Synthesis of TiO2-rGO Nanocomposite and its Application as Photoanode of Dye-Sensitized Solar Cell (DSSC)

Article Preview

Abstract:

Dye-sensitized solar cells (DSSC) are solar cells that has a great potential to be applied as renewable energy conversion. The major advantages of DSSC are the ease of fabrication process and low cost of production. Despite of these advantages, the efficiency of DSSC for converting light into electricity is still low. It is due to charge recombination in DSSC which limits the photoanode performance. Numerous efforts has been carried out to increase the efficiency of DSSC, one of which is by adding reduced graphene oxide (rGO) to titanium oxide (TiO2) to obtain TiO2-rGO nanocomposite. In this study, the synthesis of TiO2-rGO nanocomposites was carried out with concentration of rGO are 0.6, 0.8, and 1.0 wt% to amount of TiO2. We have done some characterizations to confirm the result of synthesized TiO2-rGO. UV-Vis measurement shows the addition of rGO has widened the absorption up to 400 nm. The FT-IR spectrum confirms that the rGO peaks appears at wavelength of 1400, 1600, dan 1700 cm-1 which exhibited the vibration C-O, C=C, and C=O stretching from COOH groups, respectively. The highest efficiency of DSSC with photoanode TiO2-rGO nanocomposite is 0.09% which was obtained from 0.8 wt% of rGO.

You might also be interested in these eBooks

Info:

Periodical:

Materials Science Forum (Volume 1028)

Pages:

151-156

Citation:

Online since:

April 2021

Export:

Price:

* - Corresponding Author

[1] A. P. Uthirakumar, Fabrication of ZnO Based Dye Sensitized Solar Cells, in: Prof. Leonid A. Kosyachenko (Eds.), Solar Cells - Dye-Sensitized Devices, InTech, 2011, pp.435-456.

DOI: 10.5772/19459

Google Scholar

[2] J. A. Luceno-Sanchez, A.M. Diez-Pascual and R. P. Capilla, Materials for Photovoltaics: State of Art and Recent Developments, Int. J. Mol. Sci. 20 (2019) 976.

Google Scholar

[3] F. W. Low and C. W. Lai, Recent developments of graphene-TiO2 composite nanomaterials as efficient photoelectrodes in dye-sensitized solar cells: A review, Renew. Sustain. Energy Rev. 82 (2018) 103-125.

DOI: 10.1016/j.rser.2017.09.024

Google Scholar

[4] S. Z. Siddick, C. W. Lai, J. C. Juan, and S. B. Hamid, Reduced Graphene Oxide–Titania Nanocomposite Film for Improving Dye-Sensitized Solar Cell (DSSCs) Performance, Curr. Nanosci. 13 (2017) 494-500.

DOI: 10.2174/1573413713666170519123159

Google Scholar

[5] C. P. Lee, C. T. Li, and K. C. Ho, Use of organic materials in dye-sensitized solar cells, Materials Today. 20 (2017) 267-283.

DOI: 10.1016/j.mattod.2017.01.012

Google Scholar

[6] R. Ramamoorthy, V. Eswaramoorthi, M. Sundararajan, M. Boobalan, A. D. Sivagami, and R. V. Williams, Reduced graphene oxide modified titania photoanodes for fabrication of the efficient dye‑sensitized solar cell, J. Mater. Sci. Mater. Electron. 30 (2019) 12966-12980.

DOI: 10.1007/s10854-019-01659-5

Google Scholar

[7] N. Yang, J. Zhai, D. Wang, Y. Chen, and L. Jiag, Two-dimensional graphene bridges enhanced photoinduced charge transport in dyesensitized solar cells, ACS Nano. 4 (2010) 887-894.

DOI: 10.1021/nn901660v

Google Scholar

[8] K. L. Chopra, S. Major, and D. K. Pandya, Transparent Conductors—A Status Review, Thin Solid Films. 102 (1983) 1-46.

DOI: 10.1016/0040-6090(83)90256-0

Google Scholar

[9] C. W. Lai, F. W. Low, S. Z. Siddick and J. C. Juan, Graphene/TiO2 Nanocomposites: Synthesis Routes, Characterization, and Solar Cell Applications. Handbook of Graphene. 4 (2019) 353-394.

DOI: 10.1002/9781119468455.ch64

Google Scholar

[10] N. R. Khalid, E. Ahmed, Z. Hong, L. Sana., and M. Ahmed, Enhanced photocatalytic activity of graphene TiO2 composite under visible light irradiation, Curr. Appl. Phys. 13 (2013) 659-663.

DOI: 10.1016/j.cap.2012.11.003

Google Scholar

[11] L. Safriani, A. Aprilia, S. Suryaningsih, F. Yuliasari, M. R. Nurawan, A. Nuroctaviani et al, The Addition of Reduced Graphene Oxide Layer to TiO2 Photoanode of DSSC Using UV Oven Spraying Method, Key Engineering Materials 860 (2020) 15-21.

DOI: 10.4028/www.scientific.net/kem.860.15

Google Scholar

[12] J. D. Roy-Mayhew, and I. A. Aksay, Graphene materials and their use in dye-sensitized solar cells, Chem. 114 (2014) 6323-6348.

DOI: 10.1021/cr400412a

Google Scholar

[13] U. Kanta, V. Thongpool, W. Sangkhun, N. Wongyao, and J. Wootthikanokkhan, Preparations, Characterizations, and a Comparative Study on Photovoltaic Performance of Two Different Types of Graphene/TiO2 Nanocomposites Photoelectrodes, Journal of Nanomaterials. 2017 (2017) 1-13.

DOI: 10.1155/2017/2758294

Google Scholar