Paper Titles

Utilization of Porcelain Tile Polishing Residue
p.699

Felsite in Ceramic Materials Production
p.704

Structure and Phase Composition of Ceramics Made of Powder Obtained by Chemical Dispersion of V95 Alloy
p.709

Magnetic Study on Divalent Ion Substituted Barium Hexaferrites
p.714

Effect of Phosphorus on Crystallization of Alkaline Molybdenum-Containing Borosilicate Glasses
p.720

Thermodynamic Assessment of Phase Equilibria in the SrO-Al₂O₃ System
p.725

Milling Duration Influence on Strontium Hexaferrite Technological Characteristics
p.730

Features of Melt Droplet Formation during Electrical Destruction Aluminum Films on the Semiconductor Surface
p.737

Influence of Laser Radiation on Movement of Dislocations in Silicon Single Crystals
p.742

HomeDefect and Diffusion ForumDefect and Diffusion Forum Vol. 410Effect of Phosphorus on Crystallization of...

Effect of Phosphorus on Crystallization of Alkaline Molybdenum-Containing Borosilicate Glasses

Article Preview

Abstract:

The effect of additives of P₂O₅ on the solubility of molybdenum in the amorphous part of glass and on the phase composition of the crystallized part of the highly alkaline glasses of the Li₂O–(Na₂O–K₂O)–B₂O₃-SiO₂ system was studied. The comparison of the phase composition of samples with or without phosphorus prior and after annealing allowed to determine the change of solubility of molybdenum in the amorphous part of the samples and to evaluate the thermal stability of the synthesized glass-ceramic materials. It was found, that for the compositions without phosphorus and the samples without lithium, when molybdenum is added at the synthesis stage, almost all of the molybdenum is included only in the crystalline molybdates. The study has shown an increase in the solubility of molybdenum only in the structure of lithium-containing glasses with phosphorus.

You might also be interested in these eBooks

Materials Engineering and Technologies for Production and Processing VII

Info:

Periodical:

Defect and Diffusion Forum (Volume 410)

Pages:

720-724

DOI:

https://doi.org/10.4028/www.scientific.net/DDF.410.720

Citation:

Cite this paper

Online since:

August 2021

Authors:

Viacheslav E. Eremyashev*, Galina G. Korinevskaya, Dmitry A. Zherebtsov

Keywords:

Borosilicate Glass, Glass Crystallization, Glass Structure, Molybdenum, Phosphorus, Waste Immobilization

Export:

RIS, BibTeX

Price:

Permissions:

Request Permissions

* - Corresponding Author

[1] D. Caurant, P. Loiseau, O. Majérus, V. Aubin-Chevaldonnet, I. Bardez, A. Quintas, Glasses, Glass-Ceramics and Ceramics for Immobilization of Highly Radioactive Nuclear Wastes, Nova Science Publishers, New York, (2009).

DOI: 10.1016/b978-0-12-818542-1.00090-4

[2] I.W. Donald, Waste Immobilization in Glass and Ceramic Based Hosts: Radioactive, Toxic and Hazardous Wastes, John Wiley & Sons, Ltd, (2010).

DOI: 10.1002/9781444319354

[3] W.E. Lee, M.I. Ojovan, M.C. Stennett, N.C. Hyatt, Immobilization of radioactive waste in glasses, glass composite materials and ceramics, Adv. Appl. Ceram. 105 (2006) 3-12.

DOI: 10.1179/174367606x81669

[4] J.S. McCloy, A. Goel, Glass-ceramics for nuclear-waste immobilization, MRS Bull. 42 (2017) 233-240.

DOI: 10.1557/mrs.2017.8

[5] O. Pinet, J.-F. Hollebecque, I. Hugon, V. Debono, L. Campayo, C .Vallat, V. Lemaitre, Glass ceramic for the vitriﬁcation of high level waste with a high molybdenum content, J. Nucl. Mater. 519 (2019) 121-127.

DOI: 10.1016/j.jnucmat.2019.03.041

[6] S.V. Stefanovsky, M.V. Skvortsov, O.I. Stefanovsky, B.S. Nikonov, I.A. Presniakov, I.S. Glazkova, A.G. Ptashkin, Preparation and characterization of borosilicate glass waste form for immobilization of HLW from WWER spent nuclear fuel reprocessing, MRS Adv. 2 (2017) 583-589.

DOI: 10.1557/adv.2016.622

[7] J.V. Crum, L. Turo, B .Riley, M. Tang, A. Kossoy, Multi-phase glass-ceramics as a waste form for combined fission products: alkalis, alkaline earths, lanthanides, and transition metals, J. Am. Ceram. Soc. 95 (2012) 1297-1303.

DOI: 10.1111/j.1551-2916.2012.05089.x

[8] A. Brehault, D. Patil, H. Kamat, R.E. Youngman, L.M. Thirion, J.C. Mauro, C.L. Corkhill, J.C. McCloy, A. Goel, Compositional dependence of solubility/retention of molybdenum oxides in aluminoborosilicate based model nuclear waste glasses, J Phys Chem B. 122 (2018) 1714-1729.

DOI: 10.1021/acs.jpcb.7b09158

[9] K. Ishiguro, N. Kawanishi, H. Nagaki, A. Naito, Chemical States of Molybdenum in Radioactive Waste Glass, Annual Progress Report of Power Reactor and Nuclear Fuel Development Corporation, Tokyo, Japan, (1982).

[10] R.J. Hand, R.J. Short, S. Morgan, N.C. Hyatt, G. Mobus, W.E. Lee, Molybdenum in glasses containing vitrified nuclear waste, Glass Technol. 46 (2005) 121-124.

[11] G. Calas, M. Le Grand, L. Galoisy, D. Ghaleb, Structural role of molybdenum in nuclear glasses: an EXAFS study, J. Nucl. Mater. 322 (2003) 15-20.

DOI: 10.1016/s0022-3115(03)00277-0

[12] D. Caurant, O. Majérus, E. Fadel, M. Lenoir, C. Gervais, O. Pinet, Effect of molybdenum on the structure and on the crystallization of SiO2–Na2O–CaO–B2O3 glasses, J. Am. Ceram. Soc. 90 (2007) 774-783.

DOI: 10.1111/j.1551-2916.2006.01467.x

[13] N. Chouard, D. Caurant, O. Majerus, N. Guezi-Hasni, J.L. Dussossoy, R. Baddour-Hadjean, J.P. Pereira-Ramos, Thermal stability of SiO2–B2O3–Al2O3–Na2O–CaO glasses with high Nd2O3 and MoO3 concentration, J. Alloys Compd. 671 (2016) 84-99.

DOI: 10.1016/j.jallcom.2016.02.063

[14] Y. Kawamoto, K. Clemens, M.Tomozawa, Effects of MoO3 on phase separation of Na2O-B2O3-SiO2 glasses, J. Am. Ceram. Soc. 64 (1981) 292-296.

DOI: 10.1111/j.1151-2916.1981.tb09605.x

[15] J.S. McCloy, B.J. Riley, J. Crum, J. Marcial, J.T. Reiser, K. Kruska, J.A. Peterson, D.R. Neuville, D.S. Patil, M. Saleh, K.E. Barnsley, J.V. Hanna, Crystallization study of rare earth and molybdenum containing nuclear waste glass ceramics, J. Am. Ceram. Soc. 102 (2019) 5149-5163.

DOI: 10.1111/jace.16406

[16] S. Schuller, O. Pinet, A. Grandjean, T. Blisson, Phase separation and crystallization of borosilicate glass enriched in MoO3, P2O5, ZrO2, CaO, J. Non-Cryst. Solids. 354 (2008) 296-300.

DOI: 10.1016/j.jnoncrysol.2007.07.041

[17] E. Nicoleau, S. Schuller, F. Angeli, T. Charpentier, P. Jollivet, A. Le Gac, M. Fournier, A. Mesbah, F. Vasconcelos, Phase separation and crystallization effects on the structure and durability of molybdenum borosilicate glass, J. Non-Cryst. Solids. 427 (2015) 120-133.

DOI: 10.1016/j.jnoncrysol.2015.07.001

[18] V.E. Eremyashev, D.A. Zherebtsov, G.G. Korinevskaya, V.V. Polozova, M.V. Shtenberg, S.A. Nayfert, The structure and thermal properties of high-alkali molybdenum-containing borosilicate matrix materials, Inorg. Mater. 57 (2021) 71-80.

DOI: 10.1134/s0020168521010052

[19] A.D. Prakash, M. Singh, R.K. Mishra, T.P .Valsala, A.K. Tyagi, A. Sarkar, C.P. Kaushik, Studies on modified borosilicate glass for enhancement of solubility of Molybdenum, J. Non-Cryst. Solids. 510 (2019) 172-178.

DOI: 10.1016/j.jnoncrysol.2019.01.019

[20] M. Szumera, MoO3 as a structure modifier of glasses from P2O5–SiO2–K2O–MgO–CaO system, Materials Letters. 135 (2014) 147-150.

DOI: 10.1016/j.matlet.2014.07.159

[21] V.E. Eremyashev, G.G. Korinevskaja, S.S. Bukalov, Titanium in the structure of alkali borosilicate glasses, Glass Ceram. 72 (2016) 405-408.

DOI: 10.1007/s10717-016-9798-7

[22] V.E. Eremyashev, D.A. Zherebtsov, L.M. Osipova, E.I. Danilina, Thermal study of melting, transition and crystallization of rubidium and caesium borosilicate glasses, Ceram. Int. 42 (2016) 18368-18372.

DOI: 10.1016/j.ceramint.2016.08.169

[23] V.E. Eremyashev, D.A. Zherebtsov, M.P. Brazhnikov, R.T. Zainullina, E.I. Danilina, Cerium influence on the thermal properties and structure of high-alkaline borosilicate glasses, J. Therm. Anal. Calorim. 139 (2020) 991-997.

DOI: 10.1007/s10973-019-08472-6