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Crystal structure refinement of basic tellurium nitrate: A reformulation as (Te2O4H)+(NO3)−

Verfeinerung der Kristallstruktur von basischem Telluriumnitrat. Eine Umformulierung in (Te2O4H)+(NO3)−

  • Anorganische und Physikalische Chemie
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Abstract

Basic tellurium nitrate crystallizes in the space group Pnma witha=14.607 (1),b=8.801 (1), andc=4.4633 (4) Å. Full-matrix least-squares refinement of automatic diffractometer data converged to a residualR=0.036 (R w =0.046) for 899 independent reflections. A detailed analysis of the structural data leads us to reformulate this compound as (Te2O4H)+(NO3)− with a basic structural element consisting of a charged two-dimensional puckered Te2O4H+ network with discrete NO3 − anions, an example of apositively-charged network structure.

Zusammenfassung

Basisches Telluriumnitrat kristallisiert in der Raumgruppe Pnma mita=14,607 (1),b=8,801 (1) undc=4,4633 (4) Å. Die verfeinernde Auswertung der Diffraktometerdaten konvergierte zuR=0,036 (R w =0.046) für 899 unabhängige Reflexe. Eine detaillierte Analyse der Strukturdaten führte zu einer Umformulierung dieser Verbindung als (Te2O4H)+(NO3)−, wobei die Basisstruktur aus einem geladenen, zweidimensionalen, gefalteten Te2O4H+ Netzwerk mit getrennten NO3 − Anionen besteht. Es stellt dies ein Beispiel einerpositiv geladenen Netzstruktur dar.

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Authors and Affiliations

  1. Institute of Materials Science and Department of Chemistry, University of Connecticut, 06268, Storrs, CT, U.S.A.

    J. B. Anderson, M. H. Rapposch, C. P. Anderson & E. Kostiner

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  1. J. B. Anderson
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  2. M. H. Rapposch
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  3. C. P. Anderson
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  4. E. Kostiner
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Anderson, J.B., Rapposch, M.H., Anderson, C.P. et al. Crystal structure refinement of basic tellurium nitrate: A reformulation as (Te2O4H)+(NO3)− . Monatshefte für Chemie 111, 789–796 (1980). https://doi.org/10.1007/BF00899243

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  • DOI: https://doi.org/10.1007/BF00899243

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