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  • 學位論文

後期金屬錯合物連續合環反應

Late transition-metal catalyzed cascade annulation reaction

指導教授 : 謝仁傑

摘要


利用縮合反應以及氧化還原反應合成所需之前驅物,接著最佳化之前實驗室之合環反應之條件。重新尋找可以催化的金屬,最後以鈀金屬合成出6H–吲哚並[2,3-b]喹啉及其衍生物共19個產物。

並列摘要


We use cyanation reaction, condensation reaction and reduction-oxidation reaction to synthesize the starting materials. Try to optimize the reaction condition of copper catalyst, then screen other kinds of metal. We find that palladium can give high yield of product. Again we optimized the reaction condition of palladium and synthesize a serial of Indolo[2,3-b]quinolone compounds up to 19 cases.

參考文獻


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