Isomerization of α-Pinene over Alumina-Pillared Montmorillonite

Peng Quan Yao; Lin Hua Zhu; Jin Yang; Tian Si

doi:10.4028/www.scientific.net/AMR.746.49

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HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 746Isomerization of α-Pinene over Alumina-Pillared...

Isomerization of α-Pinene over Alumina-Pillared Montmorillonite

Abstract:

In this work, the liquid phase catalytic isomerization of α-pinene over alumina-pillared montmorillonitewas investigated, and the influence of reaction temperature, reaction time and amount of the catalyston the conversion of α-pinenewere discussed systematically, and the optimum reaction conditions forisomerization of α-pineneover alumina-pillared montmorillonitewere obtained. The basal spacing of thealumina-pillared montmorillonite was characterized by X-ray diffraction, and the liquid reactant was separated and identified by gas chromatography. The result showed that alumina-pillared montmorillonite with 1.83nm of basal spacing exhibited a high catalytic activity for the isomerization of α-pinene, and 97.4% conversion of α-pinene was achievedat 373K for 3hwhen the mass ratio of catalyst to α-pinene was 1/10.

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Periodical:

Advanced Materials Research (Volume 746)

Pages:

49-52

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.746.49

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Online since:

August 2013

Authors:

Peng Quan Yao, Lin Hua Zhu, Jin Yang, Tian Si

Keywords:

Alumina-Pillared Montmorillonite, Isomerization, α-Pinene

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