Abstract
The composition of volatile components of subcutaneous fat from Iberian pig has been studied. Purge and trap gas chromatography−mass spectrometry has been used. The composition of the volatile fraction of subcutaneous fat has been used for authentication purposes of different types of Iberian pig fat. Three types of this product have been considered, montanera, extensive cebo and intensive cebo. With classification purposes, several pattern recognition techniques have been applied. In order to find out possible tendencies in the sample distribution as well as the discriminant power of the variables, principal component analysis was applied as visualisation technique. Linear discriminant analysis (LDA) and soft independent modelling by class analogy (SIMCA) were used to obtain suitable classification models. LDA and SIMCA allowed the differentiation of three fattening diets by using the contents in 2,2,4,6,6-pentamethyl-heptane, m-xylene, 2,4-dimethyl-heptane, 6-methyl-tridecane, 1-methoxy-2-propanol, isopropyl alcohol, o-xylene, 3-ethyl-2,2-dimethyl-oxirane, 2,6-dimethyl-undecane, 3-methyl-3-pentanol and limonene.
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References
Andersen HJ, Oksbjerg N, Young JF, Therkildsen M (2005) Meat Sci 70:543–554
Viera-Alcaide I, Vicario IM, Graciani E, León-Camacho M (2007) Anal Chim Acta 596:319–324
Rey AI, Daza A, López-Carrasco C, López-Bote CJ (2006) Meat Sci 73:66–74
López-Bote CJ (1998) Meat Sci 49:S17–S27
Osorio MT, Zumalacárregui JM, Cabeza EA, Figueira A, Mateo J (2008) Small Rumin Res 78:1–12
Soncin S, Chiesa LM, Cantoni C, Biondi PA (2007) J Food Compos Anal 20:436–439
Vasta V, Ratel J, Engel E (2007) J Agric Food Chem 55:4630–4639
Sebastián I, Viallon-Fernández C, Berge P, Berdagué JL (2003) Sci Aliments 23:497–511
Madruga MS, Stephen Elmore J, Dodson AT, Mottram DS (2009) Food Chem 115:1081–1087
Narváez-Rivas M, Vicario IM, Alcalde MJ, León-Camacho M (2010) Talanta 81:1224–1228
Boletín Oficial del Estado (BOE) (2004). Orden PRE/3844/2004, 18/11/2004 BOE 283: 38770-38775, Madrid, Spain
Ramírez R, Cava R (2007) J Agric Food Chem 55:1923–1931
Ruiz J, Cava R, Ventanas J, Jensen MT (1998) J Agric Food Chem 46:4688–4694
Ruíz J, Ventanas J, Cava R, Andrés A, García C (1999) Meat Sci 52:19–27
Andrade MJ, Córdoba JJ, Sánchez B, Casado EM, Rodríguez M (2009) Food Chem 113:457–463
Jolliffe IT (2002) Principal components analysis, 2nd edn. Springer, New York
Gardiner WP (1997) Statistical analysis methods for chemists. Royal Society of Chemistry, Cambridge
Massart DL (1998) Handbook of chemometrics and qualimetrics Part B. Elsevier, Amsterdam
Kaiser HF (1960) Educ Psychol Meas 20:141–151
Acknowledgements
The authors are grateful to the Designations of Origin “Los Pedroches” and “Jamón de Huelva” for the collaboration and given help. This study was supported by projects PET 2007_0015 and P08-AGR-03498.
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Published in the special issue Chemometrics (VII Colloquium Chemiometricum Mediterraneum) with Guest Editors Marcelo Blanco, Juan M. Bosque-Sendra and Luis Cuadros-Rodríguez.
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Narváez-Rivas, M., Pablos, F., Jurado, J.M. et al. Authentication of fattening diet of Iberian pigs according to their volatile compounds profile from raw subcutaneous fat. Anal Bioanal Chem 399, 2115–2122 (2011). https://doi.org/10.1007/s00216-010-4387-z
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DOI: https://doi.org/10.1007/s00216-010-4387-z