Column Bioleaching of a Saline, Calcareous Copper Sulfide Ore

Article Preview

Abstract:

“Deep in situ biomining”, widely considered to be a potentially environmentally-benign and cost effective biotechnology for extracting and recovering base metals from deep-buried base metal deposits, is being developed within the EU Horizon 2020 project “BioMOre”. Data are presented from non-aerated column experiments in which a saline, calcareous copper-rich ore (kupferschiefer) was subjected to a three-stage eaching protocol: (i) with water, to remove soluble salts; (ii) with sulfuric acid, to remove calcareous minerals and other acid-soluble salts; (iii) indirect bioleaching with a microbiologically-generated ferric iron lixiviant. Sequential leaching with water and acid removed ~85% of the chloride prior to bio-processing, while ~13% of the copper present in the ore was leached using sulfuric acid, and a further 39 - 59% by the lixiviant.

You might also be interested in these eBooks

Info:

Periodical:

Solid State Phenomena (Volume 262)

Pages:

7-11

Citation:

Online since:

August 2017

Export:

Price:

* - Corresponding Author

[1] D.B. Johnson, Biomining goes underground, Nat. Geosci. 8 (2015) 165-166.

Google Scholar

[2] D.E. Rawlings, Microbially assisted dissolution of minerals and its use in the mining industry, Pure Appl. Chem. 76 (2004) 847-859.

DOI: 10.1351/pac200476040847

Google Scholar

[3] A. Schippers, W. Sand, Bacterial leaching of metal sulfides proceeds by two indirect mechanisms via thiosulfate or via polysulfides and sulfur, Appl. Environ. Microbiol. 65 (1999) 319-321.

DOI: 10.1128/aem.65.1.319-321.1999

Google Scholar

[4] E. Pakostova, B.M. Grail, D.B. Johnson, Indirect oxidative bioleaching of a polymetallic black schist sulfide ore, Miner. Eng. 106 (2017) 102-107.

DOI: 10.1016/j.mineng.2016.08.028

Google Scholar

[5] A.L. Santos, D.B. Johnson, The effects of temperature and pH on the kinetics of an acidophilic sulfidogenic bioreactor and indigenous microbial communities, Hydrometallurgy. 168 (2017) 116-120.

DOI: 10.1016/j.hydromet.2016.07.018

Google Scholar

[6] M.A. Anwar, M. Iqbal, M.A. Qamar, M. Rehman, A.M. Khalid, Technical communication: Determination of cuprous ions in bacterial leachates and for environmental monitoring, World J. Microb. Biot. 16 (2000) 135-138.

Google Scholar

[7] L.L. Stookey, Ferrozine - a new spectrophotometric reagent for iron, Anal. Chem. 42 (1970) 779-781.

DOI: 10.1021/ac60289a016

Google Scholar

[8] R.K. Freier, Wasseranalyse, 2nd ed. Walter de Gruyter, Berlin, Germany, (1974).

Google Scholar

[9] C.M. Kay, O.F. Rowe, L. Rocchetti, K. Coupland, K.B. Hallberg, D.B. Johnson, Evolution of microbial streamer, growths in an acidic, metal-contaminated stream draining an abandoned underground copper mine, Life. 3 (2013) 189-210.

DOI: 10.3390/life3010189

Google Scholar