Abstract
Thremogravimetric (TG) studies of a new series of organotin(IV) carboxylates of the general formula RnSnL4-n (where R = CH3, C2H5, C4H9, C6H5, C6H11 and C8H17, n = 2, 3 and L = para-methoxyphenylethanoate anion) have been carried out. Horowitz and Metzger method has been used to calculate thermokinetic parameters. It has been found that diorganotin dicarboxylates have larger activation energy than those of corresponding triorganotin carboxylates. Furthermore, the activation energy, Gibb’s free energy, entropy and enthalpy of diorganotin compounds shows the following trend, (CH3)2SnL2 < (C2H5)2SnL2 < (C4H9)2SnL2 < (C8H17)2SnL2. This is attributed to steady increase in chain length of the alkyl groups. However, triorganotin compounds do not show such behavior.
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Z. Rehman, M.M. Barsan, I. Wharf, N. Muhammad, S. Ali, A. Meetsma, I.S. Butler, Inorg. Chim. Acta 361 (2008) 3322.
S. Rehman, S. Ali, S. Shahzadi, Heteroatom Chem. 19 (2008) 612.
K. Shahid, S. Ali, M.H. Bhatti, M. Mazhar, S. Mahmood, S. Rehman, Turk. J. Chem. 26 (2002) 589.
M. Danish, S. Ali, K. Shahid, M. Mazhar, J. Chem. Soc. Pak. 26 (2004) 140.
N.F. Cardarelli, Tin as Vital Nutrient, 1st ed., CRC Press Inc., Boca Raton, Florida, 1986.
S.J. Blunden, P.A. Kusak, R. Hill, The Industrial Uses of Tin Chemicals, Royal Society of Chemistry, London, 1995.
K.C. Molloy, in: F.R. Hartly (Ed.), Bioorganotin Compounds, The Chemistry of the Metal-Carbon Bond, John Wiley & Sons, Ltd., New York, 1989.
S.K. Hadjikakou, N. Hadjiliadis, Coord. Chem. Rew. 253 (2009) 235.
S. Shahzadi, K. Shahid, S. Ali, Russ. J. Coord. Chem. 33 (2007) 403.
V. Chandrasekhar, S. Nagedran, V. Baskar, Coord. Chem. Rew. 235 (2002) 1.
E.R.T. Tiekink, Appl. Organomet. Chem. 5 (1991) 1.
M. Danish, S. Ali, M. Mazhar, H. Masood, A. Badshah, A. Malik, G. Kehr, Synth. React. Inorg. Met.-Org. Chem. 27 (1997) 663.
M. Danish, S. Ali, M. Mazhar, A. Badshah, Main Group. Met. Chem. 19 (1996) 21.
H. Massod, S. Yaoob, F. Ahmed, S. Ali, S. Shahzadi, J. Iran. Chem. Soc. 3 (2006) 151.
S. Yaqub, F. Ahmed, Sadiq-ur-Rehman, S. Ali, S. Shahzadi, J. Iran. Chem. Soc. 6 (2009) 88.
S. Ahmad, S. Ali, S. Shahzadi, F. Ahmad, K.M. Khan, Truk. J. Chem. 29 (2005) 299.
M. Danish, S. Ali, A. Badshah, M. Mazhar, H. Masood, A. Malik, G. Kehr, Synth. React. Inorg. Met.-Org. Nano Met. Chem. 27 (1997) 863.
A. Valor, E. Regura, E. Torres-Garcia, S. Mendoza, F. Sanchez-Sinencio, Thermochim. Acta 389 (2002) 133.
E. Torres-Gaarcia, A. Pelaiz-Barranco, C. Vazquez- Romas, G.A. Fuentes, J. Materials Res. 16 (2001) 2209.
E. Torres-Gaarcia, A. Pelaiz-Barranco, C. Vazquez- Romas, F. Calderon-Pinar, O. Perez-Martinez, Thermochim. Acta 372 (2001) 39.
H. Al-Maydama, A. El-Shkeil, M.A. Khalid, A. Al- Karbouly, Ecl. Quim. Sao Paulo 31 (2006) 45.
N. Muhammad, Z. Rehman, S. Ali, A. Meetsma, F. Shaheen, Inorg. Chim. Acta 362 (2009) 2842.
B.A. Shah, A.V. Shah, B.N. Bhandari, R.R. Bhatt, J. Iran. Chem. Soc. 5 (2008) 252.
H.H. Horowitz, G. Metzger, Anal. Chem. 35 (1963) 1464.
D.D. Perrin, W.L.F. Armengo, Purification of Laboratory Chemicals, 3rd ed., Pergamon Press, Oxford, 2003.
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Danish, M., Ahmad, N., Zahara, N. et al. Thermokinetic studies of organotin(IV) carboxylates derived from para-methoxyphenylethanoic acid. JICS 7, 846–852 (2010). https://doi.org/10.1007/BF03246078
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DOI: https://doi.org/10.1007/BF03246078