This study proposes a novel method of fabricating silver chloride films by the precipitation of sodium chloride aqueous solution and solid-state silver nitrate aqueous solution .Bulk-type silver chloride film was obtained by melting and solidification of silver chloride powder. The effect of different sintering temperature and time to the morphology of both silver chloride films was discussed. The morphology of the precipitation-type AgCl bottom-surface is full of radial porous stick structure ,and the top-surface is composed of equiaxed grains. For precipitation-type AgCl films, the interface diffusion shows remarkable effect only at high sintering temperatures while diffusion-controlled growth is predominant at low sintering temperatures. The activation energy of interface-controlled growth of precipitation-type AgCl film is calculated to be approximately 50.2kJ/mol ,and 9.84 kJ/mol for diffusion controlled growth. The morphology of bulk-type AgCl after air-cooling can be identified as radial grains, feather-like grains and feather-like columnar grains. Large grains with feather-like morphology were formed under furnace-cooling. The morphology of Bulk-type AgCl is dominated greatly by temperature gradient. The growth mechanism of sintered bulk-type AgCl is mainly focused on diffusion-controlled growth, which has the activation energy of 4.2 kJ/mol, while the interface-controlled growth activation energy is about 12.6 kJ/mol. Precipitation-type and bulk-type AgCl films are combined to be manufactured as Dye-Sensitized Solar Cells electrodes, which have porous structures and light-recycling ability. Bulk-type AgCl and ITO glass perform extraordinary wettability and bonding. However, the porous structures grow due to heat and inter-particle necking occurs ,which decreases the quantity of voids.