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Ab-initio Calculations of T-shaped Phosphine-Platinum(II) Complexes

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Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Summary.

 The geometries and total energies of several T-shaped platinum(II) complexes of the type (H3P)PtXY (X, Y=Cl, CH3, SiH3, Si(OH)3) were calculated by ab-initio methods. In the most stable isomer, the ligand with the smallest trans influence is trans to the PH3 ligand. The trans influence increases in the order Cl<CH3<SiH3<Si(OH)3.

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Authors and Affiliations

  1. Institute of Materials Chemistry, Vienna University of Technology, A-1060 Wien, Austria, , , , , , AT

    Dietmar Sturmayr & Ulrich Schubert

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  1. Dietmar Sturmayr
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  2. Ulrich Schubert
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Corresponding author. E-mail: uschuber@mail.2serv.tuwien.ac.at

Received October 14, 2002; accepted October 14, 2002 Published online May 2, 2003

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Sturmayr, D., Schubert, U. Ab-initio Calculations of T-shaped Phosphine-Platinum(II) Complexes. Monatshefte für Chemie 134, 791–795 (2003). https://doi.org/10.1007/s00706-002-0568-6

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  • DOI: https://doi.org/10.1007/s00706-002-0568-6

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