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Characterization of Proton Conducting Carboxymethyl Cellulose/Chitosan Dual-Blend Based Biopolymer Electrolytes

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Abstract:

This article presents the discovery on biopolymer electrolytes comprising of ammonium nitrate, NH4NO3 with dual-blend biopolymer materials, carboxymethyl cellulose/chitosan which were prepared via solution-casting technique. The biopolymer blend based electrolyte films were characterized by Fourier Transform Infrared spectroscopy to investigate the formation of the dual-blend biopolymer based complexes. X-Ray Diffraction result showed that all dual-blend samples were predominantly amorphous. Electrochemical impedance spectroscopy was conducted to obtain their ionic conductivities. The highest conductivity at ambient temperature of 1.03 × 10–5 S cm–1 was obtained for the electrolyte film containing 40 wt% of NH4NO3. These results indicated that the dual-blend biopolymer based electrolyte has potential for application of electrochemical devices.

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Periodical:

Materials Science Forum (Volume 846)

Pages:

539-544

DOI:

https://doi.org/10.4028/www.scientific.net/MSF.846.539

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Online since:

March 2016

Authors:

Mohd Saiful Asmal Rani, Nor Sabirin Mohamed, Mohd Ikmar Nizam Isa*

Keywords:

Biopolymer Electrolytes, Carboxymethyl Cellulose, Chitosan, Dual-Blend

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* - Corresponding Author

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