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l-Lysine-derived optically active poly(hydrazide-imide)s: synthesis, characterization and their application in removal of heavy metal ions

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Abstract

Six novel poly(hydrazide-imide)s (PHI a–f ) were prepared from the reaction of a novel l-lysine-derived chiral diacid, ethyl l-lysine-N,N’-ditrimellitoyl diacide (1), with six synthetic dihydrazides by solution polycondensation. These polymers have inherent viscosities in the range of 0.22–0.45 dl g−1, display optical activity, and are readily soluble in polar aprotic solvents. They start to decompose (T 10%) above 248 °C and display glass-transition temperatures at 164.37–210.20 °C. All the above polymers were fully characterized by UV, FT-IR, and 1H NMR spectroscopy, TGA, DSC, inherent viscosity measurement and specific rotation.

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Acknowledgments

We gratefully acknowledge the funding support received for this project from Islamic Azad University, Firoozabad Branch.

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Authors and Affiliations

  1. Department of Chemistry, Firoozabad Branch, Islamic Azad University, Firoozabad, Fars, Islamic Republic of Iran

    Alireza Alborzi

  2. Department of Science, Payame Noor University, 19395-4697, Tehran, Islamic Republic of Iran

    Saeed Zahmatkesh & Ashkbous Yazdanpanah

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  1. Alireza Alborzi
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  2. Saeed Zahmatkesh
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  3. Ashkbous Yazdanpanah
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Correspondence to Alireza Alborzi.

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Alborzi, A., Zahmatkesh, S. & Yazdanpanah, A. l-Lysine-derived optically active poly(hydrazide-imide)s: synthesis, characterization and their application in removal of heavy metal ions. Polym. Bull. 70, 3359–3372 (2013). https://doi.org/10.1007/s00289-013-1027-8

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  • DOI: https://doi.org/10.1007/s00289-013-1027-8

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