##############################################################################
#                                                                            #
# This CIF contains the data for a data article accepted for                 #
# publication in IUCrData. It conforms to the requirements of                #
# Notes for Authors for IUCrData, and has been                               #
# peer reviewed under the auspices of IUCrData.                              #
#                                                                            #
# Full details of the Crystallographic Information File format               #
# are given in the paper "The Crystallographic Information File (CIF):       #
# a New Standard Archive File for Crystallography" by S. R. Hall, F. H.      #
# Allen and I. D. Brown [Acta Cryst. (1991), A47, 655-685].                  #
#                                                                            #
# The current version of the core CIF dictionary is obtainable from          #
# ftp://ftp.iucr.org/pub/cif_core.dic.                                       #
#                                                                            #
# Software is freely available for graphical display of the structure(s)     #
# in this CIF. For information consult the CIF software page                 #
# http://www.iucr.org/resources/cif/software.                                #
#                                                                            #
# This file may be used for bona fide research purposes within the           #
# scientific community so long as proper attribution is given to the data    # 
# article from which it was obtained.                                        #
#                                                                            #
##############################################################################
data_I
_audit_creation_method     SHELXL-97
_chemical_name_systematic
;\
Bis[2-(dimethylamino-κN)-α,α-diphenylbenzenemethanolato-κO]\
(tetrahydrofuran-κO)magnesium(II)
;
_chemical_name_common     ?
_chemical_formula_moiety     'C46 H48 Mg N2 O3'
_chemical_formula_sum     'C46 H48 Mg N2 O3'
_chemical_formula_iupac     '[Mg (C21 H20 N O2)2 (C4 H8 O)]'
_chemical_formula_weight     701.17
_chemical_melting_point     ?
_symmetry_cell_setting     triclinic
_symmetry_space_group_name_H-M     'P -1'
_symmetry_space_group_name_Hall     '-P 1'
loop_
    _symmetry_equiv_pos_as_xyz
    'x, y, z'
    '-x, -y, -z'
_cell_length_a     9.5014(15)
_cell_length_b     13.801(2)
_cell_length_c     15.834(3)
_cell_angle_alpha     66.375(4)
_cell_angle_beta     89.911(4)
_cell_angle_gamma     81.735(4)
_cell_volume     1878.9(5)
_cell_formula_units_Z     2
_cell_measurement_reflns_used     6887
_cell_measurement_theta_min     1.41
_cell_measurement_theta_max     23.25
_cell_measurement_temperature     208(2)
_cell_special_details     char
_exptl_crystal_description     plate
_exptl_crystal_colour     colorless
_exptl_crystal_size_max     0.15
_exptl_crystal_size_mid     0.10
_exptl_crystal_size_min     0.08
_exptl_crystal_density_diffrn     1.239
_exptl_crystal_density_meas     ?
_exptl_crystal_density_method     'not measured'
_exptl_crystal_F_000     748
_exptl_absorpt_coefficient_mu     0.092
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details
;
(SADABS; Sheldrick, 1996)
;
_exptl_absorpt_correction_T_min     0.9894
_exptl_absorpt_correction_T_max     0.9927
_exptl_special_details     ?
_diffrn_ambient_temperature     208(2)
_diffrn_radiation_type     MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_source     'fine-focus sealed tube'
_diffrn_radiation_monochromator     graphite
_diffrn_measurement_device_type     'Bruker SMART APEX area detector'
_diffrn_measurement_method     'Phi and omega scans'
_diffrn_detector_area_resol_mean     ?
_diffrn_reflns_number     6887
_diffrn_reflns_av_R_equivalents     0.0606
_diffrn_reflns_av_sigmaI/netI     0.1245
_diffrn_reflns_theta_min     1.41
_diffrn_reflns_theta_max     23.25
_diffrn_reflns_theta_full     23.25
_diffrn_measured_fraction_theta_max     0.974
_diffrn_measured_fraction_theta_full     0.974
_diffrn_reflns_limit_h_min     -7
_diffrn_reflns_limit_h_max     10
_diffrn_reflns_limit_k_min     -15
_diffrn_reflns_limit_k_max     13
_diffrn_reflns_limit_l_min     -17
_diffrn_reflns_limit_l_max     14
_diffrn_standards_number     ?
_diffrn_standards_interval_count     ?
_diffrn_standards_interval_time     ?
_diffrn_standards_decay_%     ?
_refine_special_details
;
 Refinement of F² against ALL reflections.  The weighted R-factor wR and
 goodness of fit S are based on F², conventional R-factors R are based
 on F, with F set to zero for negative F². The threshold expression of
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is
 not relevant to the choice of reflections for refinement.  R-factors based
 on F² are statistically about twice as large as those based on F, and R-
 factors based on ALL data will be even larger.
All H atoms were positioned geometrically (C---H = 0.93--0.97?Å) and refined
 as riding, with Uiso(H) = 1.2Ueq(C) or 1.5Ueq(methyl C).
;
_reflns_number_total     5408
_reflns_number_gt     2783
_reflns_threshold_expression     >2sigma(I)
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_all     0.1618
_refine_ls_R_factor_gt     0.0866
_refine_ls_wR_factor_gt     0.2172
_refine_ls_wR_factor_ref     0.2500
_refine_ls_goodness_of_fit_ref     1.087
_refine_ls_restrained_S_all     1.087
_refine_ls_number_reflns     5408
_refine_ls_number_parameters     469
_refine_ls_number_restraints     0
_refine_ls_hydrogen_treatment     constr
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
         'calc w=1/[σ²(Fo²)+(0.1205P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary     difmap
_refine_ls_shift/su_max     0.000
_refine_ls_shift/su_mean     0.000
_refine_diff_density_max     0.599
_refine_diff_density_min     -0.328
_refine_ls_extinction_method     none
_refine_ls_extinction_coef     ?
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    Mg Mg 0.0486 0.0363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection
;
SMART (Bruker, 2007)
;
_computing_cell_refinement
;
SAINT (Bruker, 2007)
;
_computing_data_reduction
;
SAINT (Bruker, 2007)
;
_computing_structure_solution
;
SHELXS97 (Sheldrick, 2008)
;
_computing_structure_refinement
;
SHELXL97 (Sheldrick, 2008)
;
_computing_molecular_graphics
;
ORTEP-3 (Farrugia, 2012)
;
_computing_publication_material
;
publCIF (Westrip, 2010)
;
loop_
    _atom_site_type_symbol
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_refinement_flags
    _atom_site_occupancy
    _atom_site_symmetry_multiplicity
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    Mg Mg1 0.1554(2) 0.50201(16) 0.24814(14) 0.0261(5) Uani d . 1 1 . .
    O O1 0.1102(4) 0.3872(3) 0.3537(3) 0.0292(10) Uani d . 1 1 . .
    O O2 0.0645(4) 0.6179(3) 0.1421(3) 0.0282(10) Uani d . 1 1 . .
    O O3 0.3757(4) 0.5028(4) 0.2476(3) 0.0413(12) Uani d . 1 1 . .
    N N1 0.1431(5) 0.3850(4) 0.1785(3) 0.0315(13) Uani d . 1 1 . .
    N N2 0.0968(5) 0.6150(4) 0.3196(3) 0.0302(13) Uani d . 1 1 . .
    C C1 0.2249(6) 0.2298(5) 0.3302(4) 0.0279(15) Uani d . 1 1 . .
    C C2 0.2241(6) 0.2794(5) 0.2314(4) 0.0297(15) Uani d . 1 1 . .
    C C3 0.3067(7) 0.2242(5) 0.1876(5) 0.0390(17) Uani d . 1 1 . .
    H H3 0.3031 0.2540 0.1227 0.047 Uiso calc R 1 1 . .
    C C4 0.3934(7) 0.1279(6) 0.2344(5) 0.0437(19) Uani d . 1 1 . .
    H H4 0.4499 0.0949 0.2016 0.052 Uiso calc R 1 1 . .
    C C5 0.3973(7) 0.0804(5) 0.3285(5) 0.0398(18) Uani d . 1 1 . .
    H H5 0.4559 0.0145 0.3613 0.048 Uiso calc R 1 1 . .
    C C6 0.3127(7) 0.1314(5) 0.3748(5) 0.0368(17) Uani d . 1 1 . .
    H H6 0.3147 0.0979 0.4396 0.044 Uiso calc R 1 1 . .
    C C7 -0.0133(6) 0.2342(5) 0.4035(4) 0.0283(15) Uani d . 1 1 . .
    C C8 -0.1289(6) 0.2962(5) 0.4213(4) 0.0312(16) Uani d . 1 1 . .
    H H8 -0.1177 0.3624 0.4221 0.037 Uiso calc R 1 1 . .
    C C9 -0.2602(7) 0.2618(6) 0.4378(5) 0.0417(18) Uani d . 1 1 . .
    H H9 -0.3364 0.3052 0.4496 0.050 Uiso calc R 1 1 . .
    C C10 -0.2816(8) 0.1655(6) 0.4373(5) 0.048(2) Uani d . 1 1 . .
    H H10 -0.3703 0.1419 0.4499 0.058 Uiso calc R 1 1 . .
    C C11 -0.1671(8) 0.1044(6) 0.4175(5) 0.048(2) Uani d . 1 1 . .
    H H11 -0.1794 0.0391 0.4152 0.057 Uiso calc R 1 1 . .
    C C12 -0.0359(7) 0.1381(5) 0.4013(5) 0.0417(18) Uani d . 1 1 . .
    H H12 0.0397 0.0950 0.3886 0.050 Uiso calc R 1 1 . .
    C C13 0.2103(6) 0.2382(5) 0.4881(4) 0.0279(15) Uani d . 1 1 . .
    C C14 0.3345(7) 0.2805(5) 0.4934(5) 0.0404(18) Uani d . 1 1 . .
    H H14 0.3685 0.3284 0.4392 0.048 Uiso calc R 1 1 . .
    C C15 0.4076(8) 0.2524(6) 0.5781(5) 0.049(2) Uani d . 1 1 . .
    H H15 0.4900 0.2816 0.5808 0.058 Uiso calc R 1 1 . .
    C C16 0.3590(8) 0.1814(6) 0.6583(5) 0.0460(19) Uani d . 1 1 . .
    H H16 0.4086 0.1622 0.7154 0.055 Uiso calc R 1 1 . .
    C C17 0.2375(8) 0.1387(5) 0.6542(5) 0.0409(18) Uani d . 1 1 . .
    H H17 0.2046 0.0901 0.7084 0.049 Uiso calc R 1 1 . .
    C C18 0.1641(7) 0.1681(5) 0.5695(5) 0.0366(17) Uani d . 1 1 . .
    H H18 0.0808 0.1394 0.5676 0.044 Uiso calc R 1 1 . .
    C C19 0.1316(6) 0.2769(5) 0.3901(4) 0.0265(15) Uani d . 1 1 . .
    C C20 -0.0118(7) 0.3809(5) 0.1751(5) 0.0378(17) Uani d . 1 1 . .
    H H20A -0.0631 0.4521 0.1393 0.057 Uiso calc R 1 1 . .
    H H20B -0.0440 0.3547 0.2374 0.057 Uiso calc R 1 1 . .
    H H20C -0.0298 0.3331 0.1465 0.057 Uiso calc R 1 1 . .
    C C21 0.1823(8) 0.4356(5) 0.0812(4) 0.0419(18) Uani d . 1 1 . .
    H H21A 0.1241 0.5053 0.0505 0.063 Uiso calc R 1 1 . .
    H H21B 0.1664 0.3906 0.0494 0.063 Uiso calc R 1 1 . .
    H H21C 0.2821 0.4439 0.0802 0.063 Uiso calc R 1 1 . .
    C C22 0.1243(6) 0.7708(5) 0.1704(4) 0.0289(15) Uani d . 1 1 . .
    C C23 0.1367(6) 0.7208(5) 0.2690(4) 0.0302(16) Uani d . 1 1 . .
    C C24 0.1913(7) 0.7727(5) 0.3169(5) 0.0380(17) Uani d . 1 1 . .
    H H24 0.1947 0.7413 0.3818 0.046 Uiso calc R 1 1 . .
    C C25 0.2409(7) 0.8686(5) 0.2738(5) 0.0435(19) Uani d . 1 1 . .
    H H25 0.2771 0.9014 0.3090 0.052 Uiso calc R 1 1 . .
    C C26 0.2372(7) 0.9166(5) 0.1781(5) 0.0394(18) Uani d . 1 1 . .
    H H26 0.2735 0.9809 0.1477 0.047 Uiso calc R 1 1 . .
    C C27 0.1783(7) 0.8672(5) 0.1284(5) 0.0356(17) Uani d . 1 1 . .
    H H27 0.1747 0.9001 0.0635 0.043 Uiso calc R 1 1 . .
    C C28 0.1133(7) 0.7659(5) 0.0112(4) 0.0310(16) Uani d . 1 1 . .
    C C29 0.2492(7) 0.7159(5) 0.0031(5) 0.0405(18) Uani d . 1 1 . .
    H H29 0.2995 0.6622 0.0562 0.049 Uiso calc R 1 1 . .
    C C30 0.3110(8) 0.7438(6) -0.0809(5) 0.049(2) Uani d . 1 1 . .
    H H30 0.4021 0.7094 -0.0847 0.059 Uiso calc R 1 1 . .
    C C31 0.2372(8) 0.8228(6) -0.1596(5) 0.053(2) Uani d . 1 1 . .
    H H31 0.2790 0.8419 -0.2168 0.063 Uiso calc R 1 1 . .
    C C32 0.1054(8) 0.8729(6) -0.1549(5) 0.048(2) Uani d . 1 1 . .
    H H32 0.0555 0.9259 -0.2084 0.057 Uiso calc R 1 1 . .
    C C33 0.0444(7) 0.8446(5) -0.0691(4) 0.0363(17) Uani d . 1 1 . .
    H H33 -0.0462 0.8803 -0.0661 0.044 Uiso calc R 1 1 . .
    C C34 -0.1109(6) 0.7775(5) 0.0944(4) 0.0249(15) Uani d . 1 1 . .
    C C35 -0.1616(7) 0.8754(5) 0.0983(5) 0.0394(18) Uani d . 1 1 . .
    H H35 -0.0970 0.9143 0.1107 0.047 Uiso calc R 1 1 . .
    C C36 -0.3063(8) 0.9166(6) 0.0843(5) 0.047(2) Uani d . 1 1 . .
    H H36 -0.3382 0.9823 0.0881 0.056 Uiso calc R 1 1 . .
    C C37 -0.4032(8) 0.8619(6) 0.0648(5) 0.050(2) Uani d . 1 1 . .
    H H37 -0.5009 0.8897 0.0551 0.060 Uiso calc R 1 1 . .
    C C38 -0.3532(7) 0.7650(6) 0.0599(5) 0.047(2) Uani d . 1 1 . .
    H H38 -0.4176 0.7266 0.0465 0.057 Uiso calc R 1 1 . .
    C C39 -0.2086(7) 0.7241(6) 0.0746(4) 0.0390(18) Uani d . 1 1 . .
    H H39 -0.1769 0.6583 0.0709 0.047 Uiso calc R 1 1 . .
    C C40 0.0491(6) 0.7286(5) 0.1068(4) 0.0284(15) Uani d . 1 1 . .
    C C41 -0.0609(6) 0.6210(5) 0.3222(5) 0.0355(17) Uani d . 1 1 . .
    H H41A -0.0841 0.5497 0.3554 0.053 Uiso calc R 1 1 . .
    H H41B -0.1034 0.6506 0.2596 0.053 Uiso calc R 1 1 . .
    H H41C -0.0977 0.6664 0.3532 0.053 Uiso calc R 1 1 . .
    C C42 0.1561(8) 0.5613(5) 0.4173(4) 0.0433(18) Uani d . 1 1 . .
    H H42A 0.1259 0.4917 0.4463 0.065 Uiso calc R 1 1 . .
    H H42B 0.1215 0.6048 0.4505 0.065 Uiso calc R 1 1 . .
    H H42C 0.2593 0.5523 0.4187 0.065 Uiso calc R 1 1 . .
    C C43 0.4484(7) 0.5857(6) 0.2551(6) 0.054(2) Uani d . 1 1 . .
    H H43A 0.4169 0.6013 0.3079 0.065 Uiso calc R 1 1 . .
    H H43B 0.4292 0.6517 0.1988 0.065 Uiso calc R 1 1 . .
    C C44 0.6045(8) 0.5402(7) 0.2684(6) 0.065(3) Uani d . 1 1 . .
    H H44A 0.6627 0.5971 0.2414 0.078 Uiso calc R 1 1 . .
    H H44B 0.6337 0.5003 0.3341 0.078 Uiso calc R 1 1 . .
    C C45 0.6175(8) 0.4679(7) 0.2189(6) 0.063(2) Uani d . 1 1 . .
    H H45A 0.7014 0.4123 0.2430 0.076 Uiso calc R 1 1 . .
    H H45B 0.6240 0.5080 0.1525 0.076 Uiso calc R 1 1 . .
    C C46 0.4823(7) 0.4202(6) 0.2386(5) 0.048(2) Uani d . 1 1 . .
    H H46A 0.4534 0.4023 0.1879 0.057 Uiso calc R 1 1 . .
    H H46B 0.4951 0.3551 0.2958 0.057 Uiso calc R 1 1 . .
_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    Mg1 O1 . 1.887(4) ?
    Mg1 O2 . 1.891(4) ?
    Mg1 O3 . 2.095(4) ?
    Mg1 N2 . 2.277(5) ?
    Mg1 N1 . 2.306(6) ?
    O1 C19 . 1.378(7) ?
    O2 C40 . 1.386(7) ?
    O3 C43 . 1.461(8) ?
    O3 C46 . 1.464(8) ?
    N1 C2 . 1.456(8) ?
    N1 C20 . 1.484(8) ?
    N1 C21 . 1.486(8) ?
    N2 C23 . 1.462(7) ?
    N2 C41 . 1.490(7) ?
    N2 C42 . 1.492(8) ?
    C1 C6 . 1.396(9) ?
    C1 C2 . 1.433(9) ?
    C1 C19 . 1.560(8) ?
    C2 C3 . 1.389(9) ?
    C3 C4 . 1.375(9) ?
    C3 H3 . 0.9400 ?
    C4 C5 . 1.365(10) ?
    C4 H4 . 0.9400 ?
    C5 C6 . 1.388(9) ?
    C5 H5 . 0.9400 ?
    C6 H6 . 0.9400 ?
    C7 C12 . 1.387(9) ?
    C7 C8 . 1.393(8) ?
    C7 C19 . 1.556(8) ?
    C8 C9 . 1.386(9) ?
    C8 H8 . 0.9400 ?
    C9 C10 . 1.375(9) ?
    C9 H9 . 0.9400 ?
    C10 C11 . 1.393(10) ?
    C10 H10 . 0.9400 ?
    C11 C12 . 1.381(9) ?
    C11 H11 . 0.9400 ?
    C12 H12 . 0.9400 ?
    C13 C18 . 1.382(9) ?
    C13 C14 . 1.407(9) ?
    C13 C19 . 1.575(9) ?
    C14 C15 . 1.393(9) ?
    C14 H14 . 0.9400 ?
    C15 C16 . 1.384(9) ?
    C15 H15 . 0.9400 ?
    C16 C17 . 1.382(9) ?
    C16 H16 . 0.9400 ?
    C17 C18 . 1.390(9) ?
    C17 H17 . 0.9400 ?
    C18 H18 . 0.9400 ?
    C20 H20A . 0.9700 ?
    C20 H20B . 0.9700 ?
    C20 H20C . 0.9700 ?
    C21 H21A . 0.9700 ?
    C21 H21B . 0.9700 ?
    C21 H21C . 0.9700 ?
    C22 C27 . 1.401(8) ?
    C22 C23 . 1.429(8) ?
    C22 C40 . 1.566(9) ?
    C23 C24 . 1.378(9) ?
    C24 C25 . 1.376(9) ?
    C24 H24 . 0.9400 ?
    C25 C26 . 1.387(10) ?
    C25 H25 . 0.9400 ?
    C26 C27 . 1.393(9) ?
    C26 H26 . 0.9400 ?
    C27 H27 . 0.9400 ?
    C28 C33 . 1.384(9) ?
    C28 C29 . 1.405(9) ?
    C28 C40 . 1.547(9) ?
    C29 C30 . 1.383(10) ?
    C29 H29 . 0.9400 ?
    C30 C31 . 1.389(10) ?
    C30 H30 . 0.9400 ?
    C31 C32 . 1.358(10) ?
    C31 H31 . 0.9400 ?
    C32 C33 . 1.403(9) ?
    C32 H32 . 0.9400 ?
    C33 H33 . 0.9400 ?
    C34 C39 . 1.373(9) ?
    C34 C35 . 1.393(9) ?
    C34 C40 . 1.550(8) ?
    C35 C36 . 1.392(9) ?
    C35 H35 . 0.9400 ?
    C36 C37 . 1.377(10) ?
    C36 H36 . 0.9400 ?
    C37 C38 . 1.387(10) ?
    C37 H37 . 0.9400 ?
    C38 C39 . 1.391(9) ?
    C38 H38 . 0.9400 ?
    C39 H39 . 0.9400 ?
    C41 H41A . 0.9700 ?
    C41 H41B . 0.9700 ?
    C41 H41C . 0.9700 ?
    C42 H42A . 0.9700 ?
    C42 H42B . 0.9700 ?
    C42 H42C . 0.9700 ?
    C43 C44 . 1.505(10) ?
    C43 H43A . 0.9800 ?
    C43 H43B . 0.9800 ?
    C44 C45 . 1.489(12) ?
    C44 H44A . 0.9800 ?
    C44 H44B . 0.9800 ?
    C45 C46 . 1.503(9) ?
    C45 H45A . 0.9800 ?
    C45 H45B . 0.9800 ?
    C46 H46A . 0.9800 ?
    C46 H46B . 0.9800 ?
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    O1 Mg1 O2 . . 140.1(2) ?
    O1 Mg1 O3 . . 110.6(2) ?
    O2 Mg1 O3 . . 109.3(2) ?
    O1 Mg1 N2 . . 89.85(19) ?
    O2 Mg1 N2 . . 84.29(19) ?
    O3 Mg1 N2 . . 98.27(19) ?
    O1 Mg1 N1 . . 83.25(19) ?
    O2 Mg1 N1 . . 90.97(19) ?
    O3 Mg1 N1 . . 98.81(19) ?
    N2 Mg1 N1 . . 162.9(2) ?
    C19 O1 Mg1 . . 138.6(4) ?
    C40 O2 Mg1 . . 136.4(4) ?
    C43 O3 C46 . . 108.7(5) ?
    C43 O3 Mg1 . . 126.0(4) ?
    C46 O3 Mg1 . . 125.3(4) ?
    C2 N1 C20 . . 111.2(5) ?
    C2 N1 C21 . . 114.3(5) ?
    C20 N1 C21 . . 106.7(5) ?
    C2 N1 Mg1 . . 112.5(4) ?
    C20 N1 Mg1 . . 102.3(4) ?
    C21 N1 Mg1 . . 109.0(4) ?
    C23 N2 C41 . . 111.3(5) ?
    C23 N2 C42 . . 114.0(5) ?
    C41 N2 C42 . . 106.7(5) ?
    C23 N2 Mg1 . . 112.8(4) ?
    C41 N2 Mg1 . . 102.3(3) ?
    C42 N2 Mg1 . . 108.8(4) ?
    C6 C1 C2 . . 117.2(6) ?
    C6 C1 C19 . . 118.3(5) ?
    C2 C1 C19 . . 124.5(5) ?
    C3 C2 C1 . . 117.6(6) ?
    C3 C2 N1 . . 120.7(6) ?
    C1 C2 N1 . . 121.7(5) ?
    C4 C3 C2 . . 123.2(7) ?
    C4 C3 H3 . . 118.4 ?
    C2 C3 H3 . . 118.4 ?
    C5 C4 C3 . . 119.9(6) ?
    C5 C4 H4 . . 120.1 ?
    C3 C4 H4 . . 120.1 ?
    C4 C5 C6 . . 118.6(7) ?
    C4 C5 H5 . . 120.7 ?
    C6 C5 H5 . . 120.7 ?
    C5 C6 C1 . . 123.4(7) ?
    C5 C6 H6 . . 118.3 ?
    C1 C6 H6 . . 118.3 ?
    C12 C7 C8 . . 117.4(6) ?
    C12 C7 C19 . . 125.3(6) ?
    C8 C7 C19 . . 117.4(5) ?
    C9 C8 C7 . . 121.0(6) ?
    C9 C8 H8 . . 119.5 ?
    C7 C8 H8 . . 119.5 ?
    C10 C9 C8 . . 121.6(6) ?
    C10 C9 H9 . . 119.2 ?
    C8 C9 H9 . . 119.2 ?
    C9 C10 C11 . . 117.6(6) ?
    C9 C10 H10 . . 121.2 ?
    C11 C10 H10 . . 121.2 ?
    C12 C11 C10 . . 121.1(7) ?
    C12 C11 H11 . . 119.5 ?
    C10 C11 H11 . . 119.5 ?
    C11 C12 C7 . . 121.4(6) ?
    C11 C12 H12 . . 119.3 ?
    C7 C12 H12 . . 119.3 ?
    C18 C13 C14 . . 117.7(6) ?
    C18 C13 C19 . . 124.8(6) ?
    C14 C13 C19 . . 117.5(5) ?
    C15 C14 C13 . . 120.7(6) ?
    C15 C14 H14 . . 119.6 ?
    C13 C14 H14 . . 119.6 ?
    C16 C15 C14 . . 120.1(7) ?
    C16 C15 H15 . . 119.9 ?
    C14 C15 H15 . . 119.9 ?
    C17 C16 C15 . . 119.8(7) ?
    C17 C16 H16 . . 120.1 ?
    C15 C16 H16 . . 120.1 ?
    C16 C17 C18 . . 119.8(7) ?
    C16 C17 H17 . . 120.1 ?
    C18 C17 H17 . . 120.1 ?
    C13 C18 C17 . . 121.8(6) ?
    C13 C18 H18 . . 119.1 ?
    C17 C18 H18 . . 119.1 ?
    O1 C19 C7 . . 110.7(5) ?
    O1 C19 C1 . . 113.0(5) ?
    C7 C19 C1 . . 109.6(5) ?
    O1 C19 C13 . . 106.3(5) ?
    C7 C19 C13 . . 108.0(5) ?
    C1 C19 C13 . . 109.0(5) ?
    N1 C20 H20A . . 109.5 ?
    N1 C20 H20B . . 109.5 ?
    H20A C20 H20B . . 109.5 ?
    N1 C20 H20C . . 109.5 ?
    H20A C20 H20C . . 109.5 ?
    H20B C20 H20C . . 109.5 ?
    N1 C21 H21A . . 109.5 ?
    N1 C21 H21B . . 109.5 ?
    H21A C21 H21B . . 109.5 ?
    N1 C21 H21C . . 109.5 ?
    H21A C21 H21C . . 109.5 ?
    H21B C21 H21C . . 109.5 ?
    C27 C22 C23 . . 116.9(6) ?
    C27 C22 C40 . . 118.1(5) ?
    C23 C22 C40 . . 125.0(5) ?
    C24 C23 C22 . . 118.9(6) ?
    C24 C23 N2 . . 119.6(6) ?
    C22 C23 N2 . . 121.4(5) ?
    C25 C24 C23 . . 122.8(7) ?
    C25 C24 H24 . . 118.6 ?
    C23 C24 H24 . . 118.6 ?
    C24 C25 C26 . . 119.8(6) ?
    C24 C25 H25 . . 120.1 ?
    C26 C25 H25 . . 120.1 ?
    C25 C26 C27 . . 118.3(6) ?
    C25 C26 H26 . . 120.8 ?
    C27 C26 H26 . . 120.8 ?
    C26 C27 C22 . . 123.1(6) ?
    C26 C27 H27 . . 118.4 ?
    C22 C27 H27 . . 118.4 ?
    C33 C28 C29 . . 116.7(6) ?
    C33 C28 C40 . . 124.4(6) ?
    C29 C28 C40 . . 118.9(5) ?
    C30 C29 C28 . . 121.7(6) ?
    C30 C29 H29 . . 119.2 ?
    C28 C29 H29 . . 119.2 ?
    C29 C30 C31 . . 119.5(7) ?
    C29 C30 H30 . . 120.2 ?
    C31 C30 H30 . . 120.2 ?
    C32 C31 C30 . . 120.7(7) ?
    C32 C31 H31 . . 119.7 ?
    C30 C31 H31 . . 119.7 ?
    C31 C32 C33 . . 119.3(7) ?
    C31 C32 H32 . . 120.4 ?
    C33 C32 H32 . . 120.4 ?
    C28 C33 C32 . . 122.2(7) ?
    C28 C33 H33 . . 118.9 ?
    C32 C33 H33 . . 118.9 ?
    C39 C34 C35 . . 117.5(6) ?
    C39 C34 C40 . . 118.7(6) ?
    C35 C34 C40 . . 123.8(6) ?
    C36 C35 C34 . . 121.2(7) ?
    C36 C35 H35 . . 119.4 ?
    C34 C35 H35 . . 119.4 ?
    C37 C36 C35 . . 120.7(7) ?
    C37 C36 H36 . . 119.7 ?
    C35 C36 H36 . . 119.7 ?
    C36 C37 C38 . . 118.5(7) ?
    C36 C37 H37 . . 120.8 ?
    C38 C37 H37 . . 120.8 ?
    C37 C38 C39 . . 120.5(7) ?
    C37 C38 H38 . . 119.8 ?
    C39 C38 H38 . . 119.8 ?
    C34 C39 C38 . . 121.7(7) ?
    C34 C39 H39 . . 119.2 ?
    C38 C39 H39 . . 119.2 ?
    O2 C40 C28 . . 106.9(5) ?
    O2 C40 C34 . . 110.3(5) ?
    C28 C40 C34 . . 109.0(5) ?
    O2 C40 C22 . . 113.1(5) ?
    C28 C40 C22 . . 110.0(5) ?
    C34 C40 C22 . . 107.4(5) ?
    N2 C41 H41A . . 109.5 ?
    N2 C41 H41B . . 109.5 ?
    H41A C41 H41B . . 109.5 ?
    N2 C41 H41C . . 109.5 ?
    H41A C41 H41C . . 109.5 ?
    H41B C41 H41C . . 109.5 ?
    N2 C42 H42A . . 109.5 ?
    N2 C42 H42B . . 109.5 ?
    H42A C42 H42B . . 109.5 ?
    N2 C42 H42C . . 109.5 ?
    H42A C42 H42C . . 109.5 ?
    H42B C42 H42C . . 109.5 ?
    O3 C43 C44 . . 105.3(6) ?
    O3 C43 H43A . . 110.7 ?
    C44 C43 H43A . . 110.7 ?
    O3 C43 H43B . . 110.7 ?
    C44 C43 H43B . . 110.7 ?
    H43A C43 H43B . . 108.8 ?
    C45 C44 C43 . . 103.7(7) ?
    C45 C44 H44A . . 111.0 ?
    C43 C44 H44A . . 111.0 ?
    C45 C44 H44B . . 111.0 ?
    C43 C44 H44B . . 111.0 ?
    H44A C44 H44B . . 109.0 ?
    C44 C45 C46 . . 103.2(6) ?
    C44 C45 H45A . . 111.1 ?
    C46 C45 H45A . . 111.1 ?
    C44 C45 H45B . . 111.1 ?
    C46 C45 H45B . . 111.1 ?
    H45A C45 H45B . . 109.1 ?
    O3 C46 C45 . . 105.4(6) ?
    O3 C46 H46A . . 110.7 ?
    C45 C46 H46A . . 110.7 ?
    O3 C46 H46B . . 110.7 ?
    C45 C46 H46B . . 110.7 ?
    H46A C46 H46B . . 108.8 ?
loop_
    _geom_hbond_atom_site_label_D
    _geom_hbond_atom_site_label_H
    _geom_hbond_atom_site_label_A
    _geom_hbond_site_symmetry_A
    _geom_hbond_distance_DH
    _geom_hbond_distance_HA
    _geom_hbond_distance_DA
    _geom_hbond_angle_DHA
    C20 H20C O1 . 0.97 2.57 3.095(8) 114.1
    C21 H21A O2 . 0.97 2.53 3.105(8) 118.2
    C41 H41C O2 . 0.97 2.58 3.103(8) 114.0
    C42 H42A O1 . 0.97 2.46 3.037(8) 118.2
data_global
_journal_date_recd_electronic     2019-09-30
_journal_date_accepted     2019-10-16
_journal_name_full     'IUCrData'
_journal_year     2019
_journal_volume     4
_journal_issue     10
_journal_page_first     0
_journal_page_last     0
_journal_paper_category     HM
_journal_paper_doi     10.1107/S2414314619014123
_journal_coeditor_code     WM4115
_publ_contact_author_name     'Harbi Tomah Al-Masri'
_publ_contact_author_address
;
Department of Chemistry
Faculty of Sciences
Al al-Bayt University
PO Box 130040
Mafraq 25113
Jordan
;
_publ_contact_author_email     harbialmasri@yahoo.com
_publ_contact_author_phone     oo97795969113
_publ_section_title
;\
Bis[2-(dimethylamino-κN)-α,α-diphenylbenzenemethanolato-κO]\
(tetrahydrofuran-κO)magnesium(II)
;
_publ_section_title_footnote     .
loop_
    _publ_author_name
    _publ_author_footnote
    _publ_author_address
    'Al-Masri, Harbi Tomah' .
;
Department of Chemistry
Faculty of Sciences
Al al-Bayt University
PO Box 130040
Mafraq 25113
Jordan
;
_publ_section_synopsis
;
Isolated molecules are present in the crystal structure of the title complex,
exhibiting a distorted square-pyramidal coordination sphere around the central
MgII atom. The O atom of the tetrahydrofuran molecule occupies the apical
position.
;
