This study is based on electrochemical treatment of a single small wasted ammunition , improving the number of ammunition batches processed and recreating its economic value to recover copper and lead-value metals. Optimal processing and recovery conditions by changing operating parameters , and finally the larger experimental device prototype is designed using the best experimental results. The experiment is divided into two parts,one is to observe the operation time for 3 hours, and the other is to extend the operation time to 11 hours in order to completely dissolve the ammunition (calculated by Faraday's Law). The 3-hour experiment can compare the design parameters such as electrolyte concentration, current magnitude, cathode current density, and ammunition model. Then use the 3-hour experiment to plan the parameters required to stretch the experiment to 11 hours. Compare the recovery rate and the electrolyte recovery problem, and the experiment has special design of the electrolytic cell. The electrolytic cell is divided into two groups of experiments with a rolling anode (cathode stationary) and a stationary anode (cathode rotating). The experimental operating parameters were designed as electrolyte concentration: 0.5M and 1M sulfuric acid solution, current size: 2.5 amps and 3 amps, cathode current density: 22.59 mA/cm2, 27.1 mA/cm2, 50.11 mA/cm2, and ammunition model: 9 mm, .22 Long Rifle cartridge, .223 caliber Remington cartridge, .45 Auto,and anode cell material selected to improve electrolyte composition: stainless , plastic , nylon. Experimental results The electrolyte is preferably a 1M sulfuric acid solution. Although the 0.5M electrolyte has a large amount of copper powder precipitated within 3 hours, in the 11-hour experiment, there is electrolyte in the 0.5M sulfuric acid solution. Insufficient phenomenon, it is necessary to add a procedure to stabilize the voltage of the electrolyte. The effect of the current magnitude is small, so 2.5 amps with lower current (less energy consumption) is used as the operating condition. The current density measured by the cathode current efficiency of 27.1 mA/cm2 is a good result, not the larger the current density, the better or the smaller the better. Different ammunition models are used to compare whether different ammunitions affect the anode electrolytic dissolution. The experimental results prove that they are not affected and the anode current efficiency is 100%. Therefore, this set of procedures is very effective for ammunition dissolution. At present, there is no such similar procedure in ammunition treatment technology, which is simple metal recovery or propellant recycling. The US Department of Defense points out that it can get $2,000 for a disposal of abandoned ammunition, and this research procedure can not only get the government. The grant of subsidies and the ability to sell recycled copper and lead metals will bring unlimited business opportunities.