Synthesis and Characterization of Vinyl Substituted 2,2-Bisferrocenylpropane and Corresponding Polymers

Bin Dong; Xiao Li Wang; Feng Quan Liu

doi:10.4028/www.scientific.net/AMR.798-799.112

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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 798-799Synthesis and Characterization of Vinyl...

Synthesis and Characterization of Vinyl Substituted 2,2-Bisferrocenylpropane and Corresponding Polymers

Abstract:

The homopolymer of 6-vinyl bisferrocenylpropane and copolymer of 6-vinyl bisferrocenylpropane and 6,6'-divinyl bisferrocenylpropane were obtained from ferrocene and acetone via a series of reactions. The monomers and polymers were characterized by elemental analyses, IR spectra and ^IHNMR. The thermal stabilities of the polymers were studied through DTA-TG. The results show that the solubility of the copolymer of 6-vinyl bisferrocenylpropane and 6,6'-divinyl bisferrocenylpropane is very poor and its thermal stability is obviously higher than the homopolymer of 6-vinyl bisferrocenylpropane. The reason for it is that the monomer of 6,6'-divinyl bisferrocenylpropane has two vinyl groups, so the grafting degree of the corresponding polymer is much larger than the homopolymer of 6-vinyl bisferrocenylpropane.

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Periodical:

Advanced Materials Research (Volumes 798-799)

Pages:

112-115

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.798-799.112

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Online since:

September 2013

Authors:

Bin Dong, Xiao Li Wang, Feng Quan Liu

Keywords:

6,6'-Divinyl Bisferrocenylpropane, 6-Vinyl Bisferrocenylpropane, Copolymer, Homopolymer, Thermal Stability

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