Study on the Hydrotreating Catalysts Containing Phosphorus of Coal Tar to Clean Fuels

Hong Hua Zhang; Yi Min Cao; Muhammad Usman; Li Jun Li; Chun Shan Li

doi:10.4028/www.scientific.net/AMR.531.263

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HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 531Study on the Hydrotreating Catalysts Containing...

Study on the Hydrotreating Catalysts Containing Phosphorus of Coal Tar to Clean Fuels

Abstract:

The effect of phosphorus catalysts for hydrogenation reactions were studied in this work. Different catalysts supported on γ-Al2O3 containing phosphorus (WNiP/γ-Al2O3, MoNiP/γ-Al2O3, WMoNiP/γ-Al2O3 and WMoCoP/γ-Al2O3) were prepared through ultrasonic-assisted impregnation and temperature-programming methods. The catalytic hydrotreating reaction are under the reaction conditions of PH2=9MPa, Thf=370oC, space velocity=0.5h-1, and H2/oil ratio=1400. Gasoline (≤180oC) and diesel (180–360oC) are separated from the liquid product. The fractions were characterized by Elemental analysis, FTIR, KY3000 S/N and GC-MS analysis. Though analysis of test results, it can be concluded that the WNiP/γ-Al2O3 is the excellent hydrotreating catalyst in this series at this reaction condition.

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Periodical:

Advanced Materials Research (Volume 531)

Pages:

263-267

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.531.263

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Online since:

June 2012

Authors:

Hong Hua Zhang, Yi Min Cao, Muhammad Usman, Li Jun Li, Chun Shan Li

Keywords:

Analysis, Catalytic Activity, Hydrotreating Catalysts, Phosphorus

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