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The infrared and Raman spectra of ZrO2-SiO2 glasses prepared by a sol-gel process

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Abstract

Infrared and Raman spectra were measured and interpreted on the basis of structure for various ZrO2-SiO2 glasses that were prepared by a sol-gel process involving zirconium nitrate. Interpretation of the spectra indicates the presence of both Zr-O-Si and Si-O-H linkages depending upon heat treatment conditions, and the evidence of zirconium atoms with eight fold coordination for glasses with high ZrO2 contents. The crystalline products formed during glass devitrification were monitored by vibrational spectra. The formation and detection of tetragonal ZrO2, zircon, monoclinic ZrO2 and α-cristobalite depended upon the conditions of devitrification.

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References

  1. R. G. Simhan, J. Non-Cryst. Solids 54 (1983) 335.

    Google Scholar 

  2. B. E. Yoldas, ibid. 38–39 (1980) 81.

    Google Scholar 

  3. P. P. Bihuniak and R. A. Condrate Sr, ibid. 44 (1981) 331.

    Google Scholar 

  4. Zhu Congshen, Hou Lisong, Gan Fuxi and Jiang Zhonghong, ibid. 63 (1984) 105.

    Google Scholar 

  5. M. Nogami, ibid. 69 (1985) 415.

    Google Scholar 

  6. S. S. D'Yakanov, V. I. Lygin, B. Z. Shalumov, K. L. Shepalin, A. I. Kuznetsov, V. M. Kostina and Y. I. Rastorguev, Trans. Izv. Akad. Neorg. Mat. 20 (1984) 97.

    Google Scholar 

  7. S. W. Lee, MS thesis, Alfred University (1986).

  8. F. L. Galeener, Solid State Commun. 44 (1982) 1037.

    Google Scholar 

  9. F. L. Galeener and A. E. Geissberger, Phys. Rev. B 27 (1983) 6199.

    Google Scholar 

  10. C. J. Brinker, E. P. Roth, G. W. Scherer and D. R. Tallant, J. Non-Cryst. Solids 71 (1985) 171.

    Google Scholar 

  11. A. G. Revesz and G. E. Walrafen, ibid. 54 (1983) 323.

    Google Scholar 

  12. J. C. Phillips, Phys. Rev. B 32 (1985) 5350.

    Google Scholar 

  13. M. Nogami, J. Amer. Ceram. Soc. 67 (1984) c258.

    Google Scholar 

  14. C. J. Brinker and G. W. Scherer, J. Non-Cryst. Solids 70 (1985) 301.

    Google Scholar 

  15. C. J. Brinker, G. W. Scherer and E. P. Roth, ibid. 72 (1985) 345.

    Google Scholar 

  16. G. W. Scherer, C. J. Brinker and E. P. Roth, ibid. 72 (1985) 369.

    Google Scholar 

  17. A. Bertoluzza, C. Fagnano and M. A. Morelli, ibid. 48 (1982) 117.

    Google Scholar 

  18. M. F. Best and R. A. Condrate Sr, J. Mater. Sci. Lett. 4 (1985) 994.

    Google Scholar 

  19. C. V. Edney, R. A. Condrate Sr, W. B. Crandall and M. E. Washburn, ibid. 6 (1987) 308.

    Google Scholar 

  20. N. M. Bobkava, Zh. S. Tizhovka, V. V. Tizhovka and N. G. Cherenda, Trans. Zhur. Prikl. Spek. 31 (1979) 1075.

    Google Scholar 

  21. R. Hubin and P. Tarte, Spectrochim. Acta 27A (1971) 683.

    Google Scholar 

  22. P. Dawson, M. M. Hargreave and G. R. Wilkinson, J. Phys. C 4 (1971) 240.

    Google Scholar 

  23. J. H. Nicola and H. N. Rutt, ibid. 7 (1974) 1381.

    Google Scholar 

  24. F. Conzalez-Vilchez and W. P. Griffith, J. Chem. Soc. Dalton II (1972) 1416.

  25. A. E. Pasto and R. A. Condrate Sr, Adv. Raman Spectrosc. 1 (1972) 196.

    Google Scholar 

  26. E. Anastassakis, B. Papanicolaou and I. M. Asher, J. Phys. Chem. Solids 36 (1975) 667.

    Google Scholar 

  27. H. Arash and M. Ishigame, Phys. Status Solidi (a) 71 (1982) 313.

    Google Scholar 

  28. V. G. Keramidas and W. B. White, J. Amer. Ceram. Soc. 57 (1974) 22.

    Google Scholar 

  29. C. M. Phillipi and K. S. Mazdiyasni, ibid. 54 (1971) 254.

    Google Scholar 

  30. D. P. C. Thackeray, Spectrochim. Acta 30A (1974) 549.

    Google Scholar 

  31. V. I. Aleksandrov, Yu. K. Voron'ko, B. V. Ignat'ev, E. E. Lomonova, V. V. Osiko and A. A. Sobol', Sov. Phys. Solid State 20 (1978) 305.

    Google Scholar 

  32. A. Feinberg and C. H. Perry, J. Phys. Chem. Solids 42 (1981) 513.

    Google Scholar 

  33. C. H. Perry and D. W. Liu, J. Amer. Ceram. Soc. 68 (1985) c184.

    Google Scholar 

  34. R. C. Garvie, J. Phys. Chem. 69 (1965) 1238.

    Google Scholar 

  35. F. F. Lange and D. J. Green, Adv. Ceram. 3 (1980) 217.

    Google Scholar 

  36. T. Mitsuhashi, M. Ichihara and U. Tatsuke, J. Amer. Ceram. Soc. 57 (1974) 97.

    Google Scholar 

  37. R. C. Garvie, J. Phys. Chem. 82 (1978) 218.

    Google Scholar 

  38. A. H. Heuer, N. Claussen, W. M. Kriven and M. Ruhle, J. Amer. Ceram. Soc. 65 (1982) 642.

    Google Scholar 

  39. I. Muller and W. Muller, Adv. Ceram. 12 (1983) 443.

    Google Scholar 

  40. M. Nogami and M. Tomozawa, J. Amer. Ceram. Soc. 69 (1986) 99.

    Google Scholar 

  41. S. C. Cherukuri, L. D. Pye, I. N. Chakraborty, R. A. Condrate Sr, J. R. Ferraro, B. C. Cornilsen and K. Martin, Spectrosc. Lett. 18 (1985) 123.

    Google Scholar 

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  1. Institute of Glass Science and Engineering, NYS College of Ceramics, Alfred University, 14802, Alfred, New York, USA

    S. W. Lee & R. A. Condrate Sr

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  1. S. W. Lee
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Lee, S.W., Condrate, R.A. The infrared and Raman spectra of ZrO2-SiO2 glasses prepared by a sol-gel process. J Mater Sci 23, 2951–2959 (1988). https://doi.org/10.1007/BF00547474

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