur V, Tasić N, Validžić ILj (2017a) Different behaviors in current–voltage measurements of undoped and doped Sb2S3-based solar cells. J Appl Electrochem 47:117–124. https://doi.org/10.1007/s10800-016-1025-2
Lojpur V, Mitrić M, Kačarević-Popović Z, Radosavljević A, Rakočević Z, Validžić ILj (2017b) The role of low light intensity: a cheap, stable, and solidly efficient amorphous Sb2S3 powder/hypericin composite/PVA matrix loaded with electrolyte solar cell. Environ Prog Sustain Energy 36:1507–1516. https://doi.org/10.1002/ep.12597
Lojpur V, Krstić J, Kačarević-Popović Z, Mitrić M, Rakočević Z, Validžić ILj (2017c) Efficient and novel Sb2S3 based solar cells with chitosan/poly(ethylene glycol)/electrolyte blend. Int J Energy Res. https://doi.org/10.1002/er.3899
Lojpur V, Mitrić M, Validžić ILj (2018) The role of low light intensity: a step towards understanding the connection between light, optic/lens and photovoltaic behavior for Sb2S3 thin-film solar cells. Opt Laser Technol 101:425–432. https://doi.org/10.1016/j.optlastec.2017.11.045
Rech B, Wagner H (1999) Potential of amorphous silicon for solar cells. Appl Phys A 69:155–167. https://doi.org/10.1007/s003390050986
Sharma RK, Ganesan P, Tyagi VV, Mahlia TMI (2016) Accelerated thermal cycle and chemical stability testing of polyethylene glycol (PEG) 6000 for solar thermal energy storage. Sol Energy Mater Sol Cells 147:235–239. https://doi.org/10.1016/j.solmat.2015.12.023
Validžić ILj, Janošević V, Mitrić M (2016) Characterization and current–voltage characteristics of solar cells based on the composite of synthesized Sb2S3powder with small band gap and natural dye. Environ Prog Sustain Energy 35:512–516. https://doi.org/10.1002/ep.12221
Yu Y, Wang RH, Chen Q, Peng LM (2006) High-quality ultralong Sb2Se3 and Sb2S3 nanoribbons on a large scale via a simple chemical route. J Phys Chem B 110:13415–13419. https://doi.org/10.1021/jp061599d
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This work is supported by the Ministry of Education, Science and Technological Development of the Republic of Serbia (Project 45005).
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Lojpur, V., Krstić, J., Kačarević-Popović, Z. et al. Flexible and high-efficiency Sb2S3/solid carrier solar cell at low light intensity. Environ Chem Lett 16, 659–664 (2018). https://doi.org/10.1007/s10311-017-0702-7
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DOI: https://doi.org/10.1007/s10311-017-0702-7