Abstract
This study assessed the baseline concentrations and spatial distribution of total mercury (Hg) in urban soils of the city of Arak, Iran. Concentrations of Hg were determined in soil collected from urban areas, and the spatial distribution was analyzed using the semivariogram approach in geostatistical technology. Mercury in soil ranged from 66.3 to 581 µg/kg. The experimental variogram of soil mercury concentrations was best-fitted by a spherical model. A spatial distribution map revealed that Hg concentration showed decreasing trends from south to north, west to east and center to suburb. Overall, the results showed that Hg concentrations in urban soils of Arak may be considered medium or low.
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References
Alloway BJ (1995) Heavy metals in soils. Chapman and Hall, Glasgow
Appleton JD, Weeks JM, Calvez JPS, Beinhoff C (2006) Impacts of mercury contaminated mining waste on soil quality, crops, bivalves, and fish in the Naboc River area, Mindanao, Philippines. Sci Total Environ 354:198–211
Birke M, Rauch U (2000) Urban geochemistry: investigations in the Berlin metropolitan area. Environ Geochem Health 22:233–248
Callender E, Rice KC (2000) The urban environmental gradient: anthropogenic influences on the spatial and temporal distributions of lead and zinc in sediments. Environ Sci Technol 34:232–238
Cambardella CA, Moorman TB, Novak JM, Parkin TB, Turco RF, Konopka AE (1994) Field-scale variability of soil properties in central Iowa soils. Soil Sci Soc Am J 58:1501–1511
Chen X, Xia X, Wu S, Wang F, Guo X (2010) Mercury in urban soils with various types of land use in Beijing, China. Environ Pollut 158:48–54
Fang F, Wang Q, Li J (2004) Urban environmental mercury in Changchun, a metropolitan city in Northeastern China: source, cycle, and fate. Sci Total Environ 330:159–170
Fang F, Wang H, Lin Y (2011) Spatial distribution, bioavailability, and health risk assessment of soil Hg in Wuhu urban area, China. Environ Monit Assess 179:255–265
FIFA, Fertilizer Industry federation of Australia (2006) Australian soil fertility manual, 3rd edn. CSIRO Publishing, Collingwood
Gillis AA, Miler DR (2000) Some local environmental effects on mercury emission and absorption at a soil surface. Sci Total Environ 260(1–3):191–200
Grangeon S, Guédron S, Astab J, Sarret G, Charlet L (2012) Lichen and soil as indicators of an atmospheric mercury contamination in the vicinity of a chlor-alkali plant (Grenoble, France). Ecol Indic 13:178–183
Hojdova M, Navra T, Rohovec J (2008) Distribution and speciation of mercury in mine waste dumps. Bull Environ Contam Toxicol 80:237–241
Johansson K, Bergback B, Tyler G (2001) Impact of atmospheric long range transport of lead, mercury and cadmium on the Swedish forest environment. Water Air Soil Pollut Focus 1:279–297
Kot FS, Matyushkina LA (2002) Distribution of mercury in chemical fractions of contaminated urban soils of middle Amur. Russia. J Environ Monit 4(5):803–808
Lark RM, Ferguson RB (2004) Mapping risk of soil nutrient deficiency or excess by disjunctive and indicator kriging. Geoderma 118:39–53
Linde M, Bengtsson H, Oborn I (2001) Concentration and pools of heavy metals in urban soils in Stockholm, Sweden. Water Air Soil Pollut Focus 1:83–101
Liu XM, Wu JJ, Xu JM (2006) Characterizing the risk assessment of heavy metals and sampling uncertainty analysis in paddy field by geostatistics and GIS. Environ Pollut 141:257–264
Liu J, Feng X, Zhu W, Zhang X, Yin R (2012) Spatial distribution and speciation of mercury and methyl mercury in the surface water of East River (Dongjiang) tributary of pearl river delta, South China. Environ Sci Pollut Res 19:105–112
Lu S, Wang H, Bai S (2009) Heavy metal contents and magnetic susceptibility of soils along an urban–rural gradient in rapidly growing city of eastern China. Environ Monit Assess 155:91–101
Manta DS, Angelone M, Bellanca A, Neri R, Sprovieri M (2002) Heavy metals in urban soils: a case study from the city of Palermo (Sicily). Italy. Sci Total Environ 300(1–3):229–243
Miller EK, Vanarsdale A, Keeler GJ, Chalmers A, Poissant L, Kamman NC, Brulotte R (2005) Estimation and mapping of wet and dry mercury deposition across northeastern North America. Ecotoxicology 14:53–70
Peltola P, Astrom M (2003) Urban geochemistry: a multimedia and multielement survey of a small town in Northern Europe. Environ Geochem Health 25:397–419
Reimann C, Caritat P (1998) Chemical elements in the environment: fact sheets for the geochemist and environmental scientist. Springer, Berlin p 398
Remy S, Prudent P, Hissler C, Probst JL, Krempp G (2003) Total mercury concentrations in an industrialized catchment, the Thur River basin (north-eastern France): geochemical background level and contamination factors. Chemosphere 52:635–644
Rice KC (1999) Trace element concentrations in streambed sediment across the conterminous United States. Environ Sci Technol 33:2499–2504
Rodrigues S, Pereira ME, Duarte AC, Ajmone-Marsan F, Davidson CM, Grman H, Hossack I, Hursthouse AS, Ljung K, Martini C, Otabbong E, Reinoso R, Ruiz-Cortés E, Urquhart GJ, Vrščaj B (2006a) Mercury in urban soils: a comparison of local spatial variability in six European cities. Sci Total Environ 368:926–936
Rodrigues S, PereiraME Sarabando L, Lopes LD, Cachada A, Duarte A (2006b) Spatial distribution of total Hg in urban soils from an Atlantic coastal city (Aveiro, Portugal). Sci Total Environ 368:40–46
Santos-Francés F, García-Sánchez A, Alonso-Rojo P, Contreras F (2011) Distribution and mobility of mercury in soils of a gold mining region, Cuyuni river basin. Venezuela. J Environ Manage 92(4):1268–1276
Tijhuis L, Brattli B, Sæther OM (2002) A geochemical survey of topsoil in the city of Oslo, Norway. Environ Geochem Health 24:67–94
USEPA,1996. Soil screening guidance: technical background document. EPA/540/R95/128
Vafaei R, Ostovan H, Incekara U, Pesic V (2007) Faunistic study of the aquatic beetles (Coleoptera: polyphaga) of Markazi Province (Central Iran) with new records. Arch Biol Sci Belgrade 59(3):239–242
Wang XS, Qin Y (2005) Correlation between magnetic susceptibility and heavy metals in urban topsoil: a case study from the city of Xuzhou. China. Environ Geo 49:10–18
Wang D, Shi X, Wei S (2003) Accumulation and transformation of atmospheric mercury in soil. Sci Total Environ 304(1–3):209–214
Webster R, Oliver MA (2001) Geostatistics for environmental scientists. Wiley, Chichester, pp 89–96
Won JH, Park JY, Lee TG (2007) Mercury emissions from automobiles using gasoline, diesel, and LPG. Atmos Environ 41:7547–7552
Wu Y, Zhou Q, Adriano DC (1991) Interim environmental guidelines for cadmium and mercury in soils of China. Water Air Soil Pollut 57–58:733–743
Acknowledgments
The authors gratefully acknowledge funding provided for this study by the Tarbiat Modares University of Iran. Also the authors are grateful to Dr M. Solgi (Head of Department of Horticulture at Arak University) for his support and assistance in this research.
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Solgi, E., Esmaili-Sari, A. & Riyahi-Bakhtiari, A. Spatial Distribution of Mercury in the Surface Soils of the Urban Areas, Arak, Iran. Bull Environ Contam Toxicol 93, 710–715 (2014). https://doi.org/10.1007/s00128-014-1408-1
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DOI: https://doi.org/10.1007/s00128-014-1408-1