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On the pattern of hydrogenolysis of hexane isomers over four Group VIIIB metals

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Abstract

The hydrogenolysis patterns of five hexane isomers have been compared over Rh, Pd, Ir and Pt. The selectivity of rupture of various C−C bond types is different for various metals. The “fingerprint-like” patterns are, as a rule, similar to those reported in the literature, their correlation with the position of the metal in the periodic system is pointed out.

Abstract

Изучен характеристический гидрогенолиз 5-и изомерных гексанов на катализаторах Rh, Pd, Ir и Pt. Селективность разрыва отдельных типов C−C связей отличается для различных металлов Характеристики, рассматриваемые как “отпечатки пальца” подобны к литературным данным. Отмечается их корреляция с положением данного металла в периодической системе.

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Authors and Affiliations

  1. Institute of Isotopes of the Hungarian Academy of Sciences, P.O. Box 77, H-1525, Budapest, Hungary

    Z. Paál & P. Tétényi

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  1. Z. Paál
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  2. P. Tétényi
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Paál, Z., Tétényi, P. On the pattern of hydrogenolysis of hexane isomers over four Group VIIIB metals. React Kinet Catal Lett 12, 131–137 (1979). https://doi.org/10.1007/BF02071900

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  • DOI: https://doi.org/10.1007/BF02071900

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