Luminescent Properties of As-Grown and Vacuum Annealed LiNbO3 Single Crystals

Article Preview

Abstract:

This paper reports on the luminescent properties of the congruent as-grown and vacuum annealed LiNbO3 single crystals at the UV and X-ray excitations. The shape of excitation spectra is similar for all emission bands in as-grown sample as well as in vacuum annealed sample. The emission spectra (exc=235 nm) observed in the spectral region 250…800 nm at room temperature consist of five elementary bands. Correlation of the relative intensities bands in luminescence spectra under different types of excitation and their temperature dependencies were determined. The most intensitive maxima in as-grown sample are observed at 295 and 691 nm. The main maximum after vacuum annealing is peaked around 295 nm.

You might also be interested in these eBooks

Info:

Periodical:

Solid State Phenomena (Volume 200)

Pages:

199-202

Citation:

Online since:

April 2013

Export:

Price:

[1] L. Arizmendi, Photonic applications of lithium niobate crystals, Phys. Stat. Sol. (a) 201 (2004) 253-283.

DOI: 10.1002/pssa.200303911

Google Scholar

[2] T. Volk, M. Wöhlecke, Lithium niobate: defects, photorefraction and ferroelectric switching, Springer, Berlin, 2008.

DOI: 10.1007/978-3-540-70766-0

Google Scholar

[3] L. Arizmendi, J. M. Cabrera, F. Agullo-Lopez, Defects induced in pure and doped LiNbO3 by irradiation and thermal reduction, J. Phys. C: Solid State Phys. 17 (1984) 515-529.

DOI: 10.1088/0022-3719/17/3/021

Google Scholar

[4] A. Dhar, A. Mansingh, Optical properties of reduced lithium niobate single crystals, J. Appl. Phys. 68 (1990) 5804-5809.

DOI: 10.1063/1.346951

Google Scholar

[5] D. Sugak, Ya. Zhydachevskii, Yu. Sugak et al., In-situ investigation of optical absorption changes in LiNbO3 during reducing/oxidizing high-temperature treatments, J. Phys.: Condens. Matter. 19 (2007) 086211-086222.

DOI: 10.1088/0953-8984/19/8/086211

Google Scholar

[6] D.Yu. Sugak, I.M. Solskii, I.I. Syvorotka, M.M. Vakiv, Influence of thermochemical treatment on the optical properties of the lithium niobate single crystals, New Technologies. 1 35 (2012) 3-12 (in Ukrainian).

Google Scholar

[7] L. Arizmendi, J. M. Cabrera, and F. Agullo-Lopez, X-ray induced luminescence of LiNbO3, Solid State Commun. 40 (1981) 583-585.

DOI: 10.1016/0038-1098(81)90579-2

Google Scholar

[8] S.M. Kostritskii, M. Aillerie, S. Margueron, P. Bourson, Two-photon luminescence of small polarons in reduсed LiNbO3 crystals, IOP Conf. Series: Materials Science and Engineering 15 (2010) 012057-012062.

DOI: 10.1088/1757-899x/15/1/012057

Google Scholar

[9] Ill Won Kim, Song Soo Yi, V.F. Pichugin, V.Yu. Yakovlev, M.S. Dmitriev, Luminescence and optical absorption spectra of heavily Mg-doped LiNbO3 single crystals irradiated by pulsed electron beam, J. Cryst. Growth 253 (2003) 319-325.

DOI: 10.1016/s0022-0248(03)01038-8

Google Scholar

[10] V.Yu.Yakovlev, E.V. Kabanova, T. Weber, P. Paufler, Time-resolved optical spectroscopy of LiNbO3 after irradiation with pulsed electron beams, Phys. Stat. Sol. 185 (2001) 423-428.

DOI: 10.1002/1521-396x(200106)185:2<423::aid-pssa423>3.0.co;2-x

Google Scholar

[11] I. Solskii, D. Sugak, V. Gaba, Preparation of optically homogeneous lithium niobate large size single crystals, Tekhnologiya i konstruirovanie v elektronnoi apparature 5 (2005) 51-55 (in Russian).

Google Scholar