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Determination of tertiary amines in non-aqueous solvents in the presence of primary and secondary amines

Application to 1:3 BADGE/m-XDA equivalent ratio epoxy-amine formulations

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  • Organic Analysis And Organic Materials
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Summary

In the formation of tertiary amines in the mechanism of the reaction of 1:3 BADGE/m-XDA (bisphenol A diglycidyl ether/m-xylylenediamine) equivalent ratio epoxy-amine formulations, we have used FAB mass spectrometry to confirm the different mechanisms of epoxy-amine reactions described by Shechter et al. (3) and have adapted a reaction to give a fluorescent adduct with tertiary amines for their colorimetric determination in the presence of primary and secondary amines, reporting several advantages over the previous method.

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Authors and Affiliations

  1. Departamento de Química Analítica, Nutrición y Bromatología, Area de Nutrición y Bromatología, Universidad de Santiago de Compostela, Facultad de Farmacia, E-15706, Santiago de Compostela (La Coruña), Spain

    P. López Mahía, J. Simal Gándara, P. Paseiro Losada & J. Simal Lozano

  2. Gairesa, Departamento de Investigación, Lago-Valdoviño (La Coruña), Spain

    S. Paz Abuín

Authors
  1. P. López Mahía
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  2. J. Simal Gándara
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  3. P. Paseiro Losada
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  4. S. Paz Abuín
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  5. J. Simal Lozano
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Mahía, P.L., Gándara, J.S., Losada, P.P. et al. Determination of tertiary amines in non-aqueous solvents in the presence of primary and secondary amines. Fresenius J Anal Chem 342, 581–585 (1992). https://doi.org/10.1007/BF00321917

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  • DOI: https://doi.org/10.1007/BF00321917

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