Mung Bean Shell (Vigna radiata L. Wilczek) - A Novel Cost-Effective Adsorbent for Removing Methylene Blue from Aqueous Solutions

Article Preview

Abstract:

The aim of this study was to establish an economical and environmentally benign biosorbent for removing synthetic dyes (e.g. methylene blue, MB) from wastewater. The adsorption process of MB onto abandoned mung bean (Vigna radiata L. Wilczek) shell (MBS) was investigated in a batch system. The results showed that a wide range of pH (3.74 to 9.78) was favorable for the adsorption of MB onto MBS. Equilibrium studies indicated that the Langmuir model displayed the best fit for the isothermal adsorption data. The maximum monolayer adsorption capacity (165.92 mg g-1) calculated by the Langmuir equation was higher than that of many previously investigated low-cost bioadsorbents (e.g., peanut hull, wheat straw, etc.). The adsorption process best fitted pseudo-second-order kinetic model. Thermodynamic studies showed that the adsorption process was spontaneously, exothermic and was mainly a physisorption. This study indicates that MBS is a promising, unconventional, affordable and environmentally friendly bio-measure that is easily deployed for removing cationic dyes from wastewater.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 573-574)

Pages:

68-79

Citation:

Online since:

October 2012

Export:

Price:

[1] K. Murugesan, A. Dhamija, I. -H. Nam, Y. -M. Kim and Y. -S. Chang: Dyes Pigments. Vol. 75 (2007), pp.176-184.

Google Scholar

[2] P. Bo and X. Qin: Dyes and Chemicals (in Chinese) Vol. 24 (2002), pp.29-31.

Google Scholar

[3] X. Fu, X. Chen, J. Wang and J. Liu: Microporous Mesoporous Mater. Vol. 139 (2011), pp.8-15.

Google Scholar

[4] A.W.M. Ip, J.P. Barford and G. McKay: Chem. Eng. J. Vol. 157 (2010), pp.434-442.

Google Scholar

[5] P. Luo, Y. Zhao, B. Zhang, J. Liu, Y. Yang and J. Liu: Water Res. Vol. 44 (2010), pp.1489-1497.

Google Scholar

[6] M.E. Fernandez, G.V. Nunell, P.R. Bonelli and A.L. Cukierman: Bioresour. Technol. Vol. 101 (2010), pp.9500-9507.

Google Scholar

[7] B. Bestani, N. Benderdouche, B. Benstaali, M. Belhakem and A. Addou: Bioresour. Technol. Vol. 99(2008), pp.8441-8444.

DOI: 10.1016/j.biortech.2008.02.053

Google Scholar

[8] E. Bayram and E. Ayranci: Environ. Sci. Technol. Vol. 44 (2010), pp.6331-6336.

Google Scholar

[9] G. Sreelatha, V. Ageetha, J. Parmar and P. Padmaja: J. Chem. Eng. Data Vol. 56 (2011), pp.35-42.

Google Scholar

[10] K. Marungrueng and P. Pavasant: Bioresour. Technol. Vol. 98 (2007), pp.1567-1572.

Google Scholar

[11] F. Banat, S. Al-Asheh, R. Al-Ahmad and F. Bni-Khalid: Bioresour. Technol. Vol. 98 (2007), pp.3017-3025.

DOI: 10.1016/j.biortech.2006.10.023

Google Scholar

[12] C.A.P. Almeida, N.A. Debacher, A.J. Downs, L. Cottet and C.A.D. Mello: J. Colloid Interface Sci. Vol. 332 (2009), pp.46-53.

DOI: 10.1016/j.jcis.2008.12.012

Google Scholar

[13] M. Dogan, M. Alkan, A. Türkyilmaz and Y. Özdemir: J. Hazard. Mater. Vol. 109 (2004), pp.141-148.

Google Scholar

[14] K.G. Bhattacharyya and A. Sarma: Dyes Pigments. Vol. 57 (2003), pp.211-222.

Google Scholar

[15] A. Demirbas: J. Hazard. Mater. Vol. 157 (2008), pp.220-229.

Google Scholar

[16] Y. Feng, F. Yang, Y. Wang, L. Ma, Y. Wu, P. G. Kerr and L. Yang: Bioresour. Technol. Vol. 102 (2011), pp.10280-10285.

Google Scholar

[17] S. J. Allen, Q. Gan, R. Matthews and P. A. Johnson: Ind. Eng. Chem. Res. Vol. 44 (2005), p.1942-(1949).

Google Scholar

[18] Y. Wu, J. He and L. Yang: Environ. Sci. Technol. Vol. 44 (2010), pp.6319-6324.

Google Scholar

[19] F. Deniz and S.D. Saygideger: Bioresour. Technol. Vol. 101 (2010), pp.5137-5143.

Google Scholar

[20] Y. -S. Ho: Water Res. Vol. 40 (2006), pp.119-125.

Google Scholar

[21] N. Thinakaran, P. Panneerselvam, P. Baskaralingam, D. Elango and S. Sivanesan: J. Hazard. Mater. Vol. 158 (2008), pp.142-150.

Google Scholar

[22] R. Han, Y. Wang, P. Han, J. Shi, J. Yang and Y. Lu: J. Hazard. Mater. Vol. B137 (2006), pp.550-557.

Google Scholar

[23] F. Batzias, D. Sidiras, E. Schroeder and C. Weber: Chem. Eng. J. Vol. 148 (2009), pp.459-472.

Google Scholar

[24] Y. Bulut and H. Aydın: Desalination. Vol. 194 (2006), P. 259-267.

Google Scholar

[25] V. Vadivelan and K.V. Kumar: J. Colloid Interface Sci. Vol. 286 (2005), pp.90-100.

Google Scholar

[26] F. Ferrero: J. Hazard. Mater. Vol. 142 (2007), pp.144-152.

Google Scholar

[27] H. Demir, A. Top, D. Balköse and S. Ülkü: J. Hazard. Mater. Vol. 153 (2008), pp.389-394.

Google Scholar

[28] J. Y. Song, W. H. Zou, Y. Y. Bian, F. Y. Su and R. P. Han: Desalination. Vol. 265 (2011), pp.119-125.

Google Scholar

[29] F. Raposo, M. A. De La Rubia and R. Borja: J. Hazard. Mater. Vol. 165 (2009), pp.291-299.

Google Scholar

[30] S. K. Das, J. Bhowal, A. R. Das and A. K. Guha: Langmuir. Vol. 22 (2006), pp.7265-7272.

Google Scholar

[31] J. Pan, X. Zou, X. Wang, W. Guan, C. Li, Y. Yan and X. Wu: Chem. Eng. J. Vol. 166 (2011), pp.40-48.

Google Scholar

[32] Y. Yao, F. Xu, M. Chen, Z. Xu and Z. Zhu: Bioresour. Technol. Vol. 101 (2010), pp.3040-3046.

Google Scholar

[33] N. Kannan and M.M. Sundaram: Dyes Pigments. Vol. 51 (2001), pp.25-40.

Google Scholar

[34] F. -C. Wu and R. -L. Tseng: J. Hazard. Mater. Vol. 152 (2008), pp.1256-1267.

Google Scholar

[35] F. -C. Wu, R. -L. Tseng and R. -S. Juang: Chem. Eng. J. Vol. 150 (2009), pp.366-373.

Google Scholar

[36] A.A. Atia, A.M. Donia and W.A. Al-Amrani: Chem. Eng. J. Vol. 150 (2009), pp.55-62.

Google Scholar

[37] X. Wu, B. Xiao, R. Li, C. Wang, J. Huang and Z. Wang: Environ. Sci. Technol. Vol. 45 (2011), pp.2641-2647.

Google Scholar

[38] N.M. Mahmoodi, M. Arami, H. Bahrami and S. Khorramfar: Desalination. Vol . 264 (2010), pp.134-142.

Google Scholar