Paper Titles

The Evaluation of Setting Time and FTIR Spectroscopy of Carbonate Apatite Cement as Endodontic Sealer
p.32

Synthesis of Europium(III) Complex-Based Hydroxyapatite Nanocrystals for Biolabeling Applications
p.41

Preparation of Calcium Phosphate Glasses Containing Nb₂O₅ and TiO₂
p.47

Cotton-Wool-Like Resorbable Bone Void Fillers Containing β-TCP and Calcium Carbonate Particles
p.53

Synthesis of Spherical Phosphorus-Containing Mesoporous Silica for Improving their Reaction Behavior in Simulated Body Fluid
p.59

Apatite-Forming Ability of Hydrophobicized Cellulose Nanofiber Imparted by Combination with Apatite Nuclei
p.65

Evaluation of Elution Behavior of Silver Ions from Silver-Containing Carbonate Hydroxyapatite Composites
p.72

Bioactivity Assessment of Apatite Nuclei-PVDF Composite Thin Films
p.78

Fabrication of Novel Hemostatic Film with Oxidized Cellulose and Sugar-Containing Hydroxyapatite
p.84

HomeKey Engineering MaterialsKey Engineering Materials Vol. 782Synthesis of Spherical Phosphorus-Containing...

Synthesis of Spherical Phosphorus-Containing Mesoporous Silica for Improving their Reaction Behavior in Simulated Body Fluid

Article Preview

Abstract:

Spherical phosphorus–containing mesoporous silica (PMPS) particles were synthesized. In the PMPS particle preparation using the cationic surfactant (cetyltrimethylammonium bromide) as the template, the amphiphilic surfactant (Pluronic P123) and diethyl(2–bromoethyl)phosphonate were used for the particle shape control and the phosphorus source, respectively. Furthermore, we investigated the chemical reactions of the PMPS particles in simulated body fluid (SBF). By the phosphorus–containing, the hydroxyapatite formation and silicate ion dissolution ability on the PMPS particle surfaces were enhanced. These characteristic features will be useful for the biomedical applications such as bone formation.

You might also be interested in these eBooks

Bioceramics 30

Info:

Periodical:

Key Engineering Materials (Volume 782)

Pages:

59-64

DOI:

https://doi.org/10.4028/www.scientific.net/KEM.782.59

Citation:

Cite this paper

Online since:

October 2018

Authors:

Yu Cheng Shang, Shota Yamada, Ya Dong Chai, Motohiro Tagaya*

Keywords:

Hydroxyapatite, Mesoporous Silica, Phosphorus-Containing, Simulated Body Fluid (SBF)

Export:

RIS, BibTeX

Price:

Permissions:

Request Permissions

* - Corresponding Author

[1] F. Tang, L. Li, D. Chen, Mesoporous silica nanoparticles: synthesis, biocompatibility and drug delivery, Adv Mater. 22 (2012) 1504–1534.

DOI: 10.1002/adma.201104763

[2] A. Sugawara–Narutaki, Formation of Nanoporous Architectures through The Synergetic Self-assembly of Inorganic Nanoparticles and Amphiphilic Polymers, Bull. Chem. Soc. Japan. 52 (2017) 15–19.

[3] T. Kataoka, L. Wang, K. Kobayashi, M. Nishikawa, M. Tagaya, Incorporation of terbium (Ⅲ) ion into mesoporous silica particles, Jpn. J. Appl. Phys. 55 (2016) 105503.

DOI: 10.7567/jjap.55.105503

[4] A. Isobe, S. Takeshita, T. Isobe, Composites of Eu3+–Doped Calcium Apatite Nanoparticles and Silica Particles: Comparative Study of Two Preparation Methods, Langmuir. 31 (2015) 1811–1819.

DOI: 10.1021/la503652w

[5] P. Yang, Z. Quan, C. Li, X. Kang, H. Lian, J. Lin, Bioactive, luminescent and mesoporous europium–doped hydroxyapatite as a drug carrier, Biomaterials. 29 (2008) 4341–4347.

DOI: 10.1016/j.biomaterials.2008.07.042

[6] D.W. Wang, F. Li, Z. G. Chen, G. Q. Lu, H. M. Cheng, Synthesis and Electrochemical Property of Boron–Doped Mesoporous Carbon in Supercapacitor, Chem. Mater. 20 (2008) 7195–7200.

DOI: 10.1021/cm801729y

[7] M. Tagaya, K. Kobayashi, M. Nishikawa, Additive effect of phosphoric acid on phosphorus–containing mesoporous silica film formation, Mater. Lette. 164 (2016) 651–654.

DOI: 10.1016/j.matlet.2015.11.070

[8] M. Colilla, F. Balas, M. Manzano, M. Vallet–Regí, Novel method to enlarge the surface area of SBA–15, Chem. Mater. 19 (2007) 3099–3101.

DOI: 10.1021/cm071032p

[9] Q. He, J. Shi, M. Zhu, Y. Chen, F. Chen, The three–stage in vitro degradation behavior of mesoporous silica in simulated body fluid, Micropor Mesopor Mat, 131 (2010) 314–320.

DOI: 10.1016/j.micromeso.2010.01.009

[10] H. Yu, Q. Z. Zhai, Mesoporous SBA–15 molecular sieve as a carrier for controlled release of nimodipine, Micropor Mesopor Mat. 123 (2009) 298–305.

DOI: 10.1016/j.micromeso.2009.04.013

[11] I. Izquierdo–Barba, L. Ruiz–González, J. C. Doadrio, J. M. González–Calbet, M. Vallet–Regí. Tissue regeneration: A new property of mesoporous materials, Solid State Sci. 7 (2005) 983–989.

DOI: 10.1016/j.solidstatesciences.2005.04.003

[12] X. Li, J. Shi, Y. Zhu, W. Shen, H. Li, J. Liang, J. Gao, A Template Route to the Preparation of Mesoporous Amorphous Calcium Silicate With High In Vitro Bone-Forming Bioactivity, J Biomed Mater Res B Appl Biomater. 83 (2007) 431–439.

DOI: 10.1002/jbm.b.30813

[13] Tadashi Kokubo, Hiroaki Takadama, How useful is SBF in predicting in vivo bone bioactivity? Biomaterials 27 (2006) 2907–2915.

DOI: 10.1016/j.biomaterials.2006.01.017

[14] Brunauer, L.S. Deming, W.E. Deming, E. Teller, On a Theory of the van der Waals Adsorption of Gases, J. Am. Chem. Soc. 62 (1940) 1723–1732.

DOI: 10.1021/ja01864a025

[15] E.P. Barrett, L.G. Joyner, P.P. Halenda, The determination of pore volume and area distributions in porous substances. Computations from nitrogrn isotherms, J. Am. Chem. Soc. 73 (1951) 373−380.

DOI: 10.1021/ja01145a126

[16] T. Okazaki, W. Wang, H. Kuramitz, N. Hata, S. Taguchi, Molybdenum blue spectrophotometry for trace arsenic in ground water using a soluble membrane filter and calcium carbonate column, Anal. Sci. 29 (2013) 67–72.

DOI: 10.2116/analsci.29.67

[17] K.S.W. Sing, Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity, Pure Appl. Chem. 57 (1985) 603–619.

DOI: 10.1351/pac198557040603